• Journal of Magnetics
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• 제12권3호
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• pp.103-107
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• 2007

Magnetic field induced structural transition has been systematically investigated for $La_{1-x}Ba_xMnO_3$ with the fine control of carrier doping $(0.15{\leq}x{\leq}0.20)$. Application of a magnetic field results in the suppression of the rhombohedral-orthorhombic transition temperature $(T_s)$ and the increase of insulator-metal transition temperature $(T_{MI})$. Near x = 0.17, where $T_S$ is similar to $T_{MI}$ at zero magnetic field, we found that the $T_S$ smoothly decreased with magnetic field even though it intersected the $T_{MI}$ near 3 T. Also, the magnetostructural phase diagram obtained from the temperature sweep and from the magnetic field sweep is not significantly modified. By comparing the magnetostructural transition in $La_{1-x}Sr_xMnO_3$, we have suggested that the large disorder originated from ionic size differences between La and Ba may weaken the sensitivity of the kinetic energy of $e_g$ electrons on the degree of lattice distortion in $La_{1-x}Ba_xMnO_3$.

• 한국전기전자재료학회논문지
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• 제24권8호
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• pp.632-635
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• 2011

Additions (ZnO, CuO) doped $0.98(Na_{0.5}K_{0.5})NbO_3-0.02Li(Sb_{0.17}Ta_{0.83})O_3$ (0.98NKN-0.02LST-x) lead free piezoelectric ceramics have been fabricated by ordinary sintering technique. The effects of additions doping on the dielectric, piezoelectric, and ferroelectric properties of the ceramics were mainly investigated. X-ray diffraction of the sample appeared orthorhombic phase. The specimen doped with additions exhibits enhanced electrical properties ($d_{33}$= 153 pC/N). These results indicate that the 0.98NKN-0.02LST-x ceramics is a promising candidate for lead-free piezoelectric ceramics for applications such as piezoelectric actuators, harmonic oscillator and so on.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2000년도 하계학술대회 논문집
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• pp.471-474
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• 2000

A flat type microgas sensor was fabricated on the p-type silicon wafer with low stress S $i_3$ $N_4$, whose thickness is 2${\mu}{\textrm}{m}$ using MEMS technology and its characteristics were investigated. W $O_3$thin film as a sensing material for detection of N $O_2$gas was deposited using a tungsten target by sputtering method, followed by thermal oxidation at several temperatures (40$0^{\circ}C$~$600^{\circ}C$) for one hour. N $O_2$gas sensitivities were investigated for the W $O_3$thin films with different annealing temperatures. The highest sensitivity when operating at 20$0^{\circ}C$ was obtained for the samples annealed at $600^{\circ}C$. As the results of XRD analysis, the annealed samples had polycrystalline phase mixed with triclinic and orthorhombic structures. The sample exhibit higher sensitivity when the system has less triclinic structure. The sensitivities, $R_{gas}$ $R_{air}$ operating at 20$0^{\circ}C$ to 5 ppm N $O_2$of the sample annealed at $600^{\circ}C$ were approximately 90. 90.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2005년도 하계학술대회 논문집 Vol.6
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• pp.418-419
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• 2005

$\o-LiMnO_2$ is known to have poor cycle performance causing the irreversible phase transformation on cycling. In this paper, the effect of chemical substitution on improving cycle performance of $o-LiMnO_2$ was studied at the compositions of $LiCr_xMn_{1-x}O_2$(x=0, 0.1, 0.2, 0.4). XRD is showed that structure of $LiCr_xMn_{1-x}O_2$ transformed from orthorhombic to spinel according to the increase of substitute degree. For lithium ion battery applications, $LiCr_xMn_{1-x}O_2$/Li cell were characterized electrochemically by charge/discharge cycling.

• Journal of Magnetics
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• 제18권1호
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• pp.30-33
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• 2013

The magnetocaloric effect and magnetization behavior have been analyzed in the double-perovskite $La_{0.7}Ba_{0.3}Mn_{1-X}Fe_XO_3$ compound with the sintering temperature at 1273 K. Samples were fabricated by the conventional solid-state reaction method. X-ray diffraction measurement revealed that all the samples had a single phase in orthorhombic. Detailed investigations of the magnetic entropy behavior of the samples were discussed with the variation of $T_C$. The magnetic entropy changes, ${\Delta}S_M$ of approximately 0.36-1.14 J/kg K were obtained in the temperature range of 145-350 K for the $La_{0.7}Ba_{0.3}Mn_{1-X}Fe_XO_3$ compound. The enhancement of the magnetic entropy change is believed to be due to changes in the microstructure, which changes the magnetic part of the entropy of a solid around the magnetic ordering temperature.

• Bulletin of the Korean Chemical Society
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• 제9권5호
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• pp.289-291
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• 1988

The ratio of trivalent to divalent copper has been determined by the redox titration for two superconducting phases of $YBa_2Cu^{3+}_{2x}Cu^{2+}_{3-2x}O_{6.5+x}$ with the onset temp. of 60K (x = 0.23 ${\pm}$ 0.01) and 90K (x = 0.35 ${\pm}$ 0.02), and for the insulating one (x ${\cong}$ 0) which was kept in an ambient atmosphere for 72 hrs. It is found that $T_c$, and the ratio of $Cu^{3+}/Cu^{2+}$ depend strongly on the annealing temperature and time. A typical orthorhombic phase can easily be obtained by a slow cooling or stepwise cooling at $PO_2$ = 1 atm, and shows a high Tc (ca. 90K) superconductivity.

