• 제목/요약/키워드: OH Spectrum Band

검색결과 77건 처리시간 0.026초

trans-[Co(R,R-chxn)$_2Cl_2]^+$ 착물의 대이온 및 용매의존성 원편광이색성 스펙트라 (Circular Dichroism Spectra on the Counter Ions and the Solvent Dependence of trans-$[Co(R,R-chxn)_2Cl_2]^+$ Complex)

  • 오창언;김양;박성열;도명기
    • 대한화학회지
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    • 제35권5호
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    • pp.493-499
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    • 1991
  • 여러 가지 유기용매에서 서로 다른 대이온을 가진 trans-$[Co(R,R-chxn)_2Cl_2]^+$착물의 원편광이색성(CD) 스펙트럼을 측정하였다. 여기서 R,R-chxn은 (1R,2R)-1,2-diaminocyclohexane 이다. 착물의 CD 스펙트럼에서 관찰된 변화는 현저한 용매의존성을 나타내었다. 그리고 첫 흡수띠 영역$(^1A_{2g})$에서 CD 스펙트럼의 변화 정도는 용매의 donor number(DN)에 의존하였다. trans-[Co(R,R-chxn)$_2Cl_2]^+$ 착물의 CD 스펙트럼 변화는 $^1H$ NMR 스펙트럼으로부터 R,R-chxn 리간드 중의 수평방향의 N-H 수소와 용매분자와의 우선적인 상호작용에 기인되는 것으로 해석되었다.

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이산화탄소의 적외선 스펙트럼 예측을 위한 복사 데이터베이스 활용 (Application of Radiation Databases for the Prediction of CO2 Infrared Spectrum)

  • 남현재;권오준
    • 한국항공우주학회지
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    • 제43권7호
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    • pp.626-634
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    • 2015
  • 본 연구에서는 이산화탄소의 적외선 스펙트럼을 예측하였다. 이를 위해 필요한 흡수계수는 line-by-line 기법을 적용해 계산하였으며 계산에 필요한 분광상수들은 복사 데이터베이스인 HITEMP2010과 CDSD-4000 데이터베이스를 활용하였다. 이산화탄소가 대표적으로 방출하는 2.7과 4.3, $15{\mu}m$ 밴드 영역에 대해 예측을 수행하였으며 타 연구자가 실험을 통해서 획득한 스펙트럼과 비교하여 결과를 검증하였다. 이산화탄소의 적외선 스펙트럼 예측 결과, 전반적으로 HITEMP2010 기반의 예측값과 CDSD-4000 기반의 예측값이 실험과 잘 일치하는 것을 확인하였으나 $4.3{\mu}m$ 밴드 영역에서는 CDSD-4000 기반의 예측값이 HITEMP2010 기반의 예측값보다 실험값과 더 잘 일치하는 것을 확인하였다.

BL-ASM에서 U-net 기반 위상 홀로그램의 스펙클 노이즈 감소와 이미지 품질 향상 (Speckle Noise Reduction and Image Quality Improvement in U-net-based Phase Holograms in BL-ASM)

  • 남오승;권기철;정종래;이권연;김남
    • 한국광학회지
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    • 제34권5호
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    • pp.192-201
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    • 2023
  • Band-limited angular spectrum method (BL-ASM)는 공간주파수 제어의 문제로 aliasing 오류가 발생한다. 본 논문에서는 위상 홀로그램에 대한 표본화 간격 조정 기법과 딥 러닝 기반의 U-net 모델을 사용한 스펙클 노이즈 감소 및 이미지 품질 향상 기법을 제안하였다. 제안한 기법에서는 넓은 전파 범위에서 aliasing 오류를 제거할 수 있도록 먼저 샘플링 팩터를 계산하여 표본화 간격 조절에 의한 공간주파수를 제어함으로써 스펙클 노이즈를 감소시킨다. 그 후 딥 러닝 모델을 적용한 위상 홀로그램을 학습시켜 복원 이미지의 품질을 향상시킨다. 다양한 샘플 이미지에 대한 S/W 시뮬레이션에서 기존의 BL-ASM과의 peak signal-to-noise ratio (PSNR), structural similarity index measure (SSIM)을 비교할 때 각각 평균 5%, 0.14% 정도 비율이 향상됨을 확인하였다.

