• Resources Recycling
• /
• v.18 no.1
• /
• pp.22-29
• /
• 2009

To design and construct a moving bed stoker incinerator for incineration treatment of the domestic oil fly ash, operating condition and moving bed area of incinerator were determined by performing incinerate experiment of the oil fly ash in the muffle furnace which simulates moving bed stoker incinerator in all conditions. Incineration process of the oil fly ash could be divided into 3 stages, every stage needs the appropriate operating condition for effective incineration. The optimum content of water in the heavy oil fly ash was found to be 20 wt% to prevent the ash from flying and reduce the volume. Science combustion rate of oil fly ash depends on the oxygen content, the incinerator must have a equipment to control the oxygen content in the combustion air. The optimum temperature was $750{\sim}800^{\circ}C$ in order to prevent adhesion to the stocker and evaporation of metal compounds of low melting point. Uniform combustion reaction and acceleration of combustion rate required agitation during the combustion of oil fly ash. The incineration rate was $12.53kg/m^2hr$ and the working area of moving bed incinerator was found to be $60m^2$ to incinerate 18 tons of oil fly ash per day.

• Resources Recycling
• /
• v.15 no.5 s.73
• /
• pp.11-16
• /
• 2006

A novel microwave-induced pyrolysis was used for the recovery of valuable products from waste polystyrene in motor oil. Quartz tube was introduced as microwave reactor and silicon carbide was used as the microwave absorbent. In the experiments, different pyrolysis conditions were applied, such as time range from 30 minutes to 1 hour and microwave input power range from 180 to 250W. The distillate products from pyrolysis were analyzed with GC/MS. Styrene, 1-methyl styrene, toluene, ethyl benzene were the four main products. Styrene recovery rate from polystyrene was around 50%. Temperature for the complete pyrolysis using microwave was around $300^{\circ}C$ which is much lower than that of conventional thermal pyrolysis.

• Resources Recycling
• /
• v.27 no.1
• /
• pp.45-54
• /
• 2018

This study aimed to investigate the effects of mechanical factors such as agitation speed and air rate in fly ash flotation. Specifically, we used thermal power plant fly ash with unburned carbon content of 3.4 to 3.7%. The effect of pH, agitation speed, collector dosage, and frother dosage - the key factors of froth flotation - showed unburned carbon recovery and unburned carbon content of 63% and 34%, respectively, when the dosage of safflower oil used as collector was 800 g/ton, pH was 7, agitation speed was 1,200 rpm, and frother dosage was 400 g/ton. The SEM/EDS analysis of fly ash in that case indicated that the spherical fly ash particles lowered the unburned carbon content as they floated with the air bubbles without being dissolved in the unburned carbon or settled in the ore solution. The other experiment of changing the mechanical factors such as agitation speed and air rate resulted in unburned carbon recovery and unburned carbon content of 74% and 67%, respectively, at air rate of 8 L/min and agitation speed of 900 rpm. The recovery and unburned carbon content increased as the low agitation speed and additional air injection decreased the strength of the eddy current in the ore solution and consequently prevented the floating of fine fly ash particles with unburned carbon. In addition, the recovery rate and unburned carbon increased further to 80% and 70%, respectively, showing the best performance when the agitation speed and air rate were lowered to 800 rpm and 6 L/min, respectively.

• Journal of Ocean Engineering and Technology
• /
• v.11 no.3
• /
• pp.124-131
• /
• 1997

흡착식 유회수기의 운전조건을 결정하는데 있어서 스키머의 구동속도와 기름의 물리.화학적 성질에 따른 스키머의 유회수율을 예측하는 것이 필요하다. 이 문제에 대한 이론적인 접근으로 수직구동 평판상에 부착된 기름층의 자유표면유동을 두가지 방법으로 조사하였다. 그 하나는 표면코팅시 얇은 유막에 대하여 수행하는 정상유동해석이며, 다른 방법으로는 스키머 표면유막에 대한 안정성해석이다. 해석은 기름층이 충분히 두꺼워서 스키머는 기름층에서만 작동한다고 가정하였다. 이론추정 결과는 롤러타입의 스키머에 대하여 계측한 실험치와 비교하였는데, 유막의 안정성해석 결과가 유회수기와 같이 상대적으로 고레이놀즈수에서 작동하는 유동의 경우에는 정상해석보다 좀 더 합리적으로 유막의 두께를 산정함을 알 수 있었다. 한편, 물위에 떠있는 얇은 유막층의 유회수성능도 실험하여서 주어진 유막두께에 대하여 롤러의 최적구동속도를 함께 조사하였다.

• Journal of the Korean Institute of Gas
• /
• v.26 no.2
• /
• pp.1-8
• /
• 2022

The purpose of this study is to prepare GPTMS((3-Glycidoxypropyl) trimethoxysilane)-SiO₂ nanofluid and analyze the effect of nanofluid injection on carbonate reservoirs. Structural analysis of silica nanoparticles modified by GPTMS was investigated by FTIR(Fourier transform infrared spectroscopy). C-H stretching vibrations at 2,950 cm^-1 indicating the silica surface modification with GPTMS were observed when the silane feed was over 0.5 mmol/g. Also, the coreflooding test by nanofluid injection on the aged limestone and dolomite plug samples was carried out with different particle concentration and flow rate. The incremental oil recovery was up to 18.9%, and contact angle and permeability of carbonate samples were changed by the effect of nanoparticle adsorption on pore which caused wettability alteration and pore size change. Therefore, the prepared nanofluid will be utilized as an injection fluid for enhancing oil recovery and modifying fluid flow properties such as change of rock wettability and permeability in carbonate reservoirs.