• 한국전기전자재료학회논문지
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• 제22권1호
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• pp.35-40
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• 2009

Lead free positive temperature coefficient of resistivity (PTCR) ceramics based on $BaTiO_3-(Bi_{0.5}Na_{0.5})TiO_3$ solid solution were prepared by a conventional solid state reaction method. The phase structure was showed single phase with perovskite structure regardless calcinations temperature and $Ba_{1-x}(Bi_{0.5}Na_{0.5})_xTiO_3$ structure was transformed from tetragonal to orthorhombic phase at $x{\geq}0.15$ mole. The XRD peaks with $45^{\circ}{\sim}46^{\circ}$ shifted in right the influence of crystal structure change and the intensity of peak was decreased with additive $(Bi_{0.5}Na_{0.5})TiO_3$. The curie temperature risen with additive $(Bi_{0.5}Na_{0.5})TiO_3$ but disappeared for $(Bi_{0.5}Na_{0.5})TiO_3$ addition more than 0.15 mole in TMA. In relative permittivity, the curie temperature by the transform of ferroelectric phase risen with additive $(Bi_{0.5}Na_{0.5})TiO_3$ but decreased in relative permittivity. Also, the peak of new curie temperature showed the sample containing $0.025{\sim}0.045$ mole of $(Bi_{0.5}Na_{0.5})TiO_3$ near $70^{\circ}C$ caused by phase transform from ferroelectric to ferroelectric and the peak of new curie temperature disappeared at 0.045 mole of $(Bi_{0.5}Na_{0.5})TiO_3$. In our study, it was found that the PTCR in $BaTiO_3-(Bi_{0.5}Na_{0.5})TiO_3$ system was possible for $0{\sim}0.025$ mole of $(Bi_{0.5}Na_{0.5})TiO_3$ and the maximum curie temperature by phase transition showed about at $145^{\circ}C$.

• 전기화학회지
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• 제18권1호
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• pp.31-37
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• 2015

삼성분 칼코게나이드 화합물인 황화 주석 저마늄 ($Sn_xGe_{1-x}S$) 합금 나노입자를 메틸 주석 $(Sn(CH_3)_4$, tetramethyl tin, TMT) 메틸 저마늄 $(Ge(CH_3)_4$, tetramethyl germanium, TMG), 황화수소 ($H_2S$, hydrogen sulfide) 혼합 가스의 레이저 광분해 반응법으로 합성할 수 있으며, 이때 반응기 안의 가스 혼합비율에 따라 나노입자의 주석과 저마늄의 조성비를 조절할 수 있었다. 조성비를 가변시킨 나노입자는 모두 결정성을 갖게 만들 수 있었으며, 리튬 이온 전지의 음극소재로서 우수한 특성을 보여주었다. 조성비에 따라 특성을 조사결과, 황화저마늄은 70 사이클 후 최대 1200 mAh/g의 가장 높은 방전용량을 갖는 것과, 주석 성분 함량이 클수록 높은 충방전률에서 용량 유지가 더 잘 됨을 확인하였다. 이와 같은 우수한 효율의 황화물 합금 나노입자의 새로운 대량 합성법은 고성능 에너지 변환 소재 실용화에 기여할 것으로 예상된다.

• 한국광물학회지
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• 제26권1호
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• pp.35-44
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• 2013

유사 올리빈 구조를 가지는 탄소코팅 합성 $Li^+Fe^{2+}(PO_4)^{3-}$ 분말시료에 대한 상온-고압실험을 대칭 다이아몬드 앤빌기기를 이용하여 35.0 GPa까지 시행하였다. $LiFePO_4$의 압축 데이터를 이용하여 계산된 체적탄성률은 $130.1{\pm}10.3$ GPa이다. 18 GPa 이상의 압력에서 d = 3.386 ${\AA}$ 위치에 새로운 피크가 관찰되고 35 GPa에서는 d = 2.854 ${\AA}$에 또 다른 피크가 관찰되고 있으나 주 결정구조는 사방정계인 것으로 판단된다. 압력에 대한 단위 포 부피의 압축은 M1($Li^+O_6$)의 수축이 두드러지고 M2($Fe^{2+}O_6$)와 사면체($PO_4$)의 수축은 상대적으로 작은 것으로 나타났다.

• 한국전기전자재료학회논문지
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• 제30권11호
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• pp.710-716
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• 2017

New white-light-emitting $SrSnO_3:Dy^{3+}$ phosphors were prepared using different concentrations of $Dy^{3+}$ ions via a solid-state reaction. The phase structure, luminescence, and morphological properties of the synthesized phosphors were investigated using X-ray diffraction analysis, fluorescence spectrophotometry, and scanning electron microscopy, respectively. All the synthesized phosphors crystallized in an orthorhombic phase with a major (020) diffraction peak, irrespective of the concentration of $Dy^{3+}$ ions. The excitation spectra were composed of a broad band centered at 298 nm, ascribed to the $O^2-Dy^{3+}$ charge transfer band and five weak bands in the range of 350~500 nm. The emission spectra of $SrSnO_3:Dy^{3+}$ phosphors consisted of three bands centered at 485, 577, and 665 nm, corresponding to the $^4F_{9/2}{\rightarrow}^6H_{15/2}$, $^4F_{9/2}{\rightarrow}^6H_{13/2}$, and $^4F_{9/2}{\rightarrow}^6H_{11/2}$ transitions of $Dy^{3+}$, respectively. As the $Dy^{3+}$ concentration increased from 1 to 15 mol%, the intensities of all the emission bands gradually increased, reached maxima at 15 mol% of $Dy^{3+}$ ions, and then decreased rapidly at 20 mol% due to concentration quenching. The critical distance between neighboring $Dy^{3+}$ ions for concentration quenching was calculated to be $9.4{\AA}$. The optimal white light emission by the $SrSnO_3:Dy^{3+}$ phosphors was obtained when the $Dy^{3+}$ concentration was 15 mol%.