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Re-synthesis and Electrochemical Characteristics of LiFePO4 Cathode Materials Recycled from Scrap Electrodes

  • Kim, Hyung Sun;Shin, Eun Jung
    • Bulletin of the Korean Chemical Society
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    • v.34 no.3
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    • pp.851-855
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    • 2013
  • This paper describes an environmentally friendly process for the recovery of $LiFePO_4$ cathode materials from scrap electrodes by a simple thermal treatment method. The active materials were easily separated from the aluminum substrate foil and polymeric binders were also decomposed at different temperatures ($400^{\circ}C$, $500^{\circ}C$, $600^{\circ}C$) for 30 min under nitrogen gas flow. The samples were characterized by X-ray diffraction (XRD), scanning electronic microscopy (SEM), Raman spectroscopy, Thermogravimetric analysis (TGA), and differential scanning calorimetry (DSC). The electrochemical properties of the recycled $LiFePO_4$ cathode were evaluated by galvanostatic charge and discharge modes. The specific charge/discharge capacities of the recycled $LiFePO_4$ cathode were similar to those of the original $LiFePO_4$ cathode. The $LiFePO_4$ cathode material recovered at $500^{\circ}C$ exhibits a somewhat higher capacity than those of other recovered materials at high current rates. The recycled $LiFePO_4$ cathode also showed a good cycling performance.

Status and Prospect of Test Methods of Quality Silicone Water Repellent for Protecting Reinforced Concrete

  • Sun, H.Y.;Yuan, Z.Y.;Yang, Z.;Shan, G.L.;Shen, M.X.
    • Corrosion Science and Technology
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    • v.16 no.3
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    • pp.141-150
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    • 2017
  • Impregnating with quality silicone water repellent on the concrete surface is an effective method of protecting concrete. Quality silicone water repellent has been widely used in the engineering profession because of its desirable properties such as hydrophobicity, keeping concrete breathable and preserving the original appearance of the concrete. The companies in China that produce silicone water repellent are listed. Test methods in the specifications or standards about silicone water repellent in China are summed. The test methods relative to durability of concrete impregnated with silicone water repellent (such as resistant to chloride ion penetration, resistant to alkali, resistance to freezing and thawing and weatherability etc.) and the constructive quality (such as water absorption rate, impregnating depth and the dry velocity coefficient etc.) are compared and analyzed. The results indicate that there are differences among test methods relative to different specifications with the same index and therefore, confusion has ensued when selecting test methods. All test methods with the exception of the method of water absorption rate by using a Karsten flask are not non-destructive methods or conducted in a laboratory. Finally, further research on silicone water repellent during application is proposed.

A Case Study on Caisson Foundation Grouting in Geo-Ga Bridge (거가대교 케이슨기초 그라우트 충전 사례연구)

  • Bae, Kyung-Tae;Cha, Kyung-Seob;Kim, Young-Jin;Park, Chung-Whan;Jeong, Gyeong-Hwan
    • Proceedings of the Korean Geotechical Society Conference
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    • 2010.03a
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    • pp.1046-1050
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    • 2010
  • During construction of a sea-crossing bridge grouting was used to fill densely the space between the bottom of caisson and the ground. This grout mixture was mixed with an anti-washout admixture after locating accurately the pre-cast caisson on three concrete landing pads. This method differs significantly from the costly conventional method, for bridge foundations offshore, where concrete is placed in situ after excavating inside of a temporary concrete coffering wall. To verify the grouting method in advance, the full-scale field tests were performed twice on land. After identifying the fluidity of the grout material to be filled, finding some possible problems with the main construction and revising the original design, the main construction has been continuing successfully with 20 caissons completed to date. The purpose of this paper is to introduce for the first time in Korea the grouting method including the automatic and the manual monitoring system based on the main construction of the caisson foundation.

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Evaluation on the Mechanical Performance of Low-Quality Recycled Aggregate Through Interface Enhancement Between Cement Matrix and Coarse Aggregate by Surface Modification Technology

