• Title/Summary/Keyword: Phase potential

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PMMA Coated BaF2:Er3+ Nanoparticles via a Novel One-Step Reverse-Emulsion Polymerization Process

  • Lian, Hongzhou;Fu, Lianshe;Andre, Paulo S.;Lin, Jun
    • Bulletin of the Korean Chemical Society
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    • v.34 no.8
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    • pp.2451-2454
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    • 2013
  • Poly(methyl methacrylate) coated $BaF_2:Er^{3+}$ nanoparticles were prepared via a novel reverse-emulsion polymerization process using methyl methacrylate as continuous phase and water as dispersed phase. Preparation and coating of $BaF_2:Er^{3+}$ particles were processed in a single step. The resulting polymeric composites show the characteristic $Er^{3+}$ luminescence at excitation of 980 nm and may have potential applications in amplified optical networks.

An Efficient Two-Phase Heuristic Policy for Acceptance Control in IaaS Cloud Service (IaaS 클라우드 서비스 수락제어를 위한 효율적인 2단계 휴리스틱 정책)

  • Kim, Moon Kyung;Choi, Jin Young
    • Journal of Korean Society of Industrial and Systems Engineering
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    • v.38 no.2
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    • pp.91-100
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    • 2015
  • In this study, we propose an efficient two-phase heuristic policy, called an acceptance tolerance control policy, for Infrastructure as a Service (IaaS) cloud services that considers both the service provider and customer in terms of profit and satisfaction, respectively. Each time an IaaS cloud service is requested, this policy determines whether the service is accepted or rejected by calculating the potential for realizing the two performance objectives. Moreover, it uses acceptance tolerance to identify the possibility for error with the chosen decision while compensating for both future fluctuations in customer demand and error possibilities based on past decisions. We conducted a numerical experiment to verify the performance of the proposed policy using several actual IaaS cloud service specifications and comparing it with other heuristics.

Development of High Performance Stainless Steel Powders

  • Schade, Christopher;Schaberl, John;Narasimhan, Kalathur S.
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.169-170
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    • 2006
  • Advanced melting technology is now being employed in the manufacture of stainless steel powders. The new process currently includes electric arc furnace (EAF) technology in concert with Argon Oxygen Decarburization (AOD), High Performance Atomizing (HPA) and hydrogen annealing. The new high performance-processing route has allowed the more consistent production of existing products, and has allowed enhanced properties, such as improved green strength and green density. This paper will review these processing changes along with the potential new products that are being developed utilizing this technology. These include high strength stainless steels such as duplex and dual phase as well as stainless steel powders used in high temperature applications such as diesel filters and fuel cells.

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Simultaneous optical ignition and spectroscopy of a two-phase spray flame for feedback control System (이상상태 분무 화염에서의 레이저 점화 및 분광 측정을 통한 피드백 제어 연구)

  • Lee, Seok Hwan;Kim, Hyunwoo;Do, Hyungrok;Yoh, Jack J.
    • 한국연소학회:학술대회논문집
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    • 2015.12a
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    • pp.215-218
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    • 2015
  • Simultaneous laser ignition and spectroscopy is a scheme that enables rapid determination of the local equivalence ratio and condensed fuel concentration during a reaction in a two phase spray flame. We have conducted quantitative analysis of the LIBS signals according to the equivalence ratio, droplet size, droplet number density and droplet concentration as a part of novel feedback control strategy proposed for flame ignition and stabilization with simultaneous in situ combustion flow diagnostics. This is a desirable scheme since such real time information onboard an engine for instance can be constantly monitored and fed back to the control loop to enhance the mixing process and minimize emissions of unwanted species and potential combustion instability.

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Observation of Parametric Resonance in a Magneto-Optical Trap

  • Jhe, Won-Ho;Noh, Heung-Ryoul;Kim, Ki-Hwan;Ha, Hyun-Ji
    • Journal of the Optical Society of Korea
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    • v.7 no.2
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    • pp.119-125
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    • 2003
  • We demonstrate parametric resonance in a magneto-optical trap. When we modulate the intensity of the cooling laser at about twice the resonant frequency of the trap, the atoms in the trap are divided into two parts and oscillate with 180 degree phase difference with the finite length due to nonlinearity of the trap potential. These are the effects of general nonlinear dynamics, called the Hopf bifurcation, or limit cycle motion. The amplitude and the phase of the oscillations are measured and compared with the theoretical calculations based on simple Doppler cooling theory. The experimental results are in excellent agreement with the simulation results based on the simple Doppler cooling theory.

