• Title/Summary/Keyword: P solubility

Search Result 940, Processing Time 0.031 seconds

Geochemistry of Cu-Pb-Zn-Ag Deposits from the Euiseong Mineralized Area (의성 광화대 동-연-아연-은 광상의 지화학적 연구)

  • Chi, Se-Jung;Doh, Seong-Jae;Choi, Seon-Gyu;Lee, Jae-Ho
    • Economic and Environmental Geology
    • /
    • v.22 no.3
    • /
    • pp.253-266
    • /
    • 1989
  • The Cu-Pb-Zn-Ag hydrothermal vein type deposits which comprise the Dongil and Dong-cheogogsan mines occur within the Cretaceous sedimentary rocks in the Euiseong Basin of the southern Korean peninsula. The ore mineralization is contained within three stage(I,II and III) quartz and calcite veins. Ore minerals occur as dominant chalcopyrite, galena, sphalerite, tetrahedrite and Pb, Ag, Sb and Bi-bearing sulfosalts. Stage I ore minerals were deposited between $400^{\circ}C$ and $200^{\circ}C$ from the fluid with moderate salinities(7.0 to 4.5 eq. wt. % NaCl). Evidence of boiling suggests pressure of less than 150 bars during stage I mineralization. This pressure corresponds to maximum depths of 650 m and 1700 m, respectively, assuming lithostatic and hydrostatic loads. The data on mineralogy, temperature and salinity, together with information on the solubility of Cu complex, suggest that Cu deposition is a result of boiling coupled with declining temperature from $350^{\circ}$ to $250^{\circ}C$ or declining log $a_{o_2}$(from -29.8 to -35.9 atm.)and increasing in pH. Pb, Ag, Sb and Bi-bearing sulfosalts were deposited by cooling and dilution at temperature of less than $250^{\circ}C$ from the ore fluid with less than -35.9 atm. of log $a_{o_2}$.

  • PDF

Toxic Effects of Aluminium on Freshwater Animals: Review (알루미늄이 수생동물에 미치는 독성에 관한 소고)

  • Park, Chan Jin;Kim, Dae Han;Han, Sang Ho;Gye, Myung Chan
    • Korean Journal of Environmental Biology
    • /
    • v.32 no.4
    • /
    • pp.271-285
    • /
    • 2014
  • Aluminum flows into the river from the abandoned mine leachate, industrial wastewater, and sewage and is responsible for acute toxicity in aquatic organisms. Recently, the number of reports have indicated the increased toxicity in a variety of aquatic organisms' due to the aluminum toxicity. In this study, we reviewed the toxicity of aluminum on aquatic invertebrates, fishes and amphibians and suggested the guideline for management of aluminum residues in aquatic environment and strategies for aluminum toxicity evaluation. In aquatic animals aluminum complexes evoke gill dysfunction primarily, the cytotoxicity, genotoxicity, oxidative stress, disruption of endocrine function, reproductive success, metabolism and homeostasis. Notably, at environmentally relevant concentration, aluminum complex can alter the hormone levels in fish in acidic condition. Further, since the solubility of aluminum is higher in the acidic and basic conditions, thus it is likely that the toxic effects of aluminum may not only occur in acidic water near the abandoned mines but also in lakes and rivers, where pH is raised by algal bloom.

Effect of Soaking on Expansion Volune of Gang Jung (찹쌀의 수침이 강정의 팽화부피에 미치는 영향)

  • Park, Young-Mee;Oh, Myung-Suk
    • Korean Journal of Food Science and Technology
    • /
    • v.17 no.6
    • /
    • pp.415-420
    • /
    • 1985
  • In this study, changes in physical and chemical properties of glutinous rice during various soaking periods (0, 0.08, 1, 3, 5, 7, 10 days) were investigated in order to clarify the relations ship between soaking period and expansion volume in the preparation of Gang Jung. The longer the soaking period was, the greater the expansion volume of Gang Jung was. Higher maximum viscosity and breakdown in amylogram of glutinous rice flour were observed as the soaking period was increased, As the length of soaking period increased, hardness of glutinous rice and size of flour particle significantly decreased, while sweeling power and solubility of glutinous rice flour showed no significant difference. Increased length of soaking period was associated with higher fatty acidity, higher acidity of water extract and lower pH of glutinous rice flour. Control of flour particle size distribution resulted in significantly larger expansion volume of Gang Jung. Brabender's amylogram showed that the increase of expansion volume of Gang Jung associated with the increase of soaking period was related to the change of rheological properties of glutinous rice. It seemed that changes in viscometric properties of glutinous rice was attributed to the different flour particle size distribution resulted from changes in hardness of rice during soaking.

