• Title/Summary/Keyword: Nickel (Ni)

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Study of Thermal Stability of Ni Silicide using Ni-V Alloy

  • Zhong, Zhun;Oh, Soon-Young;Lee, Won-Jae;Zhang, Ying-Ying;Jung, Soon-Yen;Li, Shi-Guang;Lee, Ga-Won;Wang, Jin-Suk;Lee, Hi-Deok;Kim, Yeong-Cheol
    • Transactions on Electrical and Electronic Materials
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    • v.9 no.2
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    • pp.47-51
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    • 2008
  • In this paper, thermal stability of Nickel silicide formed on p-type silicon wafer using Ni-V alloy film was studied. As compared with pure Ni, Ni-V shows better thermal stability. The addition of Vanadium suppresses the phase transition of NiSi to $NiSi_2$ effectively. Ni-V single structure shows the best thermal stability compared with the other Ni-silicide using TiN and Co/TiN capping layers. To enhance the thermal stability up to $650^{\circ}C$ and find out the optimal thickness of Ni silicide, different thickness of Ni-V was also investigated in this work.

The Relation of Crystallite Size and Ni2+ Content to Ferromagnetic Resonance Properties of Nano Nickel Ferrites

  • Lafta, Sadeq H.
    • Journal of Magnetics
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    • v.22 no.2
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    • pp.188-195
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    • 2017
  • The ferromagnetic resonance and other magnetic properties dependence on $Ni^{2+}/Fe^{3+}$ ratio and crystallite size were investigated for nano nickel ferrite ($NiFe_2O_4$). The crystallite size was controlled by controlling the nickel content in the starting material solution. The XRD and TEM were utilized to measure the crystallite size through Scherrer formula and particle size respectively. The most frequent particle sizes were lower than crystallite size, which ranged from 16.5 to 44.65 nm. The general behavior of M-H loop shapes and parameters showed superparamagnetic one. The saturation magnetization had a maximum value at $Ni^{2+}/Fe^{3+}$ molar ratio equal to 0.186. The FMR signals showed, generally, broad linewidths, where the maximum width and minimum resonance field were for the sample of the lowest crystalline size. Furthermore, FMR resonance field shows linear dependence on crystalline size. The fitting relation was estimated to express this linear dependency on the base of behavior coincidence between particle size and the inverse of saturation magnetization. The given interpretations to understand the intercept and the slope meanings of the fitted relation were based on Larmor equation, and inhomogeneous in the anisotropy constant.

Electrochemical Oxidation of Ethanol at Nickel Hydroxide Electrodes in Alkaline Media Studied by Electrochemical Impedance Spectroscopy

  • Kim, Jae-Woo;Park, Su-Moon
    • Journal of the Korean Electrochemical Society
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    • v.8 no.3
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    • pp.117-124
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    • 2005
  • Electrochemical oxidation of ethanol at nickel electrodes has been studied in 1 M KOH solution containing 0.20M ethanol using electrochemical impedance spectroscopy. Equivalent circuits have been worked out by simulating the impedance data, and the results were used to model the oxidation of ethanol as well as the passivation of the electrode. The maximum rate of oxidation of $Ni(OH)_2$ to NiOOH was observed at about 0.37V vs. Ag/AgCl reference electrode, while the maximum rate of ethanol oxidation at the Ni electrode was observed at about 0.42V, The charge-transfer resistance for oxidation of the electrode itself became smaller in the presence of ethanol than in its absence. These results suggest that the $\beta-Ni(OH)_2/\beta-NiOOH$ redox couple is acting as an effective electron transfer mediator far ethanol oxidation. The kinetic parameters also were obtained by the experimental and simulated results.

