• Title/Summary/Keyword: Ni-P/Cr

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The Changes of Solid, Nitrogen and Phosphorus Concentrations in Pig Slurry Stored at Various Depth of Slurry Storage Tank (돼지분뇨슬러리의 액비조내 저장깊이별 고형물 및 질소, 인의 함량분포에 관한 연구)

  • Jeong, Kwang-Hwa;Chung, Eui-Soo;Park, Chi-Ho;Kwag, Jung-Hoon;Choi, Dong-Yoon;Yoo, Yong-Hee
    • Journal of Animal Environmental Science
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    • v.12 no.3
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    • pp.161-168
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    • 2006
  • This paper describes the changes of characteristics of pig slurry according to storing depth. Most of the substances containing pollutants, such as were Management of manure and wastewater from animal confinement facilities is a critical factor for pollution control. With proper treatment processing method in both solid and liquid forms, it can be used as a fertilizer and soil conditioner. In Korea, liquid-manure handling system is very popular because its treatment and application is easy and labor saving. In the storage tank treatment, the period of fermentation process and solids-liquid separation averages six months and the supernatant liquid is being used as a fertilizer. In this study, the changes in chemical characteristics of pig slurry at varying depths of the storage tank were investigated. Results showed that the pH value of the fermented pig slurry was > 7, while the major pollutants such as BOD, SS, N and P were highest in the bottom of the tank. Therefore, the above findings proved that varying depths in the storage tank can influence the concentration of pollutants of the fermented pig slurry.

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Liquid-Composting Conditions of By-product Obtained from Degradation of Animal Carcass for Agriculture Recycling (폐가축사체의 농업적 재활용을 위한 가축사체 액상부산물의 액비화 조건 구명)

  • Seo, Young-Jin;Seo, Dong-Cheol;Kang, Se-Won;Lee, Sang-Gyu;Park, Ju-Wang;Choi, Ik-Won;Sung, Hwan-Hoo;Kang, Seog-Jin;Cho, Ju-Sik
    • Korean Journal of Environmental Agriculture
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    • v.32 no.4
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    • pp.348-354
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    • 2013
  • BACKGROUND: Globally, concern about emerging infectious diseases of livestock is growing. For the disposal of the animal carcass, it is necessary to recycle the carcass into an agriculturally usable product. The objective of this study was to investigate the composting conditions of liquid by-product obtained from degradation of animal carcass. METHODS AND RESULTS: Optimum conditions of liquid fertilizer were investigated using different microorganisms, pHs, and volumes of microorganisms (Lactobacillus rhamnosus+Pichia deserticola). Based on the results from the optimum conditions, compost maturity and quality of liquid fertilizer were evaluated for 112 days. The compost maturity of liquid fertilizer were higher in the order of LP(Lactobacillus rhamnosus + Pichia deserticola) > BC(Bacillus cereus) > BS(Bacillus subtilis). The optimum condition under different volumes of LP was injection of 0.5 mL/100 mL. The compost maturity under different pHs were higher in the order of pH 7 > $$5{\geq_-}9{\frac{._-}{.}}11$$. The liquid by-product at 56 days after composting was completely decomposed. The concentrations of T-N, T-P and $K_2O$ in liquid fertilizer at 56 days were 0.94, 0.17 and 3.78%, respectively, and the sum of those concentrations was 4.89%. CONCLUSION(S): Liquid fertilizer of by-product using pig carcass was decomposed with optimum conditions(LP, pH 7, injection of 0.5 mL/100 mL) in 56 days after composting, and was suitable for official standard of commercial fertilizer.

Geochemical Characteristics of Soil Solution from the Soil Near Mine Tailing Dumps and the Contamination Assessment in Duckum Mine (토양수의 자구화학특성에 따른 금속폐광산 광미야적장주변 토양오염평가: 덕음광산)

  • 이상훈;정주연
    • Economic and Environmental Geology
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    • v.37 no.1
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    • pp.61-72
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    • 2004
  • The soil samples were collected from the paddy field near the mine tailing dumps in the abandoned Duckum mine in Korea. In the laboratory, the soil solution was extracted from the soil using centrifuge, and analysed for the chemical composition. Physical and chemical soil properties were also analysed. Kaolinite is the main clay minerals in the paddy soil and the CEC value is therefore relatively low. Nearly all soil samples show enrichment in their trace elemental concentrations(Cd, Cu, Pb and Zn) compared with natural background level. Some soil samples exceed the soil remediation intervention values for Cd, Pb and Zn and target value for Cu, when compared with Dutch standard, whereas As, Ni and Cr are in normal range. Lead concentrations in some samples near the mine tailing dumps also exceed the standard for remediation act for agricultural area set by Korean soil conservation law. The trace elemental concentrations are higher in the paddy soil nearer the mine tailing dumps and lower for the samples from distance. Similar trend with distance is found for the soil solution chemistry but the decrease with distance from the mine tailing dumps are sharper than the changes in soil chemistry. Cadmium, Cu and Pb concentrations in the soil solution are very low, ranging from a tenth and hundredths to a maximum of several mg/l, whereas their concentrations in soils are highly enriched for natural background. Most of the trace elements are thought to be either removed by reduced iron sulphides or iron oxides, depending on the redox changes. Geochemical equilibrium modelling indicate the presence of solubility controlling solid phases for Cd and Pb, whereas Zn and Cu might have been controlled by adsorption/desorption processes. Although pollutants migration through solution phase are thought to be limited by adsorption onto various Fe, Mn solid phases, the pollutants exist as easily releasable fractions such as exchangeable site. In this case, the paddy soil would act as pollutant pool, which will supply to plants in situ. whenever the geochemical conditions favour.

