• Title/Summary/Keyword: Packed technique

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Non-thermal plasma를 이용한 VOCs의 제거기술

  • Song, Yeong-Hun;Sin, Wan-Ho;Kim, Gwan-Tae;Kim, Seok-Jun;Sim, Sun-Yong;Jang, Dong-Je
    • 한국연소학회:학술대회논문집
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    • 1998.10a
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    • pp.31-36
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    • 1998
  • An experimental study has been performed to characterize fundamental aspects of VOCs removal using non-thermal palsma technique. The removed VOCs in the present study are toluene ($C_6H_5CH_3$), ethene ($C_2H_4$), propene ($C_3H_6$) which are typical air pollutants generated from industry and automobile engines. The non-thermal plasma used in the present experiments has been produced in a wire-cylinder reactor with pulsed corona or a packed-bed reactor filled with ceramic bead. These differently generated non-thermal plasma have been visualized with an intensified CCD. The images of non-thermal plasma have been used for optimal design of a corona reactor used in the present study. The experimental results show that the removal efficiencies of VOCs with non-thermal plasma are dependant on the reactivity of VOCs with OH, O, and $O_3$. The results also show that the removal efficiencies of VOCs decrease significantly when VOCs are treated with NO that is also oxidized in the presence of OH, O, and $O_3$.

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Development of Ultra-High Pressure Capillary Reverse-Phase Liquid Chromatography/Tandem Mass Spectrometry for High-Sensitive and High-Throughput Proteomics

  • Kim, Min-Sik;Choie, Woo-Suk;Shin, Yong-Seung;Yu, Myeong-Hee;Lee, Sang-Won
    • Bulletin of the Korean Chemical Society
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    • v.25 no.12
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    • pp.1833-1839
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    • 2004
  • Recently mass spectrometry and separation methods such as liquid chromatography have become major tools in the field of proteomics. In this report, we describe in detail our efforts to develop ultra-high pressure capillary reverse-phase liquid chromatography (cRPLC) and its online coupling to a mass spectrometer by a nanoelectrospray (nanoESI) interface. The RPLC system is constructed in house to deliver LC solvents at the pressure up to 20,000 psig, which is four times higher than conventional RPLC systems. The high operation pressure allows the efficient use of packed micro-capillary columns (50, 75 and 150 ${\mu}$m i.d., up to 1.5 m long). We will discuss the effect of column diameter on the sensitivity of cRPLC/MS/MS experiments and the utility of the developed technique for proteome analysis by its application in the analysis of proteome samples having different levels of complexity.

3D Micromorphology Producing within Poly(lactic acid) Skeleton Using Room-Temperature Ionic Liquids: From Particulate, Fibrous or Porous Scaffolds to Beads

  • Shin, Ueon-Sang;Kim, Jong-Gyu
    • Bulletin of the Korean Chemical Society
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    • v.33 no.7
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    • pp.2295-2298
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    • 2012
  • We describe herein a three-dimensionally diverse micropatterning of poly(lactic acid), as a biopolymer, using 1-butyl-3-methylimidazolium-based room-temperature ionic liquids (bmim-based RTILs), [bmim]X (X = $SbF_6$, $PF_6$, $NTf_2$, Cl). Utilizing the hydrophobic bmim-based RTILs, [bmim]X (X = $SbF_6$, $PF_6$, $NTf_2$) and a phase separation technique, we were able to produce white and opaque membranes with a three-dimensional structure closely packed with particles ($10-50{\mu}m$ in diameter). The particlulate structure, made by the assistance of [bmim]$NTf_2$ and DCM, interestingly transformed to a fibrous structure by using a cosolvent, e.g., DCM/$CF_3CH_2OH$. When we used an increased amount of [bmim]$NTf_2$, the particles were effectively detached and macrosized ($100-500{\mu}m$ in diameter) and the oval-shaped beads were obtained in a powder form. By varying the counter-anion type of the imidazolium-based RTIL, for example from $NTf_2^-$ to $Cl^-$, the particulate 3D-morphology was once more transformed to a porous structure. These reserch results could be potentially useful, as a method to fabricate particulate scaffolds, fibrous or porous scaffolds, and beads as a biopolymer device in diverse fields including drug delivery, tissue regeneration, and biomedical engineering.

