• Title/Summary/Keyword: Oxide nuclear fuel

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Core Size Effects on Safety Performances of LMRs

  • Na, Byung-Chan;Dohee Hahn
    • Proceedings of the Korean Nuclear Society Conference
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    • 1997.10a
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    • pp.645-650
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    • 1997
  • An oxide fuel small size core (1200 MWt) was analyzed in comparison with a large size core (3600 MWt) in order to evaluate the size effects on transient safety performances of liquid-metal reactors (LMRs). in the first part of the study, main static safety parameters (i.e., Doppler coefficient, sodium void effect, etc.) of the two cores were characterized, and the second part of the study was focused on the dynamic behavior of the cores in two representative transient events: the unprotected loss-of-flow(ULOF) and the unprotected transient overpower (UTOP). Margins to fuel molting and sodium boiling have been evaluated for these representative transients. Results show that the small core has a generally better or equivalent level of safety performances during these events.

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Benchmark Calculations of Lattice Codes for the Doppler Coefficient of MOX Fuel

  • Shin, Ho-Cheol;Bae, Sung-Man;Kim, Yong-Bae;Lee, Sang-Hee
    • Proceedings of the Korean Nuclear Society Conference
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    • 1996.05a
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    • pp.46-51
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    • 1996
  • In this study we calculate the infite multiplication factors ($k_{\infty}$) and the Doppler temperature coefficients (DTC) of two mixed-oxide (MOX) fuel rods with different plutonium contents by using PHOENIX-P, HELIOS and CASMO-3 codes. The results were compared against the reference values obtained by MCNP-3A continuous-energy Monte Carlo code. The purpose of this study is to benchmark the accuracy of these lattice codes. The PHOENIX-P's Doppler coefficients calculated were in good agreement with the MCNP results within the Monte-Carlo uncertainty band which is in the order of $\pm$ 10% for the Doppler coefficients..

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Analysis of Core Disruptive Accident Energetics for Liquid Metal Reactor

  • Suk, Soo-Dong;Dohee Hahn
    • Nuclear Engineering and Technology
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    • v.34 no.2
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    • pp.117-131
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    • 2002
  • Core disruptive accidents have been investigated at Korea Atomic Energy Research Institute(KAERI) as part of the work to demonstrate the inherent and ultimate safety of conceptual design of the Korea Advanced Liquid Metal Reactor(KALIMER), a 150 MWe pool- type sodium cooled prototype fast reactor that uses U-Pu-Zr metallic fuel. In this study, a simple method and associated computer program, SCHAMBETA, was developed using a modified Bethe-Tait method to simulate the kinetics and thermodynamic behavior of a homogeneous spherical core over the period of the super-prompt critical power excursion induced by the ramp reactivity insertion. Calculations of the energy release during excursions in the sodium-voided core of the KALIMER were subsequently performed using the SCHAMBETA code for various reactivity insertion rates up to 100 S/s, which has been widely considered to be the upper limit of ramp rates due to fuel compaction. Benchmark calculations were made to compare with the results of more detailed analysis for core meltdown energetics of the oxide fuelled fast reactor. A set of parametric studies were also performed to investigate the sensitivity of the results on the various thermodynamics and reactor parameters.

On the intra-granular behaviour of a cocktail of inert gases in oxide nuclear fuel: Methodological recommendation for accelerated experimental investigation

  • Romano, M.;Pizzocri, D.;Luzzi, L.
    • Nuclear Engineering and Technology
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    • v.54 no.5
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    • pp.1929-1934
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    • 2022
  • Besides recent progresses in the physics-based modelling of fission gas and helium behaviour, the scarcity of experimental data concerning their combined behaviour (i.e., cocktail) hinders further model developments. For this reason, in this work, we propose a modelling methodology aimed at providing recommendations for accelerated experimental investigations. By exploring a wide range of annealing temperatures and cocktail compositions with a physics-based modelling approach we identify the most interesting conditions to be targeted by future experiments. To corroborate the recommendations arising from the proposed methodology, we include a sensitivity analysis quantifying the impact of the model parameters on fission gas and helium release, in conditions representative of high and low burnup.