  • Choi, Heesup;Choi, Hyeonggil;Lim, Myungkwan;Inoue, Masumi;Kitagaki, Ryoma;Noguchi, Takafumi
    • International Journal of Concrete Structures and Materials
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    • v.10 no.1
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    • pp.87-97
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    • 2016
  • In this study, a quantitative review was performed on the mechanical performance, permeation resistance of concrete, and durability of surface-modified coarse aggregates (SMCA) produced using low-quality recycled coarse aggregates, the surface of which was modified using a fine inorganic powder. The shear bond strength was first measured experimentally and the interface between the SMCA and the cement matrix was observed with field-emission scanning electron microscopy. The results showed that a reinforcement of the interfacial transition zone (ITZ), a weak part of the concrete, by coating the surface of the original coarse aggregate with surface-modification material, can help suppress the occurrence of microcracks and improve the mechanical performance of the aggregate. Also, the use of low-quality recycled coarse aggregates, the surfaces of which were modified using inorganic materials, resulted in improved strength, permeability, and durability of concrete. These results are thought to be due to the enhanced adhesion between the recycled coarse aggregates and the cement matrix, which resulted from the improved ITZ in the interface between a coarse aggregate and the cement matrix.

Effect of Inherent Anatomy of Plant Fibers on the Morphology of Carbon Synthesized from Them and Their Hydrogen Absorption Capacity

  • Sharon, Madhuri;Sharon, Maheshwar
    • Carbon letters
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    • v.13 no.3
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    • pp.161-166
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    • 2012
  • Carbon materials were synthesized by pyrolysis from fibers of Corn-straw (Zea mays), Rice-straw (Oryza sativa), Jute-straw (Corchorus capsularis) Bamboo (Bombax bambusa), Bagass (Saccharum officinarum), Cotton (Bombax malabaricum), and Coconut (Cocos nucifera); these materials were characterized by scanning electron microscope, X-ray diffraction (XRD), and Raman spectra. All carbon materials are micro sized with large pores or channel like morphology. The unique complex spongy, porous and channel like structure of Carbon shows a lot of similarity with the original anatomy of the plant fibers used as precursor. Waxy contents like tyloses and pits present on fiber tracheids that were seen in the inherent anatomy disappear after pyrolysis and only the carbon skeleton remained; XRD analysis shows that carbon shows the development of a (002) plane, with the exception of carbon obtained from bamboo, which shows a very crystalline character. Raman studies of all carbon materials showed the presence of G- and D-bands of almost equal intensities, suggesting the presence of graphitic carbon as well as a disordered graphitic structure. Carbon materials possessing lesser density, larger surface area, more graphitic with less of an $sp^3$ carbon contribution, and having pore sizes around $10{\mu}m$ favor hydrogen adsorption. Carbon materials synthesized from bagass meet these requirements most effectively, followed by cotton fiber, which was more effective than the carbon synthesized from the other plant fibers.

Studies on compositional Characteristics and Quantitative Determination of Buckwheat Flour in Commercial Products of Kangwondo Makkuksoo(Buckwheat Noodle) and Buckwheat Flour (강원도 막국수와 메밀분의 성분학적 특성 및 시판제품 중의 메밀함량 감별법)

  • 이상영;최용순;심태흠;김준래;김성완;정의호
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.28 no.5
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    • pp.963-968
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    • 1999
  • This study was tried to evaluate possibilities for discriminating the mixture degree of wheat flour from buckwheat products. Buckwheat was milled into four grades of powder, i.e. whole grain flour (WGF), inner layer flour(ILF), middle layer flour(MLF) and outer layer flour(OLF)), and these powders were mixed with wheat flour(WF) to make mixed samples. Ash, protein and fat contents of the buckwheat flours were high in the order of OLF=WGF>MLF>ILF. On the other hand, WF showed a similar content to OLF in ash and protein, and to ILF in fats. Potassium and magnesium contents were higher in all the buckwheat powder than in the wheat flour. Flavonoid contents were higher in order of OLF>WGF=MLF> ILF, but it was not in wheat flour. Although the reliable correlation between mix ratio and components, i.e. mag nesium or ash analyzed were found, it did not seem to reflect sufficiently the expected variations of contents of original material components. Also, compositions of commercial buckwheat products were analyzed to evaluate the mixed ratio of buckwheat flour and wheat flour. The results suggest that the components analyzed in this study as putative marker were not good in determining whether or how much buckwheat products contained wheat flour.