  • PDF

Enhancement of Manganese Removal Ability from Water Phase Using Biochar of Prinus densiflora Bark (소나무 수피 바이오차를 이용한 수중에서 망간의 제거능력 향상)

  • Kim, Min-Ji;Choi, Jung Hoon;Choi, Tae Ryeong;Choi, Suk Soon;Ha, Jeong Hyub;Lee, Young-Seak
    • Applied Chemistry for Engineering
    • /
    • v.31 no.5
    • /
    • pp.526-531
    • /
    • 2020
  • Manganese ions contained in water phase are acting as a toxic substance in the human body and also known to affect the nervous system. In particular, effective treatment technology is required since manganese removal is difficult due to its high solubility in a wide pH range. In this study, Prinus densiflora bark was chemically modified with hydrogen peroxide, and the modified adsorbent was used for removing manganese ions in an aqueous solution. The modified adsorbent showed high removal capacity of 82.1 and 56.2%, respectively, at conditions of 5 and 10 mg/L manganese ions. Also, the adsorption isotherm from the data was applied to the theoretical equation. As a result, the adsorption behavior of manganese ions was better suited to the Langmuir than Freundlich model, and it was also found from kinematics that the pseudo-second order kinetic model was more suitable. In addition, the changes of Gibbs free energy indicated that the adsorption reaction became more spontaneously with increasing temperature. Consequently, these experimental results may be used as a water treatment technology which can efficiently treat manganese ions contained in water.

Novel Quinazoline Derivatives Targeting on EGFR Kinase Mediated Signal Pathway in A431 Human Epidermoid Carcinoma Cells (A431 피부암세포의 EGFR kinase 신호체계에 선택적으로 작용하는 새로운 퀴나졸린계 억제제)

  • Jeong, Chul-Woo;Son, Byeng-Wha;Ha, Jae-Du;Kim, Gun-Do
    • Journal of Life Science
    • /
    • v.21 no.3
    • /
    • pp.349-357
    • /
    • 2011
  • Inhibitors of EGFR (epidermal growth factor receptor) kinase activity may prove useful to therapeutically intervene in cancer and to treat other proliferative diseases. In this study, we investigated the inhibitive effects of two compounds named 63013 and 63033 possess a [1,4]-dioxino quinazoline structure that links the alkoxy side chains together and their structural characteristics are considered to allow better solubility than the dialkoxyquinazoline derivatives. The EGFR kinase activities of A431 human epidermoid carcinoma cells, stimulated by EGF were inhibited by treatment with 63013 and 63033 in a dose-dependent manner respectively. Consistent with the compound-mediated EGFR kinase suppression, the major EGF-related downstream target molecules, such as MEK1/2, MAPK p44/42, AKT and STAT3, were also suppressed by both compounds. Interestingly, both compounds led to cell growth inhibition at a lower concentration than that of Gefitinib (Iressa$^{(R)}$). Collectively, our study showed that both compounds may have good therapeutic potential as an EGFR kinase specific inhibitor to treat EGFR-related diseases.

Effect of Feeding Dietary Oils on Physico-Chemical Changes of Pork during Storage (오일 급여가 돈육의 저장 중 물리ㆍ화학적 변화에 미치는 영향)

