• Title/Summary/Keyword: NiTi-based alloy

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The Wetting and Interfacial Reaction of Vacuum Brazed Joint between Diamond Grit(graphite) and Cu-13Sn-12Ti Filler Alloy (다이아몬드 grit(흑연) / Cu-13Sn-12Ti 삽입금속 진공 브레이징 접합체의 젖음성 및 계면반응)

  • Ham, Jong-Oh;Lee, Chi-Hwan
    • Journal of Welding and Joining
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    • v.28 no.3
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    • pp.49-58
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    • 2010
  • Various alloy system, such as Cu-Sn-Ti, Cu-Ag-Ti, and Ni-B-Cr-based alloy are used for the brazing of diamond grits. However, the problem of the adhesion strength between the diamond grits and the brazed alloy is presented. The adhesion strength between the diamond grits and the melting filler alloy is predicted by the contact angle, thereby, instead of diamond grit, the study on the wettability between the graphite and the brazing alloy has been indirectly executed. In this study, Cu-13Sn-12Ti filler alloy was manufactured, and the contact angles, the shear strengths and the interfacial area between the graphites (diamond grits) and braze matrix were investigated. The contact angle was decreased on increasing holding time and temperature. The results of shear strength of the graphite joints brazed filler alloys were observed that the joints applied Cu-13Sn-12Ti alloy at brazing temperature $940^{\circ}C$ was very sound condition indicating the shear tensile value of 23.8 MPa because of existing the widest carbide(TiC) reaction layers. The micrograph of wettability of the diamond grit brazed filler alloys were observed that the brazement applied Cu-13Sn-12Ti alloy at brazing temperature $990^{\circ}C$ was very sound condition because of existing a few TiC grains in the vicinity of the TiC layers.

Study on the Characteristics of Hydride Heat Pump Using the Zr-based Laves Phase Alloys (Zr-based 합금을 이용한 hydride heat pump의 작동 특성에 관한 연구)

  • Lee, Soo-Geun;Lee, Jai-Young
    • Journal of Hydrogen and New Energy
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    • v.2 no.1
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    • pp.39-46
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    • 1990
  • In order to improve the power of hydride heat pump, prototype heat pump was constructed using $Zr_{0.95}Ti_{0.05}Cr_{0.9}Fe_{1.1}$-$Zr_{0.9}Ti_{0.1}Cr_{0.6}Fe_{1.4}$ which had very good hydrogenation properties. The power changed with operating parameter such as cycle time, air flow rate, and temperature of hot air was investigated. The power shows maximum value with cycle time. The power increased with air flow rate and temperature of hot air. The power of the heat pump was $65-72 Kcal/Kg-alloy{\cdot}h$ under optimum operating condition, which was superior to that the system using $LaNi_{0.9}Al_{0.3}-MmNi_{4.15}Al_{0.66}Fe_{0.2}$ alloy pairs.

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Thermal Stability Improvement or Ni Germanosilicide Using NiPt/Co/TiN and the Effect of Ge Fraction (x) in $Si_{l-x}Ge_x$ (NiPt/Co/TiN을 이용한 Ni Germanosilicide 의 열안정성 향상 및 Ge 비율 (x) 에 따른 특성 분석)

  • Yun Jang-Gn;Oh Soon-Young;Huang Bin-Feng;Kim Yong-Jin;Ji Hee-Hwan;Kim Yong-Goo;Cha Han-Seob;Heo Sang-Bum;Lee Jeong-Gun;Wang Jin-Suk;Lee Hi-Deok
    • Proceedings of the IEEK Conference
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    • 2004.06b
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    • pp.391-394
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    • 2004
  • In this study, highly thermal stable Ni Germanosilicide has been utilized using NiPt alloy and novel NiPt/Co/TiN tri-layer. And, the Ni Germanosilicide Properties were characterized according to different Ge ratio (x) in $Si_{l-x}Ge_x$ for the next generation CMOS application. The sheet resistance of Ni Germanosilicide utilizing pure-Ni increased dramatically after the post-silicidation annealing at $600^{\circ}C$ for 30 min. Moreover, more degradation was found as the Ge fraction increases. However, using the proposed NiPt/Co/TiN tri-layer, low temperature silicidation and wide range of RTP process window were achieved as well as the improvement of the thermal stability according to different Ge fractions by the subsequent Co and TiN capping layer above NiPt on the $Si_{l-x}Ge_x$. Therefore, highly thermal immune Ni Germanosilicide up to $600^{\circ}C$ for 30 min is utilized using the NiPt/Co/TiN tri-layer promising for future SiGe based ULSI technology.