Joint properties and Interface Analysis of Friction Stir Welded Dissimilar Materials between Austenite Stainless Steel and 6013 Al Alloy (마찰교반접합한 오스테나이트계 스테인리스강과 6013알루미늄 합금 이종 접합부의 접합 특성 및 계면 성질)

  • Lee, Won-Bae;Biallas, gehard;Schmuecker, Martin;Jung, Seung-Boo
    • Journal of Welding and Joining
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    • v.23 no.5
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    • pp.61-68
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    • 2005
  • Dissimilar joining of Al 6013-T4 alloys and austenite stainless steel was carried out using friction stir welding technique. Microstructures near the weld zone and mechanical properties of the joint have been investigated. Microstructures in the stainless steel side were composed of the heat affected zone and the plastically deformed zone, while those in the Al alloy side were composed of the recrystallized zone including stainless steel particles, the thermo-mechanically affected zone and the heat affected zone. TEM micrographs revealed that the interface region was composed of the mixed layers of elongated stainless steel and ultra-fine grained Al alloy with lamella structure and intermetallic compound layer. Thickness of the intermetallic layer was approximately 300nm and was identified as the A14Fe with hexagonal close packed structure. Mechanical properties, such as tensile and fatigue strengths were lower than those of 6013 Al alloy base metal, because tool inserting location was deviated to Al alloy from the butt line, which resulted in the lack of the stirring.

Density control of ZnO nanorod arrays using ultrathin seed layer by atomic layer deposition

  • Shin, Seokyoon;Park, Joohyun;Lee, Juhyun;Choi, Hyeongsu;Park, Hyunwoo;Bang, Minwook;Lim, Kyungpil;Kim, Hyunjun;Jeon, Hyeongtag
    • Journal of Ceramic Processing Research
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    • v.19 no.5
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    • pp.401-406
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    • 2018
  • We investigated the effect of ZnO seed layer thickness on the density of ZnO nanorod arrays. ZnO has been deposited using two distinct processes consisting of the seed layer deposition using ALD and subsequent hydrothermal ZnO growth. Due to the coexistence of the growth and dissociation during ZnO hydrothermal growth process on the seed layer, the thickness of seed layer plays a critical role in determining the nanorod growth and morphology. The optimized thickness resulted in the regular ZnO nanorod growth. Moreover, the introduction of ALD to form the seed layer facilitates the growth of the nanorods on ultrathin seed layer and enables the densification of nanorods with a narrow change in the seed layer thickness. This study demonstrates that ALD technique can produce densely packed, virtually defect-free, and highly uniform seed layers and two distinctive processes may form ZnO as the final product via the initial nucleation step consisting of the reaction between $Zn^{2+}$ ions from respective zinc precursors and $OH^-$ ions from $H_2O$.

A Study on API Wrapping in Themida and Unpacking Technique (Themida의 API 난독화 분석과 복구방안 연구)

  • Lee, Jae-hwi;Han, Jaehyeok;Lee, Min-wook;Choi, Jae-mun;Baek, Hyunwoo;Lee, Sang-jin
    • Journal of the Korea Institute of Information Security & Cryptology
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    • v.27 no.1
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    • pp.67-77
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    • 2017
  • A protector is a software for protecting core technologies by using compression and encryption. Nowadays malwares use the protector to conceal the malicious code from the analysis. For detailed analysis of packed program, unpacking the protector is a necessary procedure. Lately, most studies focused on finding OEP to unpack the program. However, in this case, it would be difficult to analyze the program because of the limits to remove protecting functions by finding OEP. In this paper, we studied about the protecting functions in the Themida and propose an unpacking technique for it.

Structural Formulation of As-grown Vertically Aligned Nanostructures to Multifunctional Thin-Film Frameworks through Controlled Mechanical Rolling (기계적 롤링을 통한 수직배향 나노구조의 다용도 박막 프레임워크 변환)

  • Park, Tae Jun;Choi, Seok Min;Youn, Do Kyung;Lee, Seungjo;Park, Jaekyu;Lee, Jae Hyuk;Kim, Jeong Dae;Lee, Han Kil;Ok, Jong G.
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.25 no.4
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    • pp.266-270
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    • 2016
  • We present a useful and practical manufacturing technique that enables the structural conversion of delicate as-grown nanostructures to more beneficial and robust thin-film frameworks through controlled mechanical rolling. Functional nanostructures such as carbon nanotubes grown through chemical vapor deposition in a vertically aligned and very loosely packed manner, and thus difficult to manipulate for subsequent uses, can be prepared in an array of thin blades by patterning the growth catalyst layer. They can then be toppled as dominos through precisely controlled mechanical rolling. The nanostructures formulated to horizontally aligned thin films are much more favorable for device applications typically based on thin-film configuration. The proposed technique may broaden the functionality and applicability of as-grown nanostructures by converting them into thin-film frameworks that are easier to handle and more durable and favorable for fabricating thin-film devices for electronics, sensors, and other applications.