전산실험모형을 이용한 자동차 엔진 냉각홴의 저소음 설계 (Design of Low Noise Engine Cooling Fan for Automobile using DACE Model)

  • 심현진;박상길;조용구;오재응
    • 한국소음진동공학회논문집
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    • 제19권5호
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    • pp.509-515
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    • 2009
  • This paper proposes an optimal design scheme to reduce the noise of the engine cooling fan by adapting Kriging with two meta-heuristic techniques. An engineering model has been developed for the prediction of the noise spectrum of the engine cooling fan. The noise of the fan is expressed as the discrete frequency noise peaks at the BPF and its harmonics and line spectrum at the broad band by noise generation mechanisms. The object of this paper is to find the optimal design for noise reduction of the engine cooling fan. We firstly show a comparison of the measured and calculated noise spectra of the fan for the validation of the noise prediction program. Orthogonal array is applied as design of experiments because it is suitable for Kriging. With these simulated data, we can estimate a correlation parameter of Kriging by solving the nonlinear problem with genetic algorithm and find an optimal level for the noise reduction of the cooling fan by optimizing Kriging estimates with simulated annealing. We notice that this optimal design scheme gives noticeable results. Therefore, an optimal design for the cooling fan is proposed by reducing the noise of its system.

전산실험모형을 이용한 자동차 엔진 냉각팬의 저소음 설계 (Design of Low Noise Engine Cooling Fan for Automobile using DACE Model)

  • 심현진;이해진;이유엽;오재응
    • 한국소음진동공학회:학술대회논문집
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    • 한국소음진동공학회 2007년도 추계학술대회논문집
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    • pp.1307-1312
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    • 2007
  • This paper proposes an optimal design scheme to reduce the noise of the engine cooling fan by adapting Kriging with two meta-heuristic techniques. An engineering model has been developed for the prediction of the noise spectrum of the engine cooling fan. The noise of the fan is expressed as the discrete frequency noise peaks at the BPF and its harmonics and line spectrum at the broad band by noise generation mechanisms. The object of this paper is to find the Optimal Design for Noise Reduction of the Engine Cooling Fan. We firstly show a comparison of the measured and calculated noise spectra of the fan for the validation of the noise prediction program. Orthogonal array is applied as design of experiments because it is suitable for Kriging. With these simulated data, we can estimate a correlation parameter of Kriging by solving the nonlinear problem with genetic algorithm and find an optimal level for the noise reduction of the cooling fan by optimizing Kriging estimates with simulated annealing. We notice that this optimal design scheme gives noticeable results. Therefore, an optimal design for the cooling fan is proposed by reducing the noise of its system.

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천리안위성 통신탑재체의 위상잡음 스펙트럼 해석 (Phase noise spectrum analysis of COMS communication transponder)

  • 장정식;오대호;김영완
    • 한국정보통신학회:학술대회논문집
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    • 한국해양정보통신학회 2011년도 춘계학술대회
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    • pp.499-501
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    • 2011
  • 본 논문에서는 천리안 위성의 통신 탑재체의 위상잡음 스펙트럼 특성을 측정 분석하며, 전송 방식에 따른 위상잡음 영향을 평가한다. 천리안 위성의 탑재체는 Ka 대역을 사용하며, 고주파수 사용으로 상대적으로 위상잡음 특성이 증가할 수 있다. 아울러 고차모드 위성 전송시 위상잡음에 영향이 증가하여 전송 선능의 열화를 가져올 수 있다. 본 논문에서는 MSM 기능을 갖는 통신 탑재체의 위상잡음 특성을 측정 평가하며 고차모드 전송에 요구되는 위상잡음을 아울러 평가한다.

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Semiconductor Behavior of Passive Films Formed on Cr with Various Additive Elements

  • Tsuchiya, Hiroaki;Fujimoto, Shinji;Shibata, Toshio
    • Corrosion Science and Technology
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    • 제2권1호
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    • pp.7-11
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    • 2003
  • Photoelectrochemical response and electrochemical impedance behavior was investigated for passive film formed on sputter-deposited Cr alloy in $0.1kmol{\cdot}m^{-3}$. Photoelectrochemical action spectrum could be separated into two components, which were considered to be derived from $Cr_2O_3$ ($E_g\sim3.6eV$) and $ Cr(OH)_3 $ ($E_g\sim2.5eV$). The band gap energy, $E_g$, of each component was almost constant for various applied potentials. polarization periods and alloying additives. The photoelectrochemical response showed negative photo current for most potentials in the passive region. Therefore, the photo current apparently exhibited p-typesemiconductor behavior. On the other hand, Mort-Schottky plot of the capacitance showed positive slope, which means that passive film formed on Cr alloy has n-type semiconductor property. These apparently conflicting results are rationally explained assuming that the passive film on Cr alloy formed in the acid solution has n-type semiconductor property with a fairly deep donor level in the band gap and forms an accumulation layer in the most of potential region in the passive state.

