• Title/Summary/Keyword: Phase change behavior

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Heavy Metal Leaching Characteristics of Silicate Glass Containing EAF Dust (전기로 제강분진이 첨가된 규산염계 유리의 중금속 용출 특성)

  • Kim, Hwan-Sik;Kang, Seung-Gu;Kim, Yoo-Taek;Lee, Gi-Gang;Kim, Jung-Hwan
    • Journal of the Korean Ceramic Society
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    • v.43 no.2 s.285
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    • pp.136-141
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    • 2006
  • The stabilizing behavior of heavy metals in the silicate glass containing Electric Arc Furnace dust (EAF dust) were studied by the Toxic Characterization Leaching Procedure (TCLP) test, and the change of crystalline phase and glass network structure were investigated as a function of EAF dust content added. The glass containing EAF dust of $30\;wt\%$ an oxygen/network former ratio(R) of $2\~3$ allowing a fairly stable network structure thus showed much lower heavy metal leaching concentration than that for containing EAF dust above $50\;wt\%$ at TCLP test. For the glass containing EAF dust $50\~60\;wt\%$, however, the R was over 3, which weakened the glass network structure and increased the heavy metals leachate. Adding the EAF dust to a glass decreased the degree of Si-O-Si symmetry and increased the number of non-bridging oxygen, which decreased the chemical durability of glasses. When the dust content in a glass was over $70\;wt\%$, the Zn and Fe ions reacted to form the spinel crystal rather than to bind to network structure of glass and leaching concentration of those ions from the specimen decreased, so the spinel phase could be attributed to lowering a heavy metal leaching.

An Isolated Power System Based on Variable Speed Engine Generator with Super-capacitor (슈퍼캐패시터와 가변속 엔진발전기를 이용한 독립형 전원 시스템)

  • Lee, Joon-Hwan;Lee, Seung-Hwan;Sul, Seung-Ki
    • The Transactions of the Korean Institute of Power Electronics
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    • v.13 no.2
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    • pp.128-134
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    • 2008
  • The variable speed engine generator set is interested for an isolated power system due to reduced fuel consumption and less emission. However, because of sluggish dynamic behavior of the internal combustion engine the power quality would be degraded during the sudden load power surge, where the power required by the load is not available by the engine due to the reduced engine speed. An isolated power system based on variable speed engine with a super-capacitor bank can improve dynamic characteristics under such a sudden load change, and power quality, fuel consumption, and pollutants can be improved remarkably. Also, it is verified by the computer simulation that the inverter of 3phase-4leg is compatible to the isolated power system with unbalanced load. In this paper, the feasibility of the system has been verified based on a 26kw commercial diesel engine system.

Numerical Model of Heat Diffusion and Evaporation by LNG Leakage at Membrane Insulation (LNG 화물창 방열재 균열에 따른 액화천연가스의 확산 및 온도 예측을 위한 수치 모델)

  • Lee, Jang Hyun;Kim, YoonJo;Hwang, Se Yun
    • Journal of Ocean Engineering and Technology
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    • v.28 no.6
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    • pp.517-526
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    • 2014
  • The leakage of cryogenic LNG through cracks in the insulation membrane of an LNG carrier causes the hull structure to experience a cold spot as a result of the heat transfer from the LNG. The hull structure will become brittle at this cold spot and the evaporated natural gas may potentially lead to a hazard because of its flammability. This paper presents a computational model for the LNG flow and heat diffusion in an LNG insulation panel subject to leakage. The temperature distribution in the insulation panel and the speed of gas diffusion through it are simulated to assess the safety level of an LNG carrier subject that experiences a leak. The behavior of the leaked LNG is modeled using a multiphase flow that considers the mixture of liquid and gas. The simulation model considers the phase change of the LNG, gas-liquid multiphase interactions in the porous media, and accompanying rates of heat transfer. It is assumed that the NO96-GW membrane storage is composed of glass wool and plywood for the numerical simulation. In the numerical simulation, the seepage, heat diffusion, and evaporation of the LNG are investigated. It is found that the diffusion speed of the leakage is very high to accelerate the evaporation of the LNG.

Photo-catalytic Characteristics of Sol-Gel Synthesized TiO2 Thin Film (졸-겔법을 이용한 TiO2 박막의 광촉매 특성)

  • Choi, Kyu-Man;Kim, Yeo-Hwan;Lim, Hae-Jin
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.14 no.2
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    • pp.846-849
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    • 2013
  • Thin film of $TiO_2$ was obtained by the sol-gel dip method on the brosilicate glass substrate. It was found that the film was about $1.5{\mu}m$ thick as obtained by 4 successive coatings and annealed at varied temperatures ranged from $300^{\circ}C$ to $1100^{\circ}C$ for 2 hrs. The substrate used was having the surface area of $100mm^2$. Increasing the annealing temperature caused to change in mineralogical phase of titanium oxide i.e., amorphous, crystalline antase to rutile phases. The particle size of the titanium oxide film were ranged from $0.1{\sim}0.54{\mu}m$ estimated by the SEM analysis. The material showed an absorbance maximum at the wavelength 390nm obtained by UV-visible spectrophotometer. These results therefore, indicated that the $TiO_2$ film obtained relatively at low annealing temperature consisted predominantly with anatase phase; possessed higher photocatalytic behavior i.e., 2.4 times higher than that of only UV lamp irradiation.