EFFECT OF VARIOUS RESIN CEMENTS TO THE SHEAR BOND STRENGTH IN THE ADHESION BRIDGE (접착성가공의치에서 세멘트 종류가 전단결합강도에 미치는 영향)

  • Lee, Cheong-Hee
    • The Journal of Korean Academy of Prosthodontics
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    • v.34 no.4
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    • pp.791-799
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    • 1996
  • The purpose of this study was to compare the shear bond strength of adhesion bridge by various resin cements. One hundred and foully 1st premolars were used. The teeth were cut below 2mm from CEJ and the coronal portions were used. The coronal portions were embeded with the acrylic resin and trimmed with sic paper until the flat plane with ${\phi}$ 4mm above acrylic resin sticks in height 5mm were casted with nonprecious metal and the using surfaces were treated with sic paper from #200 to #1200 and polished with alminum oxide paste. And then, the using surfaces were sandblasted and treated with the electrochemical etching. The teeth were divided into three groups of fourty two each. In group I, teeth and specimens were cemented with Panavia 21 In group II, teeth and specimens were cemented with Superbond In group I, teeth and specimens were cemented with All-Bond & composite resin cement Each group was subdivided into three subgroups according to the storage period ; one-day storage, fifteen-day storage, and thirty-day storage. The special jig was made. Then, the specimen and jig were mounted to Instron Universal Testing Machine and the failure were measured. The results were as follows. 1. There was statisfically significant difference between the failure loads of group I and group II and III after one day storage(P<0.01), 2. There was statisfically significant difference between the failure loads of group II and group I and III and between group I and group III at fifteen day storage(P<0.01). 3. There was statisfically significant difference between the failure loads of group I and II and group III after thirty day storage(P<0.01). 4. There was statisfically significant difference between the failure loads of one day storage and fifteen and thirty days storages in group III (P<0.01).

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The Significance of the Distribution Patterns of Certain Elements in the Stream Sediments' of the St. Austell Granite Mass, Cornwall (영국(英國)콘웰주(州)의 성(聖)오우스텔 화강암괴(花崗岩塊)에 대(對)한 지구화학적(地球化學的) 연구(硏究))

  • Lee, Jae Yeong;Olinze, Simon Kaine
    • Economic and Environmental Geology
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    • v.2 no.4
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    • pp.23-71
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    • 1969
  • Sediment samples were taken at about half-mile intervals from all the inajor rivers draining the St. Austell granite mass. The minus 80 mesh(B.S.S.) fraction of each sample was analysed, using semiquantitative methods, for sodium, potassium, lithium, phosphorus, nickel, chromium, tin, tungsten, arsenic copper, zinc and lead. The work was carried out with the view to gaining further information as to the geographical distribution of such different granite facies as might axist, and to investigate the geochemical dispersion of these elements with relation to mineralisation in this area. The sesults confirm Exley's suggestion that the mass consists of two major granite intrusions, the earlier undifferentiated one is joined on the west by a later differentiated intrutive. During the work grid deviation maps proved particularly useful in obtaining data concerning the nature of the granite but frequency diagrams were not particularly helpful. All the known lode areas were associated with stream sediments containing anomalously high concentrations of lode metals and it is concluded that these high concentrations are due premarily to lode material transferred to the streams in the form of tailings lost during milling operations.