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Development of Ti-Fe-X metal hydride electrode by mechanical alloying (기계적 합금화법에 의한 Ti-Fe-X계 수소 저장합금의 제조에 관한 연구)

  • Ha, Chang-Jin;Lee, Gyeong-Seop
    • Korean Journal of Materials Research
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    • v.5 no.1
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    • pp.112-122
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    • 1995
  • Metal hydride alloys of TiFe based system have been produced by mechanical alloying(MA) method and their electrochemical characteristics have been evaluated for application for Ni/MH battery electrode. These alloys became amorphous after 36hrs ball milling and easily activated electrochemically. All MA amorphous alloys reached at the first charge/discharge cycle the maximum capacity which was 2-3 times higher than the crystalline state. But their cyclic lives were much inferior to the crystalline state. Alloying elements such as Ni, Co, Cr, Mo substituting Fe greatly improved the capacity and 180 mAh/g capacity was obtained in an alloy of TiFe_{0.6}Ni_{0.1}Co_{0.1}Cr_{0.1}Mo_{0.1}$.

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Synthesis of Ni-based Metallic Glass Composite Fabricated by Spark Plasma Sintering (방전플라즈마소결을 이용한 Ni계 비정질 복합재의 제조)

  • Kim, Song Yi;Guem, Bo Kyeong;Lee, Min Ha;Kim, Bum Sung
    • Journal of Powder Materials
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    • v.20 no.1
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    • pp.33-36
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    • 2013
  • A bulk metallic glass-forming alloy, $Ni_{59}Zr_{20}Ti_{16}Si_2Sn_3$ metallic glass powders was used for good commercial availability and good formability in supercooled liquid region. In this study, the Ni-based metallic glass was synthesized using by high pressure gas atomized metallic glass powders. In order to create a bulk metallic glass sample, the $Ni_{59}Zr_{20}Ti_{16}Si_2Sn_3$ metallic glass powders with ball-milled Ni-based amorphous powder with 40%vol brass powder and Cu powder for 20 hours. The composite specimens were prepared by Spark Plasma Sintering for the precursor. The SPS was performed at supercooled liquid region of Ni-based metallic glass. The amorphous structure of the final sample was characterized by SEM, X-ray diffraction and DSC analysis.

Low Temperature Diffusion Brazing of Commercial Pure(CP)-Ti alloy with Zr-based Filler Metal (Zr기 필러메탈을 이용한 상용 순 티타늄(CP-Ti) 합금의 저온 브레이징 특성)

  • Sun, J.H.;Shin, S.Y.;Hong, J.W.
    • Journal of the Korean Society for Heat Treatment
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    • v.29 no.1
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    • pp.1-7
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    • 2016
  • Titanium and its alloys can be usually joined with brazing method. And the alloys should be brazed at low temperature to keep their original microstructure. In this study, the mechanical strength and microstructure of the CP-Ti joint-brazed with $Zr_{54}Ti_{22}Ni_{16}Cu_8$ filler metal having melting temperature of $774{\sim}783^{\circ}C$ were investigated. The tensile strengths of the joint-brazed at $800^{\circ}C$ with $100^{\circ}C/min$ of cooling rate showed more than 400 MPa which was as high as base metal. The $Widmanst{\ddot{a}}tten$ structure consisting of Ti and $Ti_2Ni$ phase was observed in the joint area. However, the tensile strengths of the joint-brazed at $800^{\circ}C$ with $15^{\circ}C/min$ of cooling rate were decreased and the Ti, $(Ti,Zr)_2Ni$ and $Ti_2Ni$ phases were observed at the joint area. It is believed that the $(Ti,Zr)_2Ni$ laves phases could decrease the mechanical strength of the joint and the cooling rate should be controled to get high strength of the titanium joint.

