• Korean Journal of Fisheries and Aquatic Sciences
• /
• v.32 no.1
• /
• pp.56-61
• /
• 1999

Oxygen consumption rate of Far eastern catfish, Silurus asotus, weighing 280g, was measured using continuous flow respirometry chamber linked computer monitoring system. Mean oxygen consumption rates at $15^{\circ}C,\;20^{\circ}C,\;25^{\circ}C$, and $30^{\circ}C$ were ranged in 35.2$\~96.4mg\;O_2/kg$ fish/hr, 78.6$\~127.9mg\;O_2/kg$ fish/hr, 120.1$\~231.7mg\;O_2/kg$ fish/hr, and 197.5$\~352.3mg\;O_2/kg$ fish/hr, respectively. The oxygen consumption rates increased with increasing water temperature (p<0.05). A photoperiod-mediated oxygen consumption rates was higher during the light period than during the darkness (P<0.05). When acclimated with different photoperiods, 24L:0D, 12L:12D, and 0L:24D, the lowest oxygen consumption rate was observed in the continuous darkness (0L:24D). The differences between maximum and minimum oxygen consumption rates oyer 24 hour increased with increasing water temperature and the difference was the highest in 12L:12D. Oxygen consumption rate changed suddenly at dawn and at dusk.

• Journal of Korean Society of Forest Science
• /
• v.94 no.6
• /
• pp.496-503
• /
• 2005

This study was conducted to investigate the influences of sapflow flux on soil water tensions and soil moisture content at the Abies holophylla plots in Gwangneung, Gyeonggido, from September to October 2004. The Abies holophylla had been planted in 1976 and thinning and pruning were carried out in 1996 and 2004. Sapflow flux was measured by the heat pulse method, and soil water tension was measured by tensiometer at hillslope and streamside. Time domain reflectometry probes (TDR) were positioned horizontally at the depth of 10, 30 and 50 cm to measure soil moisture content. All of data were recorded every 30 minutes with the dataloggers. The sapflow flux responded sensitively to rainfall, so little sapflow was detected in rainy days. The average daily sapflow flux of sample trees was 10.16l, a maximum was 15.09l, and a minimum was 0.0l. The sapflow flux's diurnal changes showed that sapflow flux increased from 9 am and up to 0.74 l/30 min. The highest sapflow flux maintained by 3 pm and decreased almost 0.0 l/30 mm after 7 pm. The average soil water tensions were low ($-141.3cmH_2O$, $-52.9cmH_2O$ and $-134.2cmH_2O$) at hillslope and high ($-6.1cmH_2O$, $-18.0cmH_2O$ and $-3.7cmH_2O$) at streamside. When the soil moisture content decreased after rainfall, the soil water tension at hillslope responded sensitively to the sapflow flux. The soil water tension decreased as the sapflow flux increased during the day time, whereas increased during the night time when the sapflow flux was not detected. On the other hand, there was no significant relationship between soil water tension and sapflow flux at streamside. Soil moisture content at hillslope decreased continuously after rain, and showed a negative correlation to sapflow flux like a soil water tension at hillslope. As considered results above, it was confirmed that the response of soil moisture tension to sapflow flux at hillslope and streamside were different.

• Textile Coloration and Finishing
• /
• v.15 no.3
• /
• pp.140-145
• /
• 2003

The purpose of this study is searching the Elm-Bark dyes' dyeability and antibacterial activities according to the dyeing time, pH, a mordant and the method of mordancy. We used two kinds of Elm-Bark dyes which's extracted by the Electrolytic reduction water and Distilled water. Silk fabric and Cotton/nylon union fabric was used for this study. The results are as follow. K/S value is increased according to the dyeing time and the suitable pH level is pH 3. Dyeability is good with Iron(II) sulfate$(FeSO_4\cdot{7H}_2O)$ on the pre-mordancy and Potassium dichromate$(K_2Cr_2O_7)$ on the post-mordancy. The Elm-Bark dyes by the Electrolytic reduction water has good colorfastness more than by the Distilled water. Antibacterial activities is excellent and the ratio is over than 99.5%.