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Contents of Inorganic Elements in Shellfish and Geochemical Characteristics of Surface sediments on the West Coast of Korea (서해연안 패류의 성분원소 함량 및 퇴적물의 지화학적 특성)

  • Choi, Yoon Seok;Park, Kwang Jae;Song, Jae Hee;Yoon, Sang Pil;Chung, Sang Ok;An, Kyoung Ho
    • The Korean Journal of Malacology
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    • v.28 no.3
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    • pp.225-232
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    • 2012
  • In order to evaluate the relationship of between the contents of inorganic elements in shellfish and surface sediments, we measured the concentration of inorganic elements (As, Ca, Cd, Cr, Fe, Hg, Li, Mn, Ni, P, Pb, Zn) in various shellfish and surface sediments of research area. The enrichment factor (EF) and the index of accumulation rate (Igeo) of the metals showed that the research areas can be classified as moderately polluted, or unpolluted. And also we measured the geochemical characteristics of surface sediments(grain size, chemical oxygen demand (COD), ignition loss (IL) and acid volatile sulfide (AVS). The grain sizes for research areas of surface sediment were similar the ratio of silt and clay in comparison with other sites. The COD and IL in surface sediment ranged from 5.41 to 14.06 mg/g. d.w. (mean $8.78{\pm}3.16$ mg/g d.w.) and from 0.92 to 3.17% (mean $2.08{\pm}0.86%$), respectively. Siginificant differences in metal concentrations also were determinated in the shellfish tissue among the different sites. However, except for metals(Mn, Zn), which showed some elevation of concentrations, the variations in the shellfish tissue were not related to variations in the sediment.

Reversely Zoned Compositional Variations and their Origins of the Andong Pluton, Andong Batholith, Korea (안동심성암체의 역누대 초성변화와 그 성인)

  • 황상구;이보현
    • Economic and Environmental Geology
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    • v.35 no.1
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    • pp.75-95
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    • 2002
  • The Andong pluton in the Andong Batholith is composed of comagmatic plutonic rocks, in which the lithofacies comprise hornblende biotite tonalite in the central paft biotite granodiorite in the marginal paft and porphyritic biotite granite at the topside (noJthea~tern paft) of the pluton. The pluton is petrographically and petrochemically zoned, having more mafic center than margin and topside. Distribution pallern of the lithofacies represents a reverse zoning in the pluton. Modal and chemical data in the pluton show progressive and gradual compositional variations from the centrer via the margin to the topside. Quartz and K-teldspar increase toward the topside of the pluton, whereas hornblende, biotite and color index increase toward the center. The bulk composition in the pluton is also reversely zoned, with high $Si0_2$ and $K_{2}O$ in the topside facies, and high MnO, CaO, $Ti0_2$, $Fe_{2}O_{3}$t, MgO and $P_{2}O_{5}$ in the central facies. The reverse zoning is also evident in higher Cr. V, Ni, Sc and Sr of the more mafic tonalite in the interior. The reversely zoned pluton results from remobilization (resurgence) of the lower more mafic compositional zone into the upper more felsic zones of the pluton modified by thennogravitational diffusion and fractional crystallization. In the initial stages of evolution, the pluton was a petrochemical system that fonned chemical compositional zonation with mafic tonalitic magma in the lower. granodioritic one in the middle and granitic one in the upper paft of the magma chamber. Periodic influxes of more mafic magma from the ba~e resulted in mingling of liquids and redistribution of minerals, and may have triggered the remobilil.ation of the lower compositional zone into the upper more felsic zones.

A Study on Heavy Metal Concentrations in Waste Water Produced in the Casting Pickling Process at Dental Technical Laboratories (치과기공소 주조체 산세척과정에서 발생하는 폐수내 중금속 농도)

  • Jeong, Da-i;Sakong, Joon
    • Journal of Environmental Health Sciences
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    • v.44 no.1
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    • pp.55-62
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    • 2018
  • Objectives: This study set out to measure the heavy metal concentrations in waste water produced in the casting pickling process at dental technical laboratories and examine the actual state of its treatment. Methods:The investigator measured the concentrations of each heavy metal at 55 dental technical laboratories using an inductively coupled plasma optical emission system. Results: The annual usage of electrolytes was under 10 L in 50 (90.9%), and was 10L or more in five (9.1%) laboratories. Among the laboratories, 15 (27.3%) commissioned the treatment of waste,12 (21.8%) treated the waste with general sewage,and 28 (50.9%) treated the waste in aseptic tank. The arithmetic $mean{\pm}standard$ deviation and the geometric mean of chrome(Cr) were $75.3{\pm}50.9$ and 58.3 mg/L; those of cobalt (Co) were $112.3{\pm}106.7$ and 66.1 mg/L; those of nickel (Ni) were $62.9{\pm}83.5$ and 8.9 mg/L; those of molybdenum (Mo) were $17.1{\pm}13.4$ and 12.0 mg/L; those of iron (Fe) were $31.5{\pm}44.1$ and 6.2 mg/L; those of lead (Pb) were $0.3{\pm}0.3$ and 0.3 mg/L; those of beryllium (Be) were $3.6{\pm}3.6$ and 2.0 mg/L. The hydrogen ion concentration was under pH 2 across all the samples. Conclusions: The findings show that the dental technical laboratories were not doing well with the separation, storage, collection, and treatment of the electrolytes they discarded, and that most of the electrolytes were introduced through the general sewage or aseptic tank. The causes of this include alack of perception among the practitioners at dental technical laboratories and contracted companies avoiding collection for economic reasons. There is a need for education to improve the perceptions of waste water treatment among the practitioners at dental technical laboratories. Environment-related departments should be stricter with legal applications in the central and local governments. It is also required to provide proper management of commissioned treatment.