  • 진상근;김일석;송영민;정기화;이성대;김희윤;남기윤;하경희;강양수
    • Food Science of Animal Resources
    • /
    • v.23 no.3
    • /
    • pp.227-235
    • /
    • 2003
  • The results were obtained from pigs which had been fed finishing pig diets containing 5% beef tallow(C) as control and 2% perilla seed oil(Tl), 3% beef tallow and 2% squid viscera oil(T2), 3% beef tallow and 2% CLA(conjugated linoleic acid, T3). All porks were stored at 1$^{\circ}C$ for 28 days. pH value of control group was higher than other treatments. Water holding capacity(WHC) did not show any significant difference among treatments, however, WHC of C and T3 was increased as storage days increased. Protein solubility of T3 was higher than the other treatments, but that of all groups increased up to 14 days of storage and then decreased. The a* value of C was higher than the others, but b* value was low on 28 days of storage. Volatile base nitrogen(VBN) value of T3 showed the highest level, but that of Tl was the lowest. Thiobarbituric acid reactive substances(TBARS) of T2 and T3 were' higher than those of C and Tl. In sensory analysis, meat color and overall acceptability of C were higher than those of the other treatments in raw meat, and meat appearance was higher than level in Tl.

Water Reuse of Sewage Discharge Water Using Fertilizer Drawn Forward Osmosis - Evaluating the Performance of Draw Solution - (비료 유도용액의 정삼투를 이용한 하수처리수의 재이용 - 유도용액의 성능 평가 -)

  • Kim, Seung-Geon;Lee, Ho-Won
    • Membrane Journal
    • /
    • v.26 no.2
    • /
    • pp.108-115
    • /
    • 2016
  • This study is to evaluate the performance of draw solutions in the water reuse of sewage discharge water using fertilizer drawn forward osmosis. Feed water used in all experiments was the effluent from secondary sedimentation tank in activated sludge process. Considering osmotic pressure, solubility, and pH, $NH_4H_2PO_4$, KCl, $KNO_3$, $NH_4Cl$, $(NH_4)_2HPO_4$, $NH_4NO_3$, $NH_4HCO_3$, and $KHCO_3$ were screened from a comprehensive lists of fertilizer. Their performances were evaluated in terms of water permeate flux and reverse solute flux. KCl showed the highest average water flux followed by $NH_4Cl$, $NH_4NO_3$, $KNO_3$, $KHCO_3$, $NH_4HCO_3$, $NH_4H_2PO_4$, and $(NH_4)_2HPO_4$. Using KCl as draw solution, the average water permeate flux was 13.49 LMH. There was no big difference in osmotic pressure between the effluent from secondary sedimentation tank and deionized water. $NH_4H_2PO_4$ showed the lowest reverse solute flux followed by $NH_4Cl$, $(NH_4)_2HPO_4$, $KNO_3$, $NH_4HCO_3$, and $NH_4NO_3$. Using $NH_4H_2PO_4$ as draw solution, the reverse solute flux was $4.96{\times}10^{-3}mmol/m^2{\cdot}sec$.

Quality Characteristics of Domestic Strong Wheat Flour (시판 강력분 우리밀의 품질 특성)

  • Kwak, Han Sub;Kim, Mi Jeong;Kim, Oui-Woung;Kim, Sang Sook
    • Journal of the Korean Society of Food Science and Nutrition
    • /
    • v.46 no.5
    • /
    • pp.616-621
    • /
    • 2017
  • The objective of this study was to investigate the physicochemical properties of domestic strong wheat flour (DSWF). Three commercial DSWFs (D1, D2, and D3) were compared with imported strong wheat flour (ISWF). DSWFs had higher moisture content, crude protein content, lightness, and whiteness than ISWF. DSWFs showed lower solvent retention capacity and water absorption index than ISWF. DSWFs also showed significantly higher water solubility index than ISWF (P<0.05). Setback values by rapid visco analysis were significantly higher in D1 and D2 than in ISWF and D3, which means ISWF and D3 were better in retarding retrogradation. Differential scanning calorimetry results showed that ISWF required 6.2 J/g of energy for phase transition, whereas DSWFs needed 6.67~7.13 J/g. The farinograph results showed that ISWF had higher water absorption, longer dough stability time, and significantly higher softening of dough at 20 min than DSWF (P<0.05). Dough resistance and extensibility were higher in ISWF than in DSWFs.