Self-Supported NiSe/Ni Foam: An Efficient 3D Electrode for High-Performance Supercapacitors

  • Zhang, Jingtong;Zhao, Fuzhen;Du, Kun;Zhou, Yan
    • Nano
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    • v.13 no.11
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    • pp.1850136.1-1850136.12
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    • 2018
  • Three-dimensional (3D) mixed phases NiSe nanoparticles growing on the nickel foam were synthesized via a simple one-step hydrothermal method. A series of experiments were carried out to control the morphology by adjusting the amount of selenium in the synthetic reaction. Meanwhile, the as-prepared novel column-acicular structure NiSe exist three advantages including ideal electrical conductivity, high specific capacity and high cycling stability. It delivered a high capacitance of $10.8F\;cm^{-2}$ at a current density- of $5mA\;cm^{-2}$. An electrochemical capacitor device operating at 1.6 V was then constructed using NiSe/NF and activated carbon (AC) as positive and negative electrodes. Moreover, the device showed high energy density of $31W\;h\;kg^{-1}$ at a power density of $0.81kW\;kg^{-1}$, as well as good cycling stability (77% retention after 1500 cycles).

Comparative Study of Ni effect on the Corrosion Behavior of Low Alloy Steels in FGD and Acid Rain Environments (산성비 및 배연탈황설비 환경에서 Ni 첨가에 따른 저합금강의 내식성 비교연구)

  • Han, Jun-Hee;Nguyen, Dang-Nam;Jang, Young-Wook;Kim, Jung-Gu
    • Korean Journal of Metals and Materials
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    • v.47 no.9
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    • pp.558-566
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    • 2009
  • The alloying effect of a small amount of nickel on low alloy steel for application to flue gas desulfurization(FGD) systems was studied. The structural characteristics of the rust layer were investigated by scanning electron microscopy(SEM). The electrochemical properties were examined by means of potentiostatic polarization test, potentiodynamic polarization test, and electrochemical impedance spectroscopy(EIS) in a modified green death solution of 16.9 vol.% $H_2SO_4$+0.35 vol.% HCl at $60^{\circ}C$ and an acid rain solution of $6.25{\times}10^{-5}M\;H_2SO_4+5.5{\times}10^{-3}M\;NaCl$ at room temperature. It was found that as the amount of nickel increased, the corrosion rate increased in the modified green death solution, which seemed to result from micro-galvanic corrosion between NiS and alloy matrix. In acid rain solution, the corrosion rate decreased as the amount of nickel increased due to the repulsive force of $NiFe_2O_4$ rust against $Cl^-$ ions by electronegativity.

Post-annealing Effect of NiO Thin Film Grown by RF Sputtering System on 4H-SiC Substrate (4H-SiC 기판 위에 RF Sputter로 증착된 NiO 박막의 후열처리 효과)

  • Soo-Young Moon;Min-Yeong Kim;Dong-Wook Byun;Geon-Hee Lee;Sang-Mo Koo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.36 no.2
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    • pp.170-174
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    • 2023
  • Nickel oxide is a nonstoichiometric transparent conductive oxide with p-type conductivity, a wide-band energy gap of 3.4~4.0 eV, and excellent chemical stability, making it a very important candidate as a material for bipolar devices. P-type conductivity in Transparent Conductive Oxides (TCO) is controlled by the oxygen vacancy concentration. During the TCO film deposition process, additional oxygen diffusing into the NiO structure causes the formation of Ni 3p ions and Ni vacancies. This eventually affects the hole concentration of the p-type oxide thin film. In this work, the surface morphology and the electrical characteristics were confirmed in accordance with the annealing atmosphere of the nickel oxide thin film.

Corrosion Behavior of Fe-Ni Bainitic Steel Through an Inverted Austempering Multi-Step Process for Weathering Steel Applications

  • Miftakhur Rohmah;Gusti Umindya Nur Tajalla;Gilang Ramadhan;Yunita Triana;Efendi Mabruri
    • Corrosion Science and Technology
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    • v.23 no.1
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    • pp.11-19
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    • 2024
  • A Fe-Ni Bainitic steel as a weathering steel application was developed by combining its excellent mechanical properties and corrosion resistance in maritime environments. Nickel concentration (0.4-3 wt%) and inverted austempering multi-step (IAM) process were primary determinants of the microstructure of the Fe-Ni Bainitic steel. The initial austempering steel was performed at 300 ℃ for 600 seconds to obtain a partly bainitic transformation. The steel was heated again for 1800 s at 450 ℃. The microstructure was comprised of ferrite, a blocky martensite/austenite island, and a homogeneous lath-shape bainite structure with widths ranging from 4.67 to 6.89 ㎛. The maximum strength, 1480 MPa, was obtained with 3 wt% nickel. In this study, corrosion behavior was investigated utilizing potentiodynamic and electrochemical impedance spectroscopy (EIS) tests. A higher nickel content in Fe-Ni Bainitic steel refined the grain size, improved the bainite fraction, lowered the corrosion rate to 0.0257 mmpy, and increased the charge transfer of film resistance to 1369 Ω.