Theoretical Studies on the Gas-phase Reaction of Methyl Formate with Anions$^\dag$

  • Lee, Ik-Choon;Chung, Dong-Soo;Lee, Bon-Su
    • Bulletin of the Korean Chemical Society
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    • v.10 no.3
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    • pp.273-278
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    • 1989
  • The gas-phase reactions of methyl formate with anions, $-NH_2,\;-OH,\;-CH_2CN$, are studied theoretically using the AM1 method. Stationary points are located by the reaction coordinate method, refined by the gradient norm minimization and characterized by the determination of Hessian matrix. Potential energy profiles and the stationary point structures are presented for all conceivable processes. Four reaction paths are found to be possible: formyl proton and methyl proton abstractions, carbonyl addition, and $S_N2$ process. For the most basic anion $-NH_2$ the proton abstraction path is favored, while in other case, $OH\;and\;-CH_2CN$, the carbonyl addition paths are favored. In all cases the $S_N2$ process is the most exothermic, but due to the relatively high activation barrier the process can be ruled out.

Synthesis and Characteristics of Different Ratio of Stearic Acid with SiO2 Shell Through Sol-Gel Process (Sol-gel 공정을 통한 SiO2 쉘과의 상이한 스테아산 비율의 합성 및 특성)

  • Ishak, Shafiq;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2020.06a
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    • pp.66-67
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    • 2020
  • The synthesis of stearic acid composite phase change material (PCM) was investigated and the samples produced were characterized for use in latent heat storage, using a simple chemical sol-gel process. The PCM was encapsulated to tetraethyl orthosilicate by various preparation ratios of stearic acid (5, 10, 15, 20, 30 and 50%). Fourier transformation infrared spectroscope (FT-IR) and X-Ray diffraction (XRD) were performed to determine the chemical structure and crystalloid phase of the microencapsulated PCM. SATEOS1 (5%) shows the best proportion for the PCM. With the presence of stearic acid as core materials and SiO2 as the supporting materials, it does not show any chemical reaction between both of them. SATEOS1 shows promising potential for thermal energy storage as it shows a better encapsulation efficiency and good thermal stability.

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A PROFIRABILITY MODEL BASED ON PRIMARY FACTOR ANALYSIS IN THE EARLY PHASE OF HOUSING REDEVELOPMENT PROJECTS

  • Kyeong-Hwan Ahn;U-Yeong Gim;Jong-Sik Lee;Won Kwon;Jae-Youl Chun
    • International conference on construction engineering and project management
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    • 2013.01a
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    • pp.497-501
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    • 2013
  • An important decision-making element for the success of housing redevelopment projects is a prediction of the profitability of redevelopment. Risk factors influencing profitability were deduced through a review of the literature about profitability and a risk analysis developed by a survey of maintenance projects. In addition, a profitability prediction depending on the analysis of risk factors is necessary to judge the business feasibility of a project in the planning stages. A profitability prediction model of management and disposal method, which is calculated by proportional rate and which helps estimate contributions to profitability, is proposed to prevent difficulties in business development. The proposed model has the potential to prevent interruptions, reduce the length of projects, generate cost savings, and enable rational decision-making during the project period by allowing a judgment of profitability at the planning stage.

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SELECTING OPTIMUM MANAGEMENT PRACTICES IN PRE-CONSTRUCTION PHASE CONSIDERING PROJECT CHARACTERISTICS

  • Hee-Sung Cha;Ki-Hyun Kim;Young-Jin Ko
    • International conference on construction engineering and project management
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    • 2011.02a
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    • pp.609-613
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    • 2011
  • The importance of project performance management as an alternative for solving problems is rising, which are followed by the difficulties of managing construction project in the construction industry. This research classifies and applies the potential improvement made by the construction practitioners. In order to apply influential factors for success on the construction project, the research identifies the relationship between the factors and performance management practices. In addition, in order to predict the results reflecting the project characteristics which are un-improvable by the construction managers in the initial stage of construction, the effect of project characteristics to the identified management practices have been drawn by performance area. Finally, in order to improve the predicted performance, this research provides a framework in setting valid best practices according to the performance areas through a statistical analysis between the best practices and project characteristics through the industry survey.

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Preparation and Characterization of the Asymmetric Microporous Poly(vinylidene fluoride) (PVDF) Blend Membranes with Hydrophilic Surfaces

  • Hwang, Jeong-Eun;JeGal, Jong-Geon
    • Korean Membrane Journal
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    • v.9 no.1
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    • pp.1-11
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    • 2007
  • To prepare chemically stable asymmetric microporous membranes with a hydrophilic surface, which would be expected to have better antifouling properties, poly(vinylidene fluoride) (PVDF) blend membranes were prepared by the phase inversion process. PVDF mixture solutions in N-methylpyrrolidone (NMP) blended with several polar potential ionic polymers such as polyacrylonitrile (PAN), poly(methylmethacrylate) (PMMA) and poly(N-isopropylacrylamide) (NIPAM) were used for the formation of the PVDF blend membranes. They were then characterized with several analytical methods such as FESEM, FTIR, contact angle measurement, pore size distribution and permeability measurement. Regardless of different polar polymers blended, they all showed a finger-like structure with more hydrophilic surface than the pristine PVDF membrane. For all the PVDF blend membrane, due to the polar potential ionic polymers used, the flux of those was improved. Especially the PVDF blend membrane with NIPAM showed the highest flux among the membranes prepared. Also antifouling property of the PVDF membrane was improved by the use of the polar polymers.