• Journal of the Korean Graphic Arts Communication Society
• /
• v.6 no.1
• /
• pp.67-74
• /
• 1988

Absorption rates of oxygen in water soluble inks on the printing rollers were measured. As a results of experiments, could be obtained the data of rates of absorption of oxygen in 4 kinds of water soluble inks, and found the difference of absorption rate of oxygen on the parallel plates and rotating rolles.

• Journal of the Korean institute of surface engineering
• /
• v.45 no.4
• /
• pp.174-180
• /
• 2012

Low pressure inductively coupled plasma characteristics of argon and oxygen are numerically simulated for a 400 mm rectangular type system with a plasma fluid model. The results showed lower power absorption profile at the corner than a circular one in a 13.56 MHz driven 1.5 turn antenna system with a drift-diffusion and quasi-neutrality assumption. Ions controlled by electric field are more non-uniform than metastables and the power absorption profile of oxygen plasma is affected by horizontal gas flow pattern to show 25% lower power absorption at the pumping flange side. Oxygen negative ions which are generated in electron collisional dissociation of oxygen molecules was calculated as 0.1% of oxygen atoms with similar spatial profile.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.13 no.6
• /
• pp.2479-2483
• /
• 2012

This paper discusses the development of a personal compact oxygen generator for portable and mobility. The compact oxygen generator is operated with vacuum swing absorption by compact vacuum pump. The components of oxygen generator is composed on the miniaturization and weight reduction, and it is optimized by discharge pump speed, nozzle diameter and 3-way valve interval. In 0.5mm of nozzle diameter, $O_2$ concentration is approximately 37%, and flow rate is $1{\ell}$/min. On the 30cm away from the nozzle, $O_2$ concentration is increased approximately 0.5%.

• Journal of the Korean Society of Combustion
• /
• v.17 no.1
• /
• pp.12-21
• /
• 2012

Simultaneous measurements of oxygen concentration and temperature using diode laser in the combustion environment are successfully accomplished. A single DFB type diode laser of 760 nm line centre frequency is used and the scanned-wavelength direct absorption spectroscopy method and wavelength modulation spectroscopy method are applied to measure absorption signals below 793 K temperature region. The experimental results show that oxygen concentration are measured within 1% accuracy and temperature are measured within 5% accuracy. This new method of simultaneous measurements of concentration and temperature with a single diode laser shows a great promise.

• Journal of the Korean Vacuum Society
• /
• v.4 no.2
• /
• pp.194-200
• /
• 1995

2-3nm의 공간분해능을 갖는 전자에너지손실분광법(Electron Energy Loss Spectroscopy, EELS)을 이용하여, 전기적 특성조사된 YBa2Cu3O7-$\delta$ 고온초전도체 쌍결정의 결정경계(grain boundary)에서 산소의 조성변화를 조사하였다. Misorientation angle이 $14^{\circ}$, $28^{\circ}$,$ 30^{\circ}$인 3개의 쌍결정 중에서 Josephson junction 특성을 보인 $28^{\circ}$ 및 $30^{\circ}$결정경계에서의 oxygen 1s absorption edge는 결정내부에서의 oxygen 1s absorption edge와 매우 다름을 알 수 있었다. 이는 결정경계에서의 산소조성이 결정내부에 비해 낮음을 의미하며, 그 영역이 결정경계 부근 20-40nm로, coherence length에 비해 큼을 알 수 있다. 반면에, flux pinningxmr성을 보인 $14^{\circ}$결정경계에서의 oxygen 1s absorption edge는 결정내부에서와 별 차이를 보이지 않았다. 따라서 일반적으로 관찰되어온, misorientation angle이 큰 결정경계에서의 Josephson junction 특성은 결정경계 부근에서 산소의 조성이 낮아지는데에 기인하며, 그 원인은 결정경계면을 통해 산소가 out-diffusion되기 때문인 것으로 생각된다.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2013.02a
• /
• pp.398-398
• /
• 2013

