• Journal of Ceramic Processing Research
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• v.19 no.5
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• pp.413-418
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• 2018

All-solid-state lithium batteries (ASSBs) using inorganic sulfide-based solid electrolytes are considered prospective alternatives to existing liquid electrolyte-based batteries owing to benefits such as non-flammability. However, it is difficult to form a favorable solid-solid interface among electrode constituents because all the constituents are solid particles. It is important to form an effective electron conduction network in composite cathode while increasing utilization of active materials and not blocking the lithium ion path, resulting in excellent cell performance. In this study, a mixture of fibrous VGCF and spherical nano-sized Super P was used to improve rate performance by fabricating valid conduction paths in composite cathodes. Then, composite cathodes of ASSBs containing 70% and 80% active materials ($LiNi_{0.6}Co_{0.2}Mn_{0.2}O_2$) were prepared by a solution-based process to achieve uniform dispersion of the electrode components in the slurry. We investigated the influence of binary carbon additives in the cathode of all-solid-state batteries to improve rate performance by constructing an effective electron conduction network.

• Advances in nano research
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• v.10 no.1
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• pp.43-57
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• 2021

In this study, thermally induced bifurcation buckling of shallow composite cylindrical panels reinforced with aligned single-walled carbon nanotubes is investigated. Distribution of carbon nanotubes across the thickness of the cylindrical panel as reinforcements may be either uniform or functionally graded. Thermo-mechanical properties of the matrix and reinforcements are considered to be temperature dependent. Properties of the cylindrical panel are obtained using a refined micromechanical approach which introduces the auxiliary parameters into the rule of mixtures. The governing equations are obtained by using the static version of the Hamilton principle based on the first-order shear deformation theory and considering the linear strain-displacement relation. An energy-based Ritz method and an iterative process are used to obtain the critical buckling temperature of composite cylindrical panel with temperature dependent material properties. In addition, the effect of various parameters such as the boundary conditions, different geometrical conditions, distribution pattern of CNTs across the thickness and their volume fraction are studied on the critical buckling temperature and buckled pattern of cylindrical panels. It is shown that FG-X type of CNT dispersion is the most influential type in thermal stability.

• Transactions of the Korean hydrogen and new energy society
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• v.32 no.1
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• pp.86-91
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• 2021

In order to save the energy in vehicles using renewable energy, it is necessary to reduce the weight of parts with polymer matrix composites. Carbon nanotube (CNT) is the nano-scale reinforcement used to increase the interlaminar strength of fiber reinforced composites or enhance the fracture toughness of polymer. However, since the degree of improvement in mechanical properties varies according to the various experimental conditions such as shape of reinforcement, types of matrix and dispersion of reinforcement, research to find the optimal conditions is essentially needed. In this study, CNT/epoxy composites with different CNT concentration were fabricated under the same conditions, and the optimal CNT content (2 wt%) was found through Mode 1 fracture toughness test. Furthermore, through optical microscopy, it was confirmed that the fracture toughness was rather decreased due to the CNT aggregation when the CNT content exceeded 2 wt%.

• Advances in nano research
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• v.11 no.6
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• pp.657-665
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• 2021

The present work aimed to explore green approach via aqueous leaves extract of Murraya koenigii (ALEMk) for the synthesis of silver nanoparticles (AgNPsMk) in single step. The synthesis process was visualized with a color change and monitored by employing UV/Visible spectroscopy and a clear peak attained at 420 nm confirming the synthesis of AgNPsMk. The possible functional groups present in the extract which participated in the synthesis of AgNPsMk were identified with the help of FTIR spectroscopy. Further characterization using TEM images revealed the spherical shape of AgNPsMk with average particle size of 20 nm displaying well dispersion throughout the solution. Pronounced antioxidant activities of AgNPsMk at increased concentrations observed which evidencing strong radical scavenging ability. Moreover, AgNPsMk exhibited strong antibacterial behavior when tested against bacterial strains of Escherichia coli and Bacillus subtilis. Moving ahead, in vitro cytotoxicity work revealed potent cell viability loss appearing in AU565 and HeLa cancer cell lines on exposure to AgNPsMk at increased concentration. Finally, in vivo assessment carried out inside male Wistar rats indicated non toxic effect on examined liver tissues besides biochemical analysis including bilirubin, alkaline phosphtase (ALP) and serum glutamate pyruvate transaminase (SGPT) which found within the normal range when compared with control. The prior research work profoundly apprises the potential of green synthesized AgNPsMk to play a significant role in biomedical applications and formulations.

• Advances in nano research
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• v.15 no.2
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• pp.175-189
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• 2023

The under-evaluation structure includes a functionally graded porous (FGP) core which is confined by two piezoelectric carbon nanotubes reinforced composite (CNTRC) layers. The whole structure rests on the Pasternak foundation. Using quasi-3D hyperbolic shear deformation theory, governing equations of a sandwich plate are driven. Moreover, face sheets are subjected to the electric field and the whole model is under thermal loading. The properties of all layers alter continuously along with thickness direction due to the CNTs and pores distributions. By conducting the current study, the results emerged in detail to assess the effects of different parameters on buckling of structure. As instance, it is revealed that highest and lowest critical buckling load and consequently stiffness, is due to the V-A and A-V CNTs dispersion type, respectively. Furthermore, it is revealed that by porosity coefficient enhancement, critical buckling load and consequently, stiffness reduces dramatically. Current paper results can be used in various high-tech industries as aerospace factories.