High-temperature Oxidation of Ni-based Inconel 713 Alloys at 800-1100℃ in Air (니켈기 인코넬 713합금의 800-1100℃에서의 대기중 고온산화)

  • Lee, Dong-Bok
    • Journal of Surface Science and Engineering
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    • v.44 no.5
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    • pp.196-200
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    • 2011
  • The Ni-based superalloy, Inconel 713, was oxidized at $800{\sim}1100^{\circ}C$ for 50 and 100 hours in air. It displayed excellent oxidation resistance, forming a few micrometer-thick scales. The major scale was ${\alpha}-Al_2O_3$. Other scales formed were $TiO_2$, $NiAl_2O_4$ and $Cr_2O_3$. Generally, uniform oxidation occurred over the alloy surface, resulting in the formation of ${\alpha}-Al_2O_3$ with and without $Cr_2O_3$. Other oxides such as $TiO_2$ and $NiAl_2O_4$ sometimes also formed. Locally, nodular oxidation occurred at the nodules that consisted of diverse alloying elements. The scales were adherent at $800^{\circ}C$. However, they spalled a little at $900{\sim}1100^{\circ}C$.

Microstructures and Mechanical Properties of Beryllium(Be)-free Ni-Cr-Mo based Alloys for Metal-Ceramic Crown (베릴륨(Be)이 미 첨가된 치과도재소부용 Ni-Cr-Mo계 합금의 미세조직 및 기계적 성질 특성)

  • Song, Kyung-Woo;Go, Eun-Kyoung;Lee, Jung-Hwan;Jung, Jong-Hyun;Noh, Hak;Han, Jae-Ick
    • Journal of Technologic Dentistry
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    • v.28 no.2
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    • pp.321-329
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    • 2006
  • The popularity of Ni-Cr-Mo based metal alloys for metal-ceramic crown have increased recently because of low price, superior yield strength and rigidity. the use of these alloys give them the potential advantage of thinner copping with the required rigidity for long span bridges. The purpose of this study was to assess the microstructures and mechanical properties of Ni-Cr-Mo-(Si,Al,Nb,Zr,Ti.Cu,Mm) based Alloys not containing beryllium(Be) related toxic effects. The abtained results indicated that as-cast these specimen alloys showed compositional and microstructural differences, and mechanical properties values of Ni69Cr20Mo5Si2Al4 alloy among these specimen alloys was found to be superior to those of commercial Ni-Cr based alloy using in market place today.

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Surface roughness changes caused by the galvanic corrosion between a titanium abutment and base metal alloy (티타늄 지대주와 비귀금속 합금사이의 갈바닉 부식에 의한 표면 거칠기 변화 평가)

  • Lee, Jung-Jin;Song, Kwang-Yeob;Ahn, Seung-Keun;Park, Ju-Mi
    • The Journal of Korean Academy of Prosthodontics
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    • v.49 no.1
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    • pp.65-72
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    • 2011
  • Purpose: The purpose of this study was to evaluate the level of electro-chemical corrosion and surface roughness change for the cases of Ti abutment connected to restoration made of base metal alloys. Materials and methods: It was hypothesized that Ni-Cr alloys in different compositions possess different corrosion resistances, and thus the specimens ($13{\times}13{\times}1.5\;mm$) in this study were fabricated with 3 different types of metal alloys, commonly used for metal ceramic restorations. The electrochemical characteristics were evaluated with potentiostat (Parstat 2273A) and the level of surface roughness change was observed with surface roughness tester. Paired t-test was used to compare mean average surface roughness (Ra) changes of each specimen group. Results: All specimens made of nickel-chromium based alloys, average surface roughness was increased significantly (P < .05). Among them, the Ni-Cr-Be alloy ($0.016{\pm}.007\;{\mu}m$) had the largest change of roughness followed by Ni-Cr ($0.012{\pm}.003\;{\mu}m$) and Ni-Cr-Ti ($0.012{\pm}.002\;{\mu}m$) alloy. There was no significant changes in surface roughness between each metal alloys after corrosion. Conclusion: In the case of galvanic couples of Ti in contact with all specimens made of nickel-chromium based alloys, average surface roughness was increased.

Phase Transformation Behaviors of Ni-Ti shape memory Alloys (Ni-Ti 형상기억합금의 상변환 거동 연구)

  • Zhou B.;Oh J.O.;Yoon S.H.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2006.05a
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    • pp.87-88
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    • 2006
  • The phase transformation behaviors of Ni-Ti shape memory alloys were investigated through a DSC(Differential Scanning Calorimetry). The annealing temperatures were applied from $600^{\circ}C,\;700^{\circ}C,\;800^{\circ}C,\;and\;900^{\circ}C$ for their effects on the phase transformation behaviors. Based on the results of DSC, phase transformation behaviors of shape memory alloys can be predicted by Liang's phase transformation model or Tanaka's phase transformation model.

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