A Study on Machine Learning Based Anti-Analysis Technique Detection Using N-gram Opcode (N-gram Opcode를 활용한 머신러닝 기반의 분석 방지 보호 기법 탐지 방안 연구)

  • Kim, Hee Yeon;Lee, Dong Hoon
    • Journal of the Korea Institute of Information Security & Cryptology
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    • v.32 no.2
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    • pp.181-192
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    • 2022
  • The emergence of new malware is incapacitating existing signature-based malware detection techniques., and applying various anti-analysis techniques makes it difficult to analyze. Recent studies related to signature-based malware detection have limitations in that malware creators can easily bypass them. Therefore, in this study, we try to build a machine learning model that can detect and classify the anti-analysis techniques of packers applied to malware, not using the characteristics of the malware itself. In this study, the n-gram opcodes are extracted from the malicious binary to which various anti-analysis techniques of the commercial packers are applied, and the features are extracted by using TF-IDF, and through this, each anti-analysis technique is detected and classified. In this study, real-world malware samples packed using The mida and VMProtect with multiple anti-analysis techniques were trained and tested with 6 machine learning models, and it constructed the optimal model showing 81.25% accuracy for The mida and 95.65% accuracy for VMProtect.

Removal of NAPL from Aquifer Using Surfactant-enhanced Air Sparging at Elevated Temperature (승온조건의 SEAS(surfactant-enhanced air sparging) 기술을 이용한 대수층 NAPL(n-decane)의 휘발제거)

  • Song, Young-Su;Kwon, Han-Joon;Kim, Heon-Ki
    • Journal of Soil and Groundwater Environment
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    • v.14 no.6
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    • pp.87-94
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    • 2009
  • Surfactant-enhanced air sparging (SEAS) was developed to suppress the surface tension of groundwater prior to air sparging resulting in higher air saturation and larger contact area between NAPL and gas during air sparging. Larger contacting interface between NAPL and gas means faster mass transfer of contaminants from NAPL to gas phase. This new technique, however, is limited to relatively volatile contaminants because vaporization is its basic mechanism of mass transfer. In this study, SEAS was tested at an elevated temperature for a semi-volatile n-decane, which is expected not to be a good candidate of SEAS application due to its low vapor pressure at ambient temperature. Three sparging experiments were conducted using 1-dimensional column (5 cm id, 80 cm length) packed with sand; (1) ambient temperature ($23^{\circ}C$), column saturated with distilled water, (2) SEAS at ambient temperature ($23^{\circ}C$), for n-decane contaminated sand, (3) SEAS at elevated temperature ($73^{\circ}C$), for n-decane contaminated sand. Higher air saturation was achieved by SEAS compared to that by air sparging without surfactant application. The n-decane removal efficiency of SEAS at elevated temperature was significantly higher(> 10 times) than that of ambient SEAS. The n-decane concentrations in the gas effluent from column during SEAS at $73^{\circ}C$ are found to be 10 times of those measured at ambient temperature. Thus, SEAS technique can be applied for removal of semi-volatile contaminants provided that an appropriate technique for elevating aquifer temperature is available.

Improvement of a Planning Technique Based on Heuristic Target Shaping for Stereotactic Radiosurgery (방사선 수술시 경험적 표적 근사화에 근거한 최적화 방법 개선)

  • Oh Seungjong;Choi Kyoung-Sik;Song Ju-Young;Suh Tae-Suk
    • Progress in Medical Physics
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    • v.16 no.4
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    • pp.176-182
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    • 2005
  • Stereotactic radiosurgery (SRS) is a technique to deliver a high dose to a target region and a low dose to a critical organ through only one or a few irradiation. The SRS must be planned exactly. Currently the surgery plan is peformed by trial and error method. There are many questions about the reliability and reproducibility of the plan result. This study Improve each step of the Oh's method based on heuristic target shaping to obtain the better result. The target was reconstructed using cylinders with same height and the neighbored cylinders were combined according to the difference of each center and diameter. Then, spheres were packed within each cylinders by the packing rules. Two virtual targets were used to compare this method with Oh's method. As a result, the numbers of isocenter were successfully reduced - more than $35\%$ and $26\%$ - without serious differences of proscription isodose to tumour volume ratio (PITV) and maximum dose to proscription dose ratio (MDPD). This technique using cylinder piling and sphere packing will be a helpful tool to planner in stereotactic radiosurgery.

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