Journal of Environmental Science International (한국환경과학회지)

The Korean Environmental Sciences Society (한국환경과학회)
권호 표지
DOI QR코드

DOI QR Code

Degradation of Dye Wastewater by Advanced Oxidation Process: A Comparative Study

고급산화공정에 의한 안료폐수 처리: 비교 연구

  • Published : 2006.01.01
Download PDF
⟨ Previous Next ⟩

Abstract

The degradation of Rhodamine B (RhB) in water was investigated in laboratory-scale experiments, using five advanced oxidation Processes (AOPs) $UV/H_2O_2$, lenten, photo-lenten, $UV/TiO_2,\;UV/TiO_2/H_2O_2$. The photodegradation experiments were carried out in a fluidized bed photoreactor equipped with an immersed 32 W UV-C lamp as light source. initial decolorization rate and COD removal efficiency were evaluated and compared. The results obtained showed that the initial decolorization rate constant was quite different for each oxidation process. The relative order of decolorization was: photo-fenton > $UV/TiO_2/H_2O_2$ > fenton > $UV/H_2O_2$ > $UV/TiO_2$ > UV > $H_2O_2$. The relative order of COD removal was different from decolorization: photo-fenten ${\fallingdotseq}$ $UV/TiO_2/H_2O_2\;>\;UV/TiO_2\;>\;fenton\;>\;UV/H_2O_2$. The Photo-lenten and $UV/TiO_2/H_2O_2$ processes seem to be appropriate for decolorization and COD removal of dye wastewater.