Electrochemical Reduction Process for Pyroprocessing (파이로프로세싱을 위한 전해환원 공정기술 개발)

  • Choi, Eun-Young;Hong, Sun-Seok;Park, Wooshin;Im, Hun Suk;Oh, Seung-Chul;Won, Chan Yeon;Cha, Ju-Sun;Hur, Jin-Mok
    • Korean Chemical Engineering Research
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    • v.52 no.3
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    • pp.279-288
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    • 2014
  • Nuclear energy is expected to meet the growing energy demand while avoiding CO2 emission. However, the problem of accumulating spent fuel from current nuclear power plants which is mainly composed of uranium oxides should be addressed. One of the most practical solutions is to reduce the spent oxide fuel and recycle it. Next-generation fuel cycles demand innovative features such as a reduction of the environmental load, improved safety, efficient recycling of resources, and feasible economics. Pyroprocessing based on molten salt electrolysis is one of the key technologies for reducing the amount of spent nuclear fuel and destroying toxic waste products, such as the long-life fission products. The oxide reduction process based on the electrochemical reduction in a LiCl-$Li_2O$ electrolyte has been developed for the volume reduction of PWR (Pressurized Water Reactor) spent fuels and for providing metal feeds for the electrorefining process. To speed up the electrochemical reduction process, the influences of the feed form for the cathode and the type of anode shroud on the reduction rate were investigated.

Experimental Observations for Anode Optimization of Oxide Reduction Equipment

  • David Horvath;James King;Robert Hoover;Steve Warmann;Ken Marsden;Dalsung Yoon;Steven Herrmann
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.20 no.4
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    • pp.383-398
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    • 2022
  • The electrochemical behavior was investigated during the electrolysis of nickel oxide in LiCl-Li2O salt mixture at 650℃ by changing several components. The focus of this work is to improve anode design and shroud design to increase current densities. The tested components were ceramic anode shroud porosity, porosity size, anode geometry, anode material, and metallic porous anode shroud. The goal of these experiments was to optimize and improve the reduction process. The highest contributors to higher current densities were anode shroud porosity and anode geometry.

The effect of cooling rates on carbide precipitate and microstructure of 9CR-1MO oxide dispersion strengthened(ODS) steel

  • Jang, Ki-Nam;Kim, Tae-Kyu;Kim, Kyu-Tae
    • Nuclear Engineering and Technology
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    • v.51 no.1
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    • pp.249-256
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    • 2019
  • The 9Cr-1Mo ferritic-martensitic ODS steel is a promising structural material for the next generation nuclear power plants including fast reactors for application in reactor vessels and nuclear fuel. The ODS steel was cooled down by furnace cooling, air cooling, oil quenching and water quenching, respectively, after normalizing it at $1150^{\circ}C$ for 1 h and then tempering at $780^{\circ}C$ for 1 h. It is found that grain size, a relative portion of ferrite and martensite, martensitic lath configuration, behaviors of carbide precipitates, and hardness of the ODS steel are strongly dependent on a cooling rate. The grain size and martensitic lath width become smaller with the increase in a cooling rate. The carbides were precipitated at the grain boundaries formed between the ferrite and martensite phases and at the martensitic lath interfaces. In addition, the carbide precipitates become smaller and more widely dispersed with the increase in a cooling rate, resulting in that the faster cooling rate generated the higher hardness of the ODS steel.