Changes in sedimentary structure and elemental composition in the Nakdong Estuary, Korea (낙동강 하구역 퇴적구조 및 원소조성 변화에 관한 연구)

  • Kim, Yunji;Kang, Jeongwon;Park, Seonyoung
    • Journal of Wetlands Research
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    • v.23 no.3
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    • pp.213-223
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    • 2021
  • To understand the sedimentary environment of Scirpus planiculmis habitat (Myeongji and Eulsuk tidal flats) in the Nakdong Estuary, this study analyzed the statistical parameters (sorting, skewness, and kurtosis) of grain size data and the major (Al, Fe, Mn, Mg, Ca, Na, K, Ti, and P), minor (Li, Sc, V, Cr, Co, Ni, Cu, Zn, Sr, Zr, Cs, Pb, Th, and U), and rare earth elements (REEs) in sediment cores. For Myeongji, the sediment structure of the upper part of the cores was poorly sorted, more finely skewed, and more leptokurtic due to construction of the West gate. By contrast, the Eulsuk cores all differed due to the contrasting floodgate operation patterns of the West and East gates. The linear discriminate function (LDF) results corresponded to the statistical parameters for grain size. At the Eulsuk tidal flat (sites ES05 and ES11), elemental distributions were representative of Al-, Fe- and Ca-associated profiles, in which the elements are largely controlled by the accumulation of their host minerals (such as Na- and K-aluminosilicate and ferromagnesium silicate) and heavy detrital minerals at the sites. Detrital minerals including the aluminosilicates are major factors in the elemental compositions at ES05, diluting the REE contents. However, clay minerals and Fe-oxyhydroxides, as well as REE-enriched heavy minerals, appeared to be controlling factors of the elemental composition at ES11. Therefore, the mineral fractionation process is important in determining the elemental composition during sedimentation, which reflects the depositional condition of riverine-saline water mixing at both sites.

Agroenvironmental Characteristics and N.P Demand of Paddy Fields Irrigated with the Water of Nagdong River (낙동강 물 관개논의 농업환경 특성과 질소, 인산 요구량)

  • Kang, Ui-Gum;Lee, jae-Saeng;Ko, Ji-Yeon;Park, Chang-Young;Jung, Ki-Yeul
    • Korean Journal of Environmental Agriculture
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    • v.23 no.3
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    • pp.170-177
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    • 2004
  • Agroenvironmental characteristics in paddy fields irrigated with the water of Nagdong river were analyzed along the river watershed for two years from 1999. The sites monitored from upper reaches of the river were Andong, Sangju, Gumi, Goryeong, Changnyeong, Milyang and Pusan. In paddy soils, the contents of heavy metals such as Cd, Cr, Cu, Pb, Ni, Zn and As were around natural values showing the highest values in Pusan followed by Goryeong. In brown rice, the contents of heavy metals were lower than natural values. Soil chemical properties appeared higher values in the lower reaches including Goryeong than the upper ones. The highest parameters in Goryeong were pH ($5.9{\sim}6.1$), EC ($0.8{\sim}0.9\;dS/m$), $Av.P_2O_5$ ($155{\sim}201\;mg/kg$), exchangeable Ca ($6.7{\sim}7.4\;cmol^+/kg$), Mg ($1.92{\sim}2.50\;cmol^+/kg$), K ($0.18{\sim}0.21\;cmol^+/kg$) and those in Pusan were organic matter ($23.0{\sim}29.1\;g/kg$) and T-N ($1.6{\sim}1.8\;mg/kg$). In conclusion, the recommended rates of N fertilizer for rice cropping were 21.4%, 11.8% and 8.8% high for Andong, Sangju and Gumi, respectively and 14.9%, 4.6%, 4.5% and 11.5% low for Goryeong, Changnyeong, Milyang and Pusan, respectively reflecting the chemical properties of soils and the quality of irrigation water on the basis of 110 kgN/ha. In the case of phosphorous, the rates were 18.9% and 33.3% low for Changnyeong and others, respectively on the basis of $45\;kgP_2O_5/ha$. The populations of bacteria, fungi, actinomycetes, Bacillus, fluorescent Pseudomonas and Biomass C were high at the lower reaches including Goryeong, which showed relatively much nutrient contents of organic matter, total N and phosphorous etc.