• Bulletin of the Korean Chemical Society
• /
• v.30 no.5
• /
• pp.1026-1030
• /
• 2009

A novel Schiff base ligand (N, O system) 5-methoxy-2-phenyliminomethylphenol ($5-CH_3O-PMP$) was synthesized. Using the synthesized ligand as a fluorescent reagent, a fluorometric method was developed for the quantitative analysis of Al(III) ion. The quantitative analysis of Al(III) ion was performed by making the complex compound between Al(III) ion and $5-CH_3O-PMP$ in ethanol-water solution (85/15, v/v, pH 6.2). The excitation wavelength (${\lambda}em$) of the complex compound was 397 nm while the emmision wavelength (${\lambda}em$) was 498 nm. The quantitative analysis of Al(III) ion was carried out by estimating the fluorescence intensity. The various calibration curves were used for the quantitative analysis in the range of 0.27$\sim$27 ng/mL Al(III) ion concentrations. The detection limit was 0.027 ng/mL. Using the fluorometric method developed in this study, satisfying results were obtained from various samples such as tap water, hot spring water, river water, sea water and waste water, which contained considerable amounts of interfering ions.

• Bulletin of the Korean Chemical Society
• /
• v.33 no.9
• /
• pp.3009-3016
• /
• 2012

This study evaluated the use of iron-impregnated SBA-15 (Fe/SBA-15) as a catalyst for the oxidative degradation of persistent phenol analogues, such as 2-chlorophenol (2-CP), 4-chlorophenol (4-CP), 2-nitrophenol (2-NP), 4-nitrophenol (4-NP) and 2,4,6-trichlorophenol (2,4,6-TCP) in water. The oxidation reactions were carried out with reaction time, concentration of the phenols, amount of the catalysts, reaction temperature, pH of the reaction mixture as the process variables with or without using hydrogen peroxide as the oxidizing agent. The conversion achieved with Fe/SBA-15 at 353 K for 2-CP, 4-CP, 2-NP, 4-NP, 2,4,6-TCP was 80.2, 71.2, 53.1, 62.8, 77.3% in 5h with a reactant to $H_2O_2$ mole ratio of 1:1, and 85.7, 65.8, 61.9, 63.7, 78.1% in the absence of $H_2O_2$, respectively. The reactions followed pseudo first order kinetics. The leachability study indicated that the catalyst released very little iron into water and therefore, the possibility of secondary pollution is negligible.

• Journal of Mechanical Science and Technology
• /
• v.15 no.5
• /
• pp.630-638
• /
• 2001

The electrical resistivity of sinter dusts generated from the steel industry and coal fly ash from the coal power plant has been investigated using the high voltage conductivity cell based on JIS B 9915 as a function of temperature and water content. Dust characterization such as the chemical composition, size distribution, atomic concentration, and surface structure has been conducted. Major constituents of sinter dusts were Fe$_2$O$_3$(40∼74.5%), CaO (6.4∼8.2%), SiO$_2$(4.1∼6.0%), and unburned carbon (7.0∼14.7%), while the coal fly ash consisted of mainly SiO$_2$(51.4%), Al$_2$O$_3$(24.1%), and Fe$_2$O$_3$(10.5%). Size distributions of the sinter dusts were bi-modal in shape and the mass median diameters (MMD) were in the range of 24.7∼137㎛, whereas the coal fly ash also displayed bi-modal distribution and the MMD of the coal fly ash was 35.71㎛. Factors affecting resistivity of dusts were chemical composition, moisture content, particle size, gas temperature, and surface structure of dust. The resistivity of sinter dusts was so high as 10(sup)15 ohm$.$cm at 150$\^{C}$ that sinter dust would not precipitate well. The resistivity of the coal fly ash was measured 1012 ohm$.$cm at about 150$\^{C}$. Increased water contents of the ambient air lowered the dust resistivity because current conduction was more activated for absorption of water vapor on the surface layer of the dust.

• Resources Recycling
• /
• v.33 no.1
• /
• pp.15-21
• /
• 2024

The demand for electric vehicles powered by lithium-ion batteries is continuously increasing. Recovery of valuable metals from waste lithium-ion batteries will be necessary in the future. This research investigated the effect of reaction temperature on the lithium recovery ratio from hydrogen reduction followed by water leaching from lithium-ion battery NCM-based cathode materials. As the reaction temperature increased, the weight loss ratio observed after initiation increased rapidly owing to hydrogen reduction of NiO and CoO; at the same time, the H₂O amount generated increased. Above 602 ℃, the anode materials Ni and Co were reduced and existed in the metallic phases. As the hydrogen reduction temperature was increased, the Li recovery ratio also increased; at 704 ℃ and above, the Li recovery ratio reached a maximum of approximately 92%. Therefore, it is expected that Li can be selectively recovered by hydrogen reduction as a waste lithium-ion battery pretreatment, and the residue can be reprocessed to efficiently separate and recover valuable metals.