느릅나무껍질 추출액에 의한 염색성 (The Dyeing Properties of Ulmi Cortex Extract)

  • 조경래;김미숙
    • 한국염색가공학회지
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    • 제15권1호
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    • pp.30-38
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    • 2003
  • Research to dyeing properties of Ulmi cortex extract, silk and cotton fabrics were dyed and mordanted. Dyes were extracted from distilled water according to different pH values. The dyeability of Ulmi cortex extract were evaluated by conditions of dyeing temperature, dyeing time, dyeing pH, mordanting temperature, mordanting time, mordanting concentration and color fastness, etc. IR spectrum possessed absorption band of -OH at $3400cm^{-1},\;C-H\;at\; 2940cm^{ -1},\;aromatic\;C=C\;at\;1628cm^{-1},\;1518cm^{-1},\;C-O\;at\; 1107cm^{ -1},\;1043cm^{-1}$. And the $\labmda$max of extract appeared at 220nm and 280nm, so the substance of Ulmi cortex extract were catechin and tannin. Surface color of dyed fabrics were reddish yellow~yellow~greenish yellow. From the color fastness test, the fabrics dyed with PH 7 extract were excellent in irradiation and washing. Mordanting improved the color fastness and K/S value of dyed fabrics.

염류용액 방전의 온도 측정에 관한 연구 (A Study on the Temperature Measurement Using Optical Emission in Saline Solution Discharge with Pin to Plate Electrodes)

  • 김중균
    • 조명전기설비학회논문지
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    • 제30권1호
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    • pp.66-71
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    • 2016
  • In this study, electrical and spectroscopic characteristics were investigated in the pin to plate discharge of 0.9% weight per unit volume saline solution. The positive and positive- and negative-going dc pulse with 5% duty ratio were applied to tungsten pin electrode. The more amount of discharge current flew in negative discharge. The temperature, which is considered as a local value in the vicinity of vapor of discharge, was about 3,000K which is much higher than the value recommended to be controlled. It can be suggested that not only the temperature of liquid but also the local temperature of vapor is monitored to investigate damages on tissue or cells in biological application.

Rapid and Nondestructive Discrimination of Fusarium Asiaticum and Fusarium Graminearum in Hulled Barley (Hordeum vulgare L.) Using Near-Infrared Spectroscopy

  • Lim, Jong Guk;Kim, Gi Young;Mo, Chang Yeun;Oh, Kyoung Min;Kim, Geon Seob;Yoo, Hyeon Chae;Ham, Hyeon Heui;Kim, Young Tae;Kim, Seong Min;Kim, Moon S.
    • Journal of Biosystems Engineering
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    • 제42권4호
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    • pp.301-313
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    • 2017
  • Purpose: This study was conducted to discriminate between normal hulled barley and Fusarium (Fusarium asiaticum and Fusarium graminearum) infected hulled barley by using the near-infrared spectroscopy (NIRS) technique. Methods: Fusarium asiaticum and Fusarium graminearum were artificially inoculated in hulled barley and the reflectance spectrum of the barley spike was obtained by using a near-infrared spectral sensor with wavelength band in the range 1,175-2,170 nm. After obtaining the spectrum of the specimen, the hulled barley was cultivated in a greenhouse and visually inspected for infections. Results: From a partial least squares discriminant analysis (PLS-DA) prediction model developed from the raw spectrum data of the hulled barley, the discrimination accuracy for the normal and infected hulled barley was 99.82% (563/564) and 100% (672/672), respectively. Conclusions: NIRS is effective as a quick and nondestructive method to detect whether hulled barley has been infected with Fusarium. Further, it expected that NIRS will be able to detect Fusarium infections in other grains as well.