Keywords

References

  1. 강준원, 박훈수, 최광호, 1995, 이산화티타늄 광촉매에서의 광분해반응에 의한 유기물질 제거에 관한 연구, 대한환경공학회지, 17(3), 283-294
  2. 김태민, 김성준, 이태희, 2001, 광촉매 현탁식 UV/ $TiO_{2}/H_{2}O_{2}$ 시스템을 이용한 페놀의 분해, 대한환경공학회지, 23(3), 396-406
  3. Ollis, S. F., E. Pelizzetti and N. Serpone, 1991, Photocatalyzed destruction of water contam­inants, Environ. Sci. Technol., 25, 1523-1529
  4. 이종현, 이현준, 남해욱, 박태주, 1999, Fenton 산화를 이용한 안료폐수의 유기물, 색도 제거 특성, 대한환경공학회지, 21(5), 1013-1021
  5. Prairie, M. R., L. R. Evans, B. M. Strange and S. L. Martinez, 1993, An investigation of $TiO_{2}$ photocatalysis for the treatment of water con­taminated with matals and organic chemicals, Environ. Sci. Technol., 27(9), 1776- 1782 https://doi.org/10.1021/es00046a003
  6. Dillert, R., A. E. Cassano, R. Goslich and B. Deflft, 1999, Large scale studies in solar catalytic wastewater treatment, Catalysis Today, 54, 267-282 https://doi.org/10.1016/S0920-5861(99)00188-1
  7. Matthews, R. W., 1986, Photo-oxidation of organic material in aqueous suspensions of titanium dioxide, Wat. Res., 20(5), 569-578 https://doi.org/10.1016/0043-1354(86)90020-5
  8. Fox, M. A. and M. T. Dulay, 1993, Heterogeneous photocatalysis, Chem. Rev., 93, 341-357 https://doi.org/10.1021/cr00017a016
  9. Muruganandhaam, M. and M. Swaminathan, 2004, Solar photocatalytic degradation of a re­active azo dye in $TiO_{2}$-suspension, Sol. energy Mater. Sol. Cells, 81, 439-457 https://doi.org/10.1016/j.solmat.2003.11.022
  10. 박영식, 2005, 회전원판 광촉매 반응기(Rotating Dick Photocatalytic Reactor)를 이용한 Rhodamine B의 색 제거, 한국물환경학회지, 21(1), 46-51
  11. 허탁, 이한수, 이호인, 2001, 광촉매와 광 펜턴 산화법을 이용한 6-Hydroxy-2- Isopropyl-4­-Methyl Pyrimidine 폐수의 분해, Applied chemistry, 5(2), 272-275
  12. Piera, E., C. Calpa, E. Brillas, X. Domenech and J. Peral, 2000, 2,4-Dichlorophenoxyacetic acid degradation by catalyzed ozonation: $TiO_{2}/UVA/O_{3}$ and $Fe(2)/UVA/O_{3}$ systems, Applied Catalysis B: Environmental, 27, 169-177 https://doi.org/10.1016/S0926-3373(00)00149-1
  13. 가톨릭대학교, 식품영양정보센터 홈페이지 : http://songsim.catholic.ac.kr/-foonubar/sub/food/food4./htm
  14. 동국대학교, 중소규모사업상을 위한 건강도우마 홈페이지 : http://wwwk.dongguk.ac.kr/-ksg6203/menu5/업종/(1712기고)염색가공업.html
  15. APH-AWWA-WPCE: Standard Methods for the Examination of Water and Wastewater, 18th Ed., APHA, Washington D.C., 1992
  16. 오동규, 윤태일, 1991, Fenton's reagent를 이용한 염색폐수의 처리, 대한환경공학회지, 13(2), 123-132
  17. 정은지, 이규훈, 박태주, 1996, Fenton 산화에 의한 안료폐수의 유기물, 색도 제거, 대한환경공학회 추계학술발표대회 논문집, 456-459
  18. 조일형, 고영림, 이소진, 이홍근, 조경덕, 2000, Fenton 및 Photo-Fenton 산화공정을 이용한 염색 폐수의 처리에 관한 연구, 한국환경위생학회지, 26(4), 29-37
  19. 이근대, 박진환, 안병현, 홍성수, 1998, $TiO_{2}$ 광 촉매에 의한 니트로페놀의 분해, 대한환경공학회지, 20(1), 1599-1610
  20. 김수명, 1998, 난분해성 유기오염물의 화학적 산화를 위한 Photo-fenton-반응의 기초 연구, 대한환경공학회지, 20(10), 1385-1394
  21. Muruganandhaam, M. and M. Swaminathan, 2004, Decolourisation of Reactive Orange 4 by fenton and photo-fenton oxidation technology, Dyes and Pigments, 63, 315-321 https://doi.org/10.1016/j.dyepig.2004.03.004
  22. 안갑환, 권수광, 박영식, 2004, Rhodamine B의 오존 등/광촉매 탈색, 대한환경공학회지, 26(10), 1063-1069
  23. Neamtu, M., A. Yediler, I. Siminiceanu, M. Macoveanu and A. Kettrup, 2004, Decoloriza­tion of disperse red 354 azo dye in water by several process-a comparative study, Dyes and Pigments, 60, 61-684 https://doi.org/10.1016/S0143-7208(03)00129-3
  24. Arslan, I. and A. A. Balcioglu, 1999, De­gradation of commercial reactive dyestuffs by heterogenous and homogenous advanced oxidation processes; a comparative study, Dyes and Pigments, 43, 95-108 https://doi.org/10.1016/S0143-7208(99)00048-0
  25. 강태희, 오병수, 박세준, 강민구, 김종성, 강준원, 2005, 고급산화공정을 이용한 염료폐수의 처리 기술, 한국물환경학회지, 21(3), 267-273
  26. Kang, S. F., C. H. Liao and S. T. Po, 2000, Decolorization of textile wastewater by photofenton oxidation technology, Chemosphere, 41, 1287-1294 https://doi.org/10.1016/S0045-6535(99)00524-X
  27. Kang, S. F., C. H. Liao and H. P. Hung, 1999, Perooxidation treatment of dye manufacturing wastewater in the presence of ultraviolet light and ferrous ions, J. of Hazardous Materials, B65, 317-333