• Progress in Superconductivity and Cryogenics
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• v.10 no.1
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• pp.1-5
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• 2008

The effect of $BaCeO_3$ doping on the critical current density of YBCO film by TFA-MOD method was studied. $BaCeO_3$ doping was made by two method; one is direct addition of $BaCeO_3$ nano-sized powder prepared by citrate process followed by grinding with planetary ball mill for 10 hours. Another is addition of Ba-Ce precursor solution prepared with Ba-acetate and Ce acetate dissolved in TFA to the YBCO-TFA precursor solution. The film was made by standard dip coating and heat treatment process with conversion temperature of $790^{\circ}C$ in 1000 ppm oxygen containing moisturized Ar gas atmosphere. The direct addition of $BaCeO_3$ powder resulted in YBCO film with good epitaxial growth and no evidence of second phase formation. The addition through precursor solution resulted in the increase of critical current density upto 30 at% doping and uniform dispersion of $BaCeO_3$ fine inclusion was confirmed by SEM-EDX.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2020.06a
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• pp.181-182
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• 2020

In this study, oxidized graphene nanoplatelet(GO) was prepared by oxidizing graphene nanoplatelet(GNP) with nitric acid in order to solve the problem of dispersion of GNP, one of nano materials. GNP/Epoxy and GO/Epoxy were prepared by mixing GNP, GO with 0.1, 0.3, 0.5 and 1.0 wt.% in epoxy and the mechanical properties, bond performance were evaluated. As a result, GNP/Epoxy and GO/Epoxy showed higher tensile strength than Neat Epoxy at the 0.1, 0.3 wt.%. Especially, when 0.1 wt.% of GO was incorporated into epoxy resin, it showed highest tensile strength. It was confirmed that acid treatment of GNP was effective in improving the mechanical properties of epoxy paint. However, graphene material was found that it was not effective in improving the bond strength of the epoxy paint.

• Advances in nano research
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• v.14 no.5
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• pp.463-474
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• 2023

The purpose of this paper is to present the analysis of propagating and evanescent waves in functionally graded (FG) nanoplates with the consideration of nonlocal effect. The analytical integration nonlocal stress expansion Legendre polynomial method is proposed to obtain complete dispersion curves in the complex domain. Unlike the traditional Legendre polynomial method that expanded the displacement, the presented polynomial method avoids employing the relationship between local stress and nonlocal stress to construct boundary conditions. In addition, the analytical expressions of numerical integrations are presented to improve the computational efficiency. The nonlocal effect, inhomogeneity of medium and their interactions on wave propagation are studied. It is found that the nonlocal effect and inhomogeneity of medium reduce the frequency bandwidth of complex evanescent Lamb waves, and make complex evanescent Lamb waves have a higher phase velocity at low attenuation. The occurrence of intersections of propagating Lamb wave in the nonlocal homogeneous plate needs to satisfy a smaller Poisson's ratio condition than that in the classical elastic theory. In addition, the inhomogeneity of medium enhances the nonlocal effect. The conclusions obtained can be applied to the design and dynamic response evaluation of composite nanostructures.

• Advances in nano research
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• v.15 no.4
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• pp.367-384
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• 2023

Natural frequency behavior of graphene platelets reinforced composite (GPL-RC) joined truncated conical-cylindrical- conical shells resting on Winkler-type elastic foundation is presented in this paper for the first time. The rule of mixture and the modified Halpin-Tsai approach are applied to achieve the mechanical properties of the structure. Four different graphene platelets patterns are considered along the thickness of the structure such as GPLA, GPLO, GPLX, GPLUD. Finite element procedure according to Rayleigh-Ritz formulation has been used to solve 2D-axisymmetric elasticity equations. Application of 2D axisymmetric elasticity theory allows thickness stretching unlike simple shell theories, and this gives more accurate results, especially for thick shells. An efficient parametric investigation is also presented to show the effects of various geometric variables, three different boundary conditions, stiffness of elastic foundation, dispersion pattern and weight fraction of GPLs nanofillers on the natural frequencies of the joined shell. Results show that GPLO and BC3 provide the most rigidity that cause the most natural frequencies among different BCs and GPL patterns. Also, by increasing the weigh fraction of nanofillers, the natural frequencies will increase up to 200%.

• Nuclear Engineering and Technology
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• v.56 no.6
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• pp.2141-2152
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• 2024

Tungsten is the most promising plasma facing material for fusion reactors. Rolled W-Y₂(Zr)O₃ bulk material has been successfully produced in this study for future fusion engineering applications. The introduction of Zr is conducive to the refinement of the second phase particles. Nano-sized Y-Zr-O particles are observed in the powder and bulk samples. Related results show that the Y-Zr-O particle dispersion distribution improves the heat load resistance of W-Y₂(Zr)O₃ composite material. For four-point bend experiments in the same sampling direction, the DBTT of W-Y₂(Zr)O₃ composite materials is lower compared to the pure tungsten. For the same material, the DBTT of the material was selected for testing along the RD direction is lower compared to the material was selected for testing along the TD direction. Findings of this study provide suggestions for the subsequent industrial preparation of nanoscale particle-doped tungsten materials.