A STUDY ON THE ROOT CANAL MORPHOLOGY CHANGE BY NICKEL-TITANIUM AND STAINLESS STEEL FILE INSTRUMENTATION USING COMPUTERIZED TOMOGRAPHY (Nickel-Titanium file과 Stainless steel file을 이용한 근관형성시 컴퓨터 단층촬영사진상의 근관형태 변화에 관한 연구)

  • So, Mun-Seop;Im, Mi-Kyung;Lee, Keon-Il;Lee, Yong-Keun;Lee, Su-Jong
    • Restorative Dentistry and Endodontics
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    • v.22 no.2
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    • pp.659-669
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    • 1997
  • The goals of root canal instrumentation are complete debridement of pulp tissue, removal of microbes and affected dentin, and proper cleaning and shaping of the root canal space before obturation. Instrumentation with stainless steel files has been shown to produce undesirable results in canals, regardless of the improved technique or modified file type used. Nickel-Titanium(Ni-Ti) alloy has been shown to be exceptionally elastic, having a lower bending moment and lower permanent set after torsion, compared with similar gauge stainless steel. The purpose of this study was to evaluate the change of root canal prepared by Ni-Ti rotary and stainless steel instruments. Thirty-four single rooted teeth of similar shape and canal size were divided into three groups. The teeth were scanned by computed tomography before instrumentation. In group 1, canals were instrumented using a step-back technique with K-file. In group 2, canals were prepared with K-flex file using the same technique as group 1. Group 3 was prepared with nickel-titanium(Ni-Ti) rotary instrument using a manufacture's instruction. Instrumented teeth were again scanned using computed tomography, and reformated images of the uninstrumented canals were compared with images of the instrumented canals. K-flex file and Ni-Ti file caused significantly less canal transportation than K-file in the 8mm root canal section from the apex(p<0.05). K-flex file and Ni-Ti file produced more centered canal preparation than K-file in the 2mm section(p<0.05). Ni-Ti file maintained more precisely the center of the canal than K-flex file in the 10mm section (p<0.05). There was no difference in the removed volume of canals among each groups.

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Electrical properties of polyethylene composite films filled with nickel powder and short carbon fiber hybrid filler

  • Mironov, V.S.;Kim, Seong Yun;Park, Min
    • Carbon letters
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    • v.14 no.2
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    • pp.105-109
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    • 2013
  • Effects of the amount of nickel powder (Ni) in Ni-carbon fiber (CF) hybrid filler systems on the conductivity(or resistivity) and thermal coefficient of resistance (TCR) of filled high density polyethylene were studied. Increases of the resistivity and TCR with increasing Ni concentration at a given hybrid filler content were observed. Using the fiber contact model, we showed that the main role of Ni in the hybrid filler system is to decrease the interfiber contact resistance when Ni concentration is less than the threshold point. The formation of structural defects leading to reduced reinforcing effect resulted in both a reduction of strength and an increase of the coefficient of thermal expansion in the composite film; these changes are responsible for the increases of both resistivity and TCR with increasing Ni concentration in the hybrid filler system.

Mechanochemical synthesis of $LaNiO_3$ from mixtures of $La_2O_3$ and NiO ($La_2O_3$와 NiO의 혼합물로부터 $LaNiO_3$의 메카노케미칼 합성)

  • Kim, Dae-Young;Seo, Byung-Jun;Son, Se-Mo;Kim, Kang-Eun;Chung, Su-Tae
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07b
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    • pp.621-624
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    • 2002
  • Lanthanum nickel oxide$(LaNiO_3)$ powders have been prepared via a mechanochemical processing without any additional heat treatment. When a mixed lanthanum and nickel oxide was mechanically activated for 6 hours with 450 rpm, a stable and single phase perovskite powder was successfully synthesized and its crystallite size of about 90 nm is calculated by using the Scherrer equation.

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