• 대한임베디드공학회논문지
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• 제2권2호
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• pp.76-81
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• 2007

A novel multi-layer type micro gas sensor for $NO_X$ detection was designed and fabricated. Micro platform defined as type II-1 in this article for micro gas sensor was fabricated using the MEMS technology to meet the demanding needs of lower power consumption. Nano composite materials were fabricated with nanosized tin oxide powder and $\underline{m}$ulti-$\underline{w}$all $\underline{c}$arbon $\underline{n}$ano $\underline{t}$ube (MWCNT) to improve sensitivity. We investigated characteristics of fabricated multi-layer type micro gas sensor with $NO_2$ concentration variations at constant 2.2 V. Sensitivity (S) of micro gas sensor were observed to increase from 2.9, to 7.4 and 11.2 as concentrations of $NO_2$ gases increased from 2.4 ppm, to 3.6 ppm and 4.9 ppm. When 2.4 ppm of $NO_2$ gas was applied, response time and recovery time of micro gas sensor were recorded as 101 seconds and 142 seconds, respectively.

• 한국전기전자재료학회논문지
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• 제28권2호
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• pp.75-79
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• 2015

Ti was deposited on the Al substrate using DC magnetron sputtering with changing the $N_2$ gas for the possible application of a solar absorbing layer. $N_2$ gas ranged from 50 to 75 sccm was systematically applied in the 5 sccm interval and the variation of the absorption rate was investigated. Microstructural examination and elemental analysis indicate that Ti was reacted with $N_2$ gas and formed $TiNO_x$ compound. As compared with the film without any exposure of $N_2$ gas, absorption rate improved by more than 20%. Typically the average absorption of $TiNO_x$ fim with 65% of $N_2$ gas was about 99% in the visible range, and the average absorption was more than 90% in the infrared absorption region respectively.

• 한국재료학회지
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• 제23권9호
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• pp.477-482
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• 2013

We investigated the detection properties of nitrogen monoxide (NO) gas using transparent p-type $CuAlO_2$ thin film gas sensors. The $CuAlO_2$ film was fabricated on an indium tin oxide (