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A STUDY ON THE DIMENSIONAL ACCURACY OF MODELS USING 3-DIMENSIONAL COMPUTER TOMOGRAPHY AND 2 RAPID PROTOTYPING METHODS

  • Cho Lee-Ra;Park Chan-Jin;Park In-Woo
    • The Journal of Korean Academy of Prosthodontics
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    • v.39 no.6
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    • pp.633-640
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    • 2001
  • Statement of problem. Relatively low success rate of root analogue implant system was supposed to be due to the time duration between extraction and implant installation. The use of three-dimensional computer tomography and the reconstruction of objects using rapid prototyping methods would be helpful to shorten this time. Purpose. This aim of this study was to evaluate the application possibility of the 3-dimensional computer tomography and the rapid prototyping to root analogue implants. Material and methods. Ten single rooted teeth were prepared. Width and height of the teeth were measured by the marking points. This was followed by CT scanning, data conversion and rapid prototyping model fabrication. 2 methods were used; fused deposition modelling and stereolithography. Same width and height of this models were measured and compared to the original tooth. Results. Fused deposition modelling showed an enlarged width and reduced height. The stereolithography showed more exact data compared with the fused deposition modelling. Smaller standard deviation were recorded in the stereolithographic method. Overall width error from tooth to rapid prototyping was 7.15% in fused deposition modelling and 0.2% in stereolithography. Overall height showed the tendency of reducing dimensions. Conclusion. From the results of this study, stereolithography seems to be very predictable method of fabricating root analogue implant.

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A Study on the Development of Uniform Design by Using the Hanji Thread Fabric - Focusing on the Music Hall Uniform - (한지사 직물을 이용한 유니폼 디자인 개발에 관한 연구 - 음악홀 유니폼을 중심으로 -)

  • Beom, Seo-Hee;Lee, Hyun-Og;Shon, Young-Mi
    • Fashion & Textile Research Journal
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    • v.12 no.2
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    • pp.149-155
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    • 2010
  • The advanced and complicated modern society recognizes image creation based on the identity of the global competitive age as the important means. The requirement for a new vision to the globally environmental problem has affected on design so that as environmentally-friendly products and technologies have been developed and original expression modes have been appeared which the medium of paper which is natural material, paper has been highlighted newly. Hanji made of mulberry fiber, a bast fiber of mulberry is a representative environment-friendly natural fiber. In addition, it has various functions similar to those of yellow earth such as emission of far infrared rays, antibiosis, deodorization, fast dry ability of sweat, and simple dyeing ability. It is Hanji threads that are produced from various processes of Hanji materials. Therefore, hanji threads are able to be both woven and knitted still remaining Hanji's excellent characteristics. In addition, it is light, bio-degradable, durable and washable, and it is an environment friendly product with the distinguished texture and sensitivity. Under the concept of 'Circle' designed the uniforms of music hall to inform that the uniforms as a media representing music hall represents the unique Sori Arts Center of Jeollabuk-do traditional style.

Effect of Residual Stress on Femoral Arterial Stress-Strain Behavior

  • Chandran, K.B.;Mun, J.H.;Chen, J.S.;Nagaraj, A.;McPherson, D.D.
    • Journal of Mechanical Science and Technology
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    • v.15 no.7
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    • pp.965-973
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    • 2001
  • It is well established that arteries are subjected to residual stress. Due to the effect of residual stress, the arteries open to a horse-shoe shape when a longitudinal cut is made on an excised arterial segment. Previously, the residual stress has been quantified by the opening angle of the horse-shoe shape. We have employed a finite element analysis of the open arterial segment to restore the same to the original cylindrical shape and computed the circumferential strain as well as the stress distribution in the wall. In this study, the stress distribution in the femoral arteries of miniswine was computed with and without the residual stress for a range of transmural pressures. Our analysis showed that the residual stress has the effect of redistribution of the circumferential stresses between the intima and the adventitia under physiological loading. The redistribution of the stress with the inclusion of residual stress may be important in the studies on effect of wall stresses on the endothelial and vascular smooth muscle cells.

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Experimental Study for the Durability Enhancement of Plastic Spur Gear (플라스틱스퍼기어의 내구성향상에 관한 실험연구)

  • Kim, Chung-Hyeon;An, Hyo-Seok;Jeong, Tae-Hyeong
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.26 no.9
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    • pp.1914-1922
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    • 2002
  • Operating test of power-transmission plastic spur gears were performed inspecting both characteristics of friction-wear and endurance, and suggesting endurance improvement method that either drills internal holes of tooth or inserts metallic pin in the internal hole of tooth and verifying this newly-provided method. In case of acetal gears, amount of friction-wear is observed to increase by development of plastic deformation and increase of tooth stiffness due to brittle material property of acetal. To the contrary, in case of nylon gears, suggested method is shown to drop down the tooth temperature for about 3∼10$^{\circ}C$ than original gear, thus amount of wear is reduced by over 30% and operating lift prolonged by more than 200%. Hence, suggested method is proved to be practically applicable to the plastic gears made by soft polymers such as Nylon.