Journal of the Korean Society for Aeronautical & Space Sciences (한국항공우주학회지)

The Korean Society for Aeronautical and Space Sciences (한국항공우주학회)
권호 표지
DOI QR코드

DOI QR Code

Application of Radiation Databases for the Prediction of CO2 Infrared Spectrum

이산화탄소의 적외선 스펙트럼 예측을 위한 복사 데이터베이스 활용

  • Nam, Hyun Jae (Department of Aerospace Engineering, Korea Advanced Institute of Science and Technology) ;
  • Kwon, Oh Joon (Department of Aerospace Engineering, Korea Advanced Institute of Science and Technology)
  • Received : 2014.11.21
  • Accepted : 2015.06.16
  • Published : 2015.07.01
Download PDF
⟨ Previous Next ⟩

Abstract

In the present study, numerical predictions of infrared spectra for $CO_2$ molecule were conducted. Absorption coefficients of $CO_2$ which are required for simulating the spectra, were calculated by using a line-by-line method and by adopting spectroscopic parameters from the radiation databases, HITEMP2010 and CDSD-4000. Simulations were made in the 2.7, 4.3, and $15{\mu}m$ band regions, and the results were compared with the measurements of other researchers. It was found that the calculated results are well matched with the various measurements. However, in the $4.3{\mu}m$ band region, the CDSD-4000 based calculation yields a better fit to the measurement than the HITEMP2010 based calculation does.

본 연구에서는 이산화탄소의 적외선 스펙트럼을 예측하였다. 이를 위해 필요한 흡수계수는 line-by-line 기법을 적용해 계산하였으며 계산에 필요한 분광상수들은 복사 데이터베이스인 HITEMP2010과 CDSD-4000 데이터베이스를 활용하였다. 이산화탄소가 대표적으로 방출하는 2.7과 4.3, $15{\mu}m$ 밴드 영역에 대해 예측을 수행하였으며 타 연구자가 실험을 통해서 획득한 스펙트럼과 비교하여 결과를 검증하였다. 이산화탄소의 적외선 스펙트럼 예측 결과, 전반적으로 HITEMP2010 기반의 예측값과 CDSD-4000 기반의 예측값이 실험과 잘 일치하는 것을 확인하였으나 $4.3{\mu}m$ 밴드 영역에서는 CDSD-4000 기반의 예측값이 HITEMP2010 기반의 예측값보다 실험값과 더 잘 일치하는 것을 확인하였다.

Keywords

References

  1. Ferriso, C. C., Ludwig, C. B. and Acton, L., "Spectral-Emissivity Measurements of the 4.3 $CO_2$ Band between 2650 and 3000 K," J. Opt. Soc. Am, Vol. 56, 1966, pp.171-173. https://doi.org/10.1364/JOSA.56.000171
  2. Ludwig, C. B., Ferriso, C. C., Acton, L., "High-Temperature Spectral Emissivities and Total Intensities of the 15- Band System of $CO_2$", J. Opt. Soc. Am, Vol. 56, 1966, pp.1685-1692. https://doi.org/10.1364/JOSA.56.001685
  3. Doraiswamy, S., Kelley, J. D., and Candler, G. V., "Vibrational Modeling of $CO_2$ in High Enthalpy Nozzle Flows," Proc. 47th AIAA Aerospace Sciences Meeting Including the New Horizons Form and Aerospace Exposition, 2009, AIAA 2009-1570.
  4. Depraz, S., Perrin, M. Y., Riviere, Ph., and Soufiani, A., "Infrared Emission Spectroscopy of $CO_2$ at High Temperature. Part II: Experimental Results and Comparisons with Spectroscopic Databases," J. Quant. Spectrosc. Radiat. Transfer, Vol. 113, 2012, pp.14-25. https://doi.org/10.1016/j.jqsrt.2011.09.013
  5. Evseev, V., Fateev, A. and Clausen, S., "High-Resolution Transmission Measurements of $CO_2$ at High Temperatures for Industrial Applications," J. Quant. Spectrosc. Radiat. Transfer, Vol. 113, 2012, pp.2222-2233. https://doi.org/10.1016/j.jqsrt.2012.07.015
  6. Cai, J. and Modest, M. F., "Improved Full-Spectrum k-Distribution Implementation for Inhomogeneous Media Using a Narrow-Bnad Database," J. Quant. Spectrosc. Radiat. Transfer, Vol. 141, 2014, pp.65-72. https://doi.org/10.1016/j.jqsrt.2014.02.028
  7. Riviere, Ph. and Soufiani, A., "Updated Band Model Parameters for $H_2O,\;CO_2,\;CH_4$ and CO Radiation at High Temperature," Int. J. Heat Mass Trans., Vol. 55, 2012, pp.3349-3358. https://doi.org/10.1016/j.ijheatmasstransfer.2012.03.019
  8. Dorigon, L. J., Duciak, G., Brittes, R., Cassol, F., Galarca, M., Franca, F.H.R., "WSGG Correlations Based on HITEMP2010 for Computation of Thermal Radiation in Non-isothermal, Non-homogeneous $H_2O/CO_2$ mixtures," Int. J. Heat Mass Trans., Vol. 64, 2013, pp.863-873. https://doi.org/10.1016/j.ijheatmasstransfer.2013.05.010
  9. Rothman, L. S., Gordon, I. E., Barbe, A., Benner, D. C., Bernath, P. F., Birk, M., Boudon, V., Brown, L. R., Compargue, A. et al., "The HITRAN 2008 Molecular Spectroscopic Database," J. Quant. Spectrosc. Radiat. Transfer, Vol. 11, 2009, pp.533-572.
  10. Rothman, L. S., Gordon, I. E., Barber, R. J., Dothe, H., Gamache, R. R., Goldman, A., Perevalov, V. I., Tashkun, S.A., and Tennyson, J., "HITEMP, the High-Temperature Molecular Spectroscopic Database," J. Quant. Spectrosc. Radiat. Transfer, Vol.111, 2010, pp.2139-2150 https://doi.org/10.1016/j.jqsrt.2010.05.001
  11. Tashkun, S. A. and Perevalov, V. I., "CDSD-4000:High-Resolution, High-Temperature Carbon Dioxide Spectroscopic Databank," J. Quant. Spectrosc. Radiat. Transfer, Vol.112, 2011, pp.1403-1410. https://doi.org/10.1016/j.jqsrt.2011.03.005
  12. Fisher, J., Gamache, R. R., Goldman, A., Rothman, L. S., and Perrin, A., "Total Internal Partition Sums for Molecular Species in the 2000 Edition of the HITRAN Database," J. Quant. Spectrosc. Radiat. Transfer, Vol. 82, 2003, pp.401-412. https://doi.org/10.1016/S0022-4073(03)00166-3
  13. Osipov, V. M., "Partition Sums and Dissociation Energy for 12C16O2 at High Temperatures," Mol. Phys., Vol. 102, 2004, pp.1785-1792. https://doi.org/10.1080/00268970412331287016