Contraction Behavior of Collagen Gel and Fibroblats Activity in Dermal Equivalent Model

  • Yang, Eun-Kyung;Lee, Doo-Hoon;Park, Sue-Nie;Choe, Tae-Boo;Park, Jung-Keug
    • Journal of Microbiology and Biotechnology
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    • v.7 no.4
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    • pp.267-271
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    • 1997
  • We developed a dermal equivalent (DE) which was engineered using human dermal fibroblasts and a matrix of collagen gel. The in vitro construction of the DE was accomplished by casting a porcine collagen type I solution plus concentrated medium with isolated and cultured fibroblasts. These constructs were attached to culture dishes or left floating in culture medium. Contraction of attached gels results in decreased gel thickness without a change in gel diameter, and contraction of floating gels results in decreased gel thickness and diameter. After contraction, there was no increase in cell number in floating gels, but cells in attached gels began to increase after about 4 days of the lag phase in cell growth curve. At this lag phase, addition of fibroblast growth factor (FGF) at a concentration of $0.1{\mu}$/ml promoted cell proliferation in the attached collagen gels, but no effect in floating gels. These results indicate that the method of contraction had an influence on the extracellular matrix (ECM) organization, and this influenced not only cell growth but also fibroblast responsiveness to FGF. This suggests that attached collagen gel is more suitable as a dermal equivalent than the floating gel. And the final contracted area of attached gel is much larger than that of the floating gel since floating gel is contracted in all directions but attached gel is contracted only vertically.

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Microstructures and Thermal Properties of Polycaprolactone/Epoxy Resin/SiO2 Hybrids

  • He, Lihua;Liu, Pinggui;Ding, Heyan
    • Journal of Adhesion and Interface
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    • v.7 no.4
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    • pp.32-38
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    • 2006
  • A series of organic-inorganic hybrids, PCL/EP/$SiO_2$, involving epoxy resin and triethoxysilane-terminated polycaprolactone elastomer (PCL-TESi) were prepared via polymerization of diglycidyl ether of bisphenol A (DGEBA) with amine curing agent KB-2 and sol-gel process of PCL-TESi. The curing reactions were started from the initially homogeneous mixture of DGEBA, KB-2 and the PCL-TESi. The organicinorganic hybrids containing up to 4.95% (wt) of $SiO_2$ were obtained and characterized by FT-IR, transmission electron microscopy (TEM), differential scanning calorimetry (DSC) and thermogravimetry analysis (TGA). It was experimentally shown that the swelling property in toluene, morphologies and thermal properties of the resulting hybrids were quite dependent on the contents of $SiO_2$. The crosslink network density decreases with increasing of the PCL-TESi. And in TEM, the phase separated morphology of these hybrids was found, which resulted from the coagulation of Si-O-Si networks resulting from $-Si(OC_2H_5)_3$ of PCL-TESi self-curing by hydrolytic silanol condensation, with the advancement of the curing reaction in the modified epoxy resin systems. Meanwhile, the change of the $SiO_2$ content made the morphologies changed from aggregated particles of Si-O-Si in the hybrid to nanocluster of interconnected Si-O-Si particles, then to aggregated Si-O-Si dispersing in the continuous cured epoxy phase again, and last to co-continuous interpenetrating network. The glass transition behavior of the hybrid material was cooperative motion of large chain segments, which were hindered by the inorganic Si-O-Si network. And in TG analysis, the characteristic temperature at 5% of weight loss was evidently increased from $120.5^{\circ}C$ of pure cured epoxy to $277.6^{\circ}C$ of 3.84% (wt) of $SiO_2$ modified epoxy due to the existence of Si-O-Si when PCL-TESi was added in the hybrid.

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Electrical Properties of ZnO-Bi2O3-Sb2O3 Ceramics (ZnO-Bi2O3-Sb2O3 세라믹스의 전기적 특성)

  • Hong, Youn-Woo;Shin, Hyo-Soon;Yeo, Dong-Hun;Kim, Jong-Hee;Kim, Jin-Ho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.8
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    • pp.738-748
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    • 2008
  • In this study, it has been investigated on the changing behavior of electrical properties in $ZnO-Bi_2O_3-Sb_2O_3$ (Sb/Bi=2.0, 1.0 and 0.5) ceramics. The samples were prepared by conventional ceramic process, and then characterized by I-V, C-V curve plots, impedance and modulus spectroscopy (IS & MS) measurement. The electrical properties of ZBS systems were strongly dependent on Sb/Bi. In ZBS systems, the varistor characteristics were deteriorated noticeably with increasing Sb/Bi and the donor density and interface state density were increased with increasing Sb/Bi. On the other hand, we observed that the grain boundary reacted actively with the ambient oxygen according to Sb/Bi ratio. Especially the grain boundaries of Sb/Bi=0.5 systems were divided into two types, i.e. sensitive to oxygen and thus electrically active one and electrically inactive intergranular one with temperature. Besides, the increased pyrochlore and $\beta$-spinel phase with Sb/Bi ratio caused the distributional inhomogeneity in the grain boundary barrier height and the temperature instability. To the contrary, the grain boundary layer was relatively homogeneous and more stable to temperature change and kept the system highly nonlinear at high Bi-rich phase contents.