Physicochemical Property of Borosilicate Glass for Rare Earth Waste From the PyroGreen Process

  • Young Hwan Hwang;Mi-Hyun Lee;Cheon-Woo Kim
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.21 no.2
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    • pp.271-281
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    • 2023
  • A study was conducted on the vitrification of the rare earth oxide waste generated from the PyroGreen process. The target rare earth waste consisted of eight elements: Nd, Ce, La, Pr, Sm, Y, Gd, and Eu. The waste loading of the rare earth waste in the developed borosilicate glass system was 20wt%. The fabricated glass, processed at 1,200℃, exhibited uniform and homogeneous surface without any crystallization and precipitation. The viscosity and electrical conductivity of the melted glass at 1,200℃ were 7.2 poise and 1.1 S·cm-1, respectively, that were suitable for the operation of the vitrification facility. The calculated leaching index of Cs, Co, and Sr were 10.4, 10.6, and 9.8, respectively. The evaluated Product Consistency Test (PCT) normalized release of the glass indicated that the glass satisfied the requirements for the disposal acceptance criteria. Furthermore, the pristine, 90 days water immersed, 30 thermal cycled, and 10 MGy gamma ray irradiated glasses exhibited good compressive strength. The results indicated that the fabricated glass containing rare earth waste from the PyroGreen process was acceptable for the disposal in the repository, in terms of chemical durability and mechanical strength.

Economic evaluation of thorium oxide production from monazite using alkaline fusion method

  • Udayakumar, Sanjith;Baharun, Norlia;Rezan, Sheikh Abdul;Ismail, Aznan Fazli;Takip, Khaironie Mohamed
    • Nuclear Engineering and Technology
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    • v.53 no.7
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    • pp.2418-2425
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    • 2021
  • Monazite is a phosphate mineral that contains thorium (Th) and rare earth elements. The Th concentration in monazite can be as high as 500 ppm, and it has the potential to be used as fuel in the nuclear power system. Therefore, this study aimed to conduct the techno-economic analysis (TEA) of Th extraction in the form of thorium oxide (ThO2) from monazite. Th can be extracted from monazite through an alkaline fusion method. The TEA of ThO2 production studied parameters, including raw materials, equipment costs, total plant direct and indirect costs, and direct fixed capital cost. These parameters were calculated for the production of 0.5, 1, and 10 ton ThO2 per batch. The TEA study revealed that the highest production cost was ascribed to installed equipment. Furthermore, the highest return on investment (ROI) of 21.92% was achieved for extraction of 1 ton/batch of ThO2, with a payback time of 4.56 years. With further increase in ThO2 production to 10 ton/batch, the ROI was decreased to 5.37%. This is mainly due to a significant increase in the total capital investment with increasing ThO2 production scale. The minimum unit production cost was achieved for 1 ton ThO2/batch equal to 335.79 $/Kg ThO2.

Influence of Temperature on the Fretting Wear of Advanced Nuclear Fuel Cladding Tube against Supporting Grid (온도 상승이 개량형 핵연료 피복관과 지지격자 사이의 프레팅 마멸에 미치는 영향)

  • Lee Young-Ze;Park Yong-Chang;Jeong Sung-Hoon;Kim Jin-Seon;Kim Yong-Hwan
    • Tribology and Lubricants
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    • v.22 no.3
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    • pp.144-148
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    • 2006
  • The experimental investigation was performed to find the associated changes in characteristics of fretting wear with various water temperatures. The fretting wear tests were carried out using the zirconium alloy tubes and the grids with increasing the water temperature. The tube materials in water of $20^{\circ}C,\;50^{\circ}C\;and\;80^{\circ}C$ were tested with the applied load of 20 N and the relative amplitude of $200{\mu}m$. The worn surfaces were observed by SEM, EDX analysis and 2D surface profiler. As the water temperature increased, the wear volume was decreased, but oxide layer was increased on the worn surface. The abrasive wear mechanism was observed at water temperature of $20^{\circ}C$ and adhesive wear mechanism occurred at water temperature of $50^{\circ}C,\;80^{\circ}C$. As the water temperature increased, surface micro-hardness was decreased, but wear depth and wear width were decreased due to increasing stick phenomenon. Stick regime occurred due to the formation of oxide layer on the worn surface with increasing water temperatures