Enzymatic Modification of Soy Proteins: Effects of Functional Properties of Soy Isolate upon Proteolytic Hydrolysis (대두단백질(大豆蛋白質)의 효소적(酵素的) 변형(變形) : 분리대두단백질(分離大豆蛋白質)의 기능성(機能性)에 미치는 단백질가수분해(蛋白質加水分解)의 영향(影響))

  • Kang, Yeung-Joo
    • Korean Journal of Food Science and Technology
    • /
    • v.16 no.2
    • /
    • pp.211-217
    • /
    • 1984
  • To study affinity of proteolytic enzymes to soy proteins, the physicochemical and functional properties of enzymatically modified protein products, kinetic parameters and degree of hydrolysis were measured using trypsin, alcalase (serine type protease) and pronase. Bacterial alcalase and pronase showed much greater affinity to soy protein than animal intestinal trypsin. This effect was very significant when unheated soy isolate was used as a substrate. Specific activities of these enzymes decreased with the increment of substrate concentration (over 2.0%, w/v) when heat denatured soy protein was used as a substrate. However, the decrease in specific activity was negligible at substrate concentrations lower than 2.0%. Polyacrylamide gel electrophoretic results showed that the pattern of 2S protein band changed distinctly in alcalase hydrolysis as compared with those of trypsin and pronase. Protein solubilities of alcalase and pronase hydrolyzates increased by 25-30%, at their pI (pH 5.0) over the control. Virtually no change was observed in solubility by trypsin hydrolysis. Heat coagulability and calcium-tolerance of the protein increased by enzymatic hydrolysis. No clear tendency, however, was observed for emulsion properties, foam expansion and the amount of free -SH groups. The enzyme treatment considerably decreased foam stability.

  • PDF

THE EFFECT OF ETHYLENE GLYCOL ANALOGS ON MECHANICAL PROPERTIES OF MOIST DEMINERALIZED DENTIN MATRIX (Ethylene Glycol 유사체가 탈회된 상아질의 물리적 성질에 미치는 영향)

  • Lee Kyung-Hee;Cho Young-Gon;Lee Kwang-Won
    • Restorative Dentistry and Endodontics
    • /
    • v.31 no.4
    • /
    • pp.290-299
    • /
    • 2006
  • Objectives: The purpose of this study is to evaluate the effect of ethylene glycol analogs on modulus of elasticity and ultimate tensile strength of moist, demineralized dentin matrix. Methods: Dentin disks 0.5 mrn thick were prepared from mid-coronal dentin of extracted. unerupted, human third molars. 'I' beam and hour-glass shaped specimens were prepared from the disks, the ends protected with nail varnish and the central regions completely demineralized in 0.5M EDTA for 5 days. Ultimate tensile stress (UTS) and low strain modulus of elasticity (E) were determined with specimens immersed for 60 min in distilled water $(H_{2}O)$, ethylene glycol $(HO-CH_{2}-CH_{2}-OH)$, 2-methoxyethanol $(H_{3}CO-CH_{2}-CH_{2}-OH)$, and 1,2-dimethoxyethane $(H_{3}CO-CH_{2}-CH_{3}-OCH_{3})$ prior to testing in those same media. Modulus of elasticity was measured on the same specimens in a repeated measures experimental design. The results were analyzed with a one-way ANOVA on ranks, followed by Dunn's test at ${\alpha}\;=\;0.05$. Regression analysis examined the relationship between UTS or E and hoy's solubility parameter for hydrogen bonding $({\delta}_{h})$ of each solvent. Results: The UTS of demineralized dentin in water, ethylene glycol, 2-methoxyethanol, and 1,2-dimethoxyethane was 24 (3), 30 (5), 37 (6), and 45 (6) MPa, ${\times}$ (SD) N = 10. Low strain E for the same media were 16 (13), 23 (14), 52 (24), and 62 (22) MPa. Regression analysis of UTS vs ${\delta}_{h}$ revealed a significant $(p\;<\;0.0001,\;r\;=\;-0.99,\;R^{2}\;=\;0.98)$ inverse, exponential relationship. A similar inverse relationship was obtained between low strain E vs ${\delta}_{h}\;(p\;<\;0.0005,\;r\;=\;-0.93,\;R^{2}\;=\;0.86)$. Significance: The tensile properties of demineralized dentin are dependent upon the hydrogen bonding ability of polar solvents $({\delta}_{h})$. Solvents with low ${\delta}_{h}$ values may permit new interpeptide H-bonding in collagen that increases its tensile properties. Solvents with high ${\delta}_{h}$ values prevent the development of these new interpeptide H-bonds.