• Journal of Environmental Science International
• /
• v.15 no.1
• /
• pp.67-75
• /
• 2006

The degradation of Rhodamine B (RhB) in water was investigated in laboratory-scale experiments, using five advanced oxidation Processes (AOPs) $UV/H_2O_2$, lenten, photo-lenten, $UV/TiO_2,\;UV/TiO_2/H_2O_2$. The photodegradation experiments were carried out in a fluidized bed photoreactor equipped with an immersed 32 W UV-C lamp as light source. initial decolorization rate and COD removal efficiency were evaluated and compared. The results obtained showed that the initial decolorization rate constant was quite different for each oxidation process. The relative order of decolorization was: photo-fenton > $UV/TiO_2/H_2O_2$ > fenton > $UV/H_2O_2$ > $UV/TiO_2$ > UV > $H_2O_2$. The relative order of COD removal was different from decolorization: photo-fenten ${\fallingdotseq}$ $UV/TiO_2/H_2O_2\;>\;UV/TiO_2\;>\;fenton\;>\;UV/H_2O_2$. The Photo-lenten and $UV/TiO_2/H_2O_2$ processes seem to be appropriate for decolorization and COD removal of dye wastewater.

• Korean Journal of Soil Science and Fertilizer
• /
• v.43 no.6
• /
• pp.880-885
• /
• 2010

Importance of climate change and its impact on agriculture and environment has increased with a rise of greenhouse gases (GHGs) concentration in Earth's atmosphere. Nitrous oxide ($N_2O$) emission in upland fields were assessed in terms of emissions and their control at the experimental plots of National Academy of Agricultural Science (NAAS), Rural Development Administration (RDA) located in Suwon city. It was evaluated $N_2O$ emissions at different soil water content, soil temperature, and mineral N conditions in a upland cultivating red pepper and soy bean. The results were as follows: 1) There were significant correlation between amount of $N_2O$ emissions and soil temperature, soil water content and mineral N conditions showed $0.528^{**}$, $0.790^{***}$ and $0.937^{***}$ in red pepper field and $0.658^{***}$, $0.710^{***}$ and $0.865^{***}$ in soybean field, respectively. 2) From the contribution rate analysis as to contribution factors for $N_2O$ emission, it appeared that contribution rate was in the order of mineral N (71.9%), soil moisture content (23.6%), and soil temperature (4.5%) in pepper field and mineral N (65.5%), soil moisture contents (19.2%), and soil temperature (15.2%) in soybean field.

• Advances in nano research
• /
• v.15 no.4
• /
• pp.295-304
• /
• 2023

In this paper, a powerful photocatalyst based on carbon nanocomposite is developed in order to obtain a new material applicable in water treatment and especially for the discoloration of effluents used in the textile industry. For that, TiO₂-graphene nanocomposites have been successfully synthesized by a mixture of Functionalized Graphene Sheet (FGS) and tetrachlorotitanium complexes to form FGS-TiO₂ nanocomposite. In the presence of an anionic surfactant, we used a new chemical process to functionalize graphene sheets in order to make them an excellent medium for blocking and preventing the aggregation of TiO₂ nanoparticles. The components of these nanocomposites are characterized by means of X-ray diffraction (XRD), Fourier Transform Infrared Spectroscopy (FT-IR), Scanning Electron Microscopy (SEM) and Transmission Electron Microscopy (TEM), which confirms the successful formation of the FGS-TiO₂ nanocomposite. It was found that the TiO₂ nanoparticles were dispersed uniformly on the graphene plane which possesses better charge separation capability than pure TiO₂. The FGS-TiO₂ nanocomposites exhibited higher photocatalytic activity compared to pure TiO₂ for the removal of three dyes: such as Methylene Blue (MB), Bromophenol Blue (BB) and Alizarin Red-S (AR) in water. The removal process was fast and more efficient with FGS-TiO₂ nanocomposite in daylight (in the absence of UV irradiation) compared to pure TiO₂ nanoparticles without and under UV in all pH range.