The electronic properties and the local structure of tantalum oxide thin film with variation of oxygen flow rate ranging from 9.5 to 16 sccm (standard cubic centimeters per minute) have been investigated by X-ray photoelectron spectroscopy (XPS), Reflection Electron Energy Loss Spectroscopy (REELS), and X-ray absorption spectroscopy (XAS). The XPS results show that the Ta4f spectrum for all films consist of the strong spin-orbit doublet $Ta4f_{7/2}$ and $Ta4f_{5/2}$ with splitting of 1.9 eV. The oxygen flow rate of the film results in the appearance of new features in the Ta4f at binding energies of 23.2 eV, 24.4 eV, 25.8, and 27.3 eV, these peaks attribute to $Ta^{1+}$, $Ta^{2+}$, $Ta^{4+}$/$Ta^{2+}$, and $Ta^{5+}$, respectively. Thus, the presence of non-stoichiometric state from tantalum oxide ($TaO_x$) thin films could be generated by the oxygen vacancies. The REELS spectra suggest the decrease of band gap for tantalum oxide thin films with increasing the oxygen flow rate. The absorption coefficient ${\mu}$ and its fine structure were extracted from the fluorescence mode of extended X-ray absorption fine structure (EXAFS) spectra. In addition, bond distances (r), coordination numbers (N) and Debye-Waller factors (${\sigma}^2$) each film were determined by a detailed of EXAFS data analysis. EXAFS spectrapresent both the increase of coordination number of the first Ta-O shell and a considerable reduction of the Ta-O bond distance with the increase of oxygen flow rate.

• Journal of the Korean Graphic Arts Communication Society
• /
• v.7 no.1
• /
• pp.16-30
• /
• 1989

The anodixed aluminium film by sulfuric acid - method has many pores, the inner, called barrier layers, is active. They have strong absorption of dye. on be other, the absorption of dye is lost by Sealing, the surface is not dyed. We make IMAGE FORMATION on the film by the chemical behavior. This study made sure whether ion absorption is not in the barrier layer by IRRS and ESCA, considerated the mechanism of inage formation.

• Journal of the Korean Ceramic Society
• /
• v.40 no.11
• /
• pp.1102-1105
• /
• 2003

The fiber drawing process induced defects in silica fiber have been investigated. This study has focused on the Oxygen Deficient Centers (ODCs) and E' centers induced by the fiberization process in low-OH silica fibers. To investigate those defects induced by the fiberization process, the optical absorption spectrum and Electron Spin Resonance (ESR) have both been employed. The concentration of Oxygen Deficient Centers (ODCs) and E' centers are increased by the fiber drawing process. The population of defects in the neck-down region has also been investigated. The most significant generation of defects during fiber drawing process has been shown to occur in this region of silica preform. The population of defects is higher on the edge region than in the center of neck-down region.

• Journal of the Korean institute of surface engineering
• /
• v.29 no.6
• /
• pp.660-665
• /
• 1996

Thin films of indium oxide and indium tin oxide have been prepared by d.c. magnetron sputtering onto the fused silica substrates kept at 90, 200 and $300^{\circ}C$. In order to elucidate the optical absorption process in low energy region below 3 eV, we have analyzed the absorption coefficients obtained from reflectance and transmittance measurements for these films based on the Lucovsky model. It has been found for the first time that a defect center in the band gap is located at 0.8~1.4 eV below the Fermi level in all films and arises from oxygen vacancies in their films. The optical absorption in low energy region is explained to be dominated by the transition of electrons trapped at the positively charged (+2e) oxygen vacancies with s-like nature to the conduction band formed from the 5s-orbit in indium atoms.

• Journal of Electrochemical Science and Technology
• /
• v.1 no.1
• /
• pp.31-38
• /
• 2010

In this study, we have demonstrated the fine structure effect of PdCo electrocatalyst on oxygen reduction reaction activity with different alloy composition and heat-treatment time. In order to identify the intrinsic factors for the electrocatalytic activity, various X-ray analyses were used, including inductively coupled plasma-atomic emission spectrometer, transmission electron microscopy, X-ray diffractometer, and X-ray Absorption Spectroscopy technique. In particular, extended X-ray absorption fine structure was employed to extract the structural parameters required for understanding the atomic distribution and alloying extent, and to identify the corresponding simulated structures by using FEFF8 code and IFEFFIT software. The electrocatalytic activity of PdCo alloy nanoparticles for the oxygen reduction reaction was evaluated by using rotating disk electrode technique and correlated to the change in structural parameters. We have found that Pd-rich surface was formed on the Co core with increasing heating time over 5 hours. Such core shell structure of PdCo/C showed that a superior oxygen reduction reaction activity than pure Pd/C or alloy phase of PdCo/C electrocatalysts, because the adsorption energy of adsorbates was apparently reduced by lowering the dband center of the Pd skin due to a combination of the compressive strain effect and ligand effect.