• Economic and Environmental Geology
• /
• v.41 no.5
• /
• pp.617-624
• /
• 2008

Azerbaijan, located on western part of Caspian Sea, has been developed oil and gas exploration and production business from about 200 years ago and once charged of 50% of world oil production in the early 20th century. After Azerbaijan was independent of Soviet Union in 1991, foreign oil companies, including Korean oil companies, have been investing in Azerbaijan oil business on offshore blocks. Productive capacity of downstream in the Azerbaijan is lower than productive capacity of upstream, whereas there are important pipelines, such as BTC, SCP, NREP, and WREP, provide opportunities of the oil and gas exporting to the world. Oil fields in onshore blocks in the Azerbaijan are almost mature oil fields, caused by high recovery rate. Offshore oil blocks are still high potential in oil exploration with high risk.

• Membrane and Water Treatment
• /
• v.4 no.4
• /
• pp.277-291
• /
• 2013

The transport and recovery of Levafix brilliant red E-4BA and Levafix brilliant red E-6BA were investigated using polytetrafluoroethylene (PTFE) fiber based supported liquid membrane containing tetra butyl ammonium bromide (TBAB) in coconut oil as a carrier. The influencing parameters studied are: pH of the feed solution, concentration of dye in the feed solution, extractant concentration, and various kind of stripping agent, rate of stirring, time of transport, reusability of membrane and stability of membrane. Increase in TBAB concentration inside the membrane enhances the flux with its maximum value at $1.553{\times}10^{-4}$ M TBAB. Further increase in the concentration of TBAB leads to decreased rate of transport due to increase in viscosity of membrane liquid. The optimum conditions for dye transport are: pH of feed ($7{\pm}0.1$), $1.553{\times}10^{-4}$ M extractant concentration, 350 rpm for stirring, $4.9{\times}10^{-1}$ M potassium hydrogen phthalate as a stripping solution, the time of transport 6 h. It was noticed that flux values were increased with increasing dye concentration in the feed phase. Applying this study to textile wastewater, dyes were transported up to 98% in 6 h. This recovery technique is rewarding to environment and economic.

• Tunnel and Underground Space
• /
• v.23 no.6
• /
• pp.538-546
• /
• 2013

This paper deals with a hydraulic fracturing technique, which is one of the methods to maximize the recovery rate and productivity of oil and gas in the petroleum industry. In the hydraulic fracturing, typically water mixed with sand and chemicals is injected into a wellbore in order to create artificial fractures along which formation fluids migrate to the well. In recent years, it is widely used in non-conventional oil and gas such as oil shale and shale gas. Three main stages of the hydraulic fracturing process, the proposed design models for the effective hydraulic fracturing and diagnostics after fracturing treatment are introduced. In addition, this paper introduces reservoir geomechanics to solve various problems in the process of hydraulic fracturing.

• Journal of the Korean Society for Marine Environment & Energy
• /
• v.4 no.2
• /
• pp.43-51
• /
• 2001

Now our ocean environment pollution is very serious. Its harm hinders in marine breeding and the safe navigation of ships at the coast. We have used an assembly system for a measure taken against environment pollution like this. But, here are some problems awaiting solution. First, most of combustible materials among ocean waste are high polymer, so it is necessary some special equipment to incinerate them. In the process we can't overlook air pollution by exhaust gas. Also, when we reclaim these wastes, we remember that they can't be decomposed naturally and leaking water may pollute soil. Thus now a days new treatment method has been developed, it recycles and doesn't product secondary pollution materials by recovering oil from pyrolysis. For it, this study investigated chemicalㆍphysical properties of wastes. And it found condition of recovering the most oil. Also it probed that the variation of temperature raising speed affects the weight reduction characteristics of wastes. Also, while studying recovered oil by waste pyrolysis and the rate of non-condensing gas in accordance with the variation of temperature raising speed. Finally we had confidence the development of pyrolysis oil recovery would succeed because we carried out evaluation at an economic point of view about it.

• Tunnel and Underground Space
• /
• v.23 no.1
• /
• pp.1-12
• /
• 2013

Enhanced oil recovery (EOR) technology coupled with underground carbon dioxide sequestration is introduced. $CO_2$ can be injected into an oil reservoir in order to enhance oil production rate and $CO_2$ EOR can be turned into CCS in a long term sense. Coupling $CO_2$ EOR with CCS may secure a large scale and consistent $CO_2$ source for EOR, and the $CO_2$ EOR can bring an additional economic benefit for CCS, since the benefit from enhanced oil production by $CO_2$ EOR will compensate costs for CCS implementation. In this paper, we introduced the characteristics of $CO_2$ EOR technology and its market prospect, and reviewed the Weyburn $CO_2$ EOR project which is the first large-scale $CO_2$ EOR case utilizing an anthropogenic $CO_2$ source. We also introduced geotechnical elements for a successful and economical implementation of $CO_2$ EOR with CCS and they were a miscroseismic monitoring during and after injection of $CO_2$, and determination of minimum miscible pressure (MMP) and maximum injection pressure (MIP) of $CO_2$.