A Theoretical Study on Interface Characteristics of SiC Particulate Reinforced Metal Matrix Composite Using Ultrasonics (초음파를 이용한 입자강화 금속복합재료의 계면특성에 관한 이론적 연구)

  • Lee, Joon-Hyun
    • Journal of the Korean Society for Nondestructive Testing
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    • v.13 no.4
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    • pp.9-17
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    • 1994
  • It is well recognized recently that ultrasonic technique is one of the most widely used methods of nondestructive evaluation to characterize material properties of nonconventional engineering materials. Therefore it is very important to understand physical phenomenon on propagation behavior of elastic wave in these materials, which is directly associated with ultrasonic signals in the test. In this study, the theoretical analysis on multi-scattering of harmonic elastic wave due to the particulate with interface between matrix and fiber in metal matrix composites(MMCs) was done on the basis of Lax's quasi-crystalline approximation and extinction theorem. SiC particulate (SiCp) reinforced A16061-T6 composite material was chosen for this analysis. From this analysis, frequency dependences of phase velocity and amplitude attenuation of effective plane wave due to the change of volume fraction of SiC particulate were clearly found. It was also shown that the interface condition between matrix and fiber in MMCs gives a direct effect on the variation of phase velocity of plane wave in MMCs.

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Fabrication of AlN Thin Film by Reactive RF Magnetron Sputtering and Sensing Characteristics of Oil Pressure (반응성 RF 마그네트론 스퍼터링에 의한 AlN 박막 제조 및 유압 감지 특성)

  • Seok, Hye-Won;Kim, Sei-Ki;Kang, Yang-Koo;Hong, Yeon-Woo;Lee, Young-Jin;Ju, Byeong-Kwon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.27 no.12
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    • pp.815-819
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    • 2014
  • Aluminum nitride (AlN) thin film and TiN film as a buffer layer were deposited on INCONEL 600 substrate by reactive RF magnetron sputtering at room temperature(R.T.) under 25~75% $N_2/Ar$ atmosphere. The as-deposited AlN films at 25~50% $N_2/Ar$ showed a polycrystalline phase of hexagonal AlN, and an amorphous phase. The peak of AlN (002) plane, which was determinant on a performance of piezoelectric transducer, became strong with increasing the $N_2/Ar$ ratio. Any change in the preferential orientation of the as-deposited AlN films was not observed within our $N_2$ concentration range. The piezoelectric sensing properties of AlN module were performed using pressure-voltage measurement system. The output signal voltage of AlN module showed a linear behavior between 20~80 mV in 1~10 MPa range, and the pressure-sensing sensitivity was calculated as 3.6 mV/MPa.

A Study on Consciousness & Value of Sexuality of Elementary School Children (초등학교 학생들의 성 의식 및 가치관에 관한 연구)

  • Lee, Hae-Yun;Park, Young-Soo
    • The Journal of Korean Society for School & Community Health Education
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    • v.2 no.1
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    • pp.53-65
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    • 2001
  • The purposes of this study were to collect basic data on education of Sexuality(Health education) of consciousness & value of sexuality of elementary school children. 584,6th grade students in elementary school in Yong-In city were analysed and the results are as follow; 1. Knowledges of sexuality for children was at a average level, especially "physical change of puberty" and "sexual violence" were well recognized but "the physical characteristics of male & female" and "physiological phenomena of men" were less recognized. Attitudes of sexuality were positive for "relationship with partners" and "expression of mind". Practices of sexuality were at a low rate in the case of "shaking hands with partner" and "experience of sexual behavior". The Value of sexuality was at a high rates in the case of "the role of sex", "equality" & "self-identification", therefore students need good education of sexuality from childhood 2. Sexuality education of students increased knowledges of sexuality as a consciousness. There was no relationship between attitudes and pratices of sexuality. Educated children valued sexuality move highly than uneducated children. This result shows that education is needed with regard to both the knowledge and value of sexuality in a planned system. We need some program to provide more information on sexual attitudes and practices. 3. There was a high correlation between the consciousness of sexuality and value placed on it. As sexual awareness increases amongst students codes of morality develop Positive sexual attitudes served as good role models for sex. In particular positive sexual attitudes have a big effect on sexual values. In addition, as sexual awareness and attitude increase amongst students the role of sexual development. The elementary school phase sexual values are developed and determined. It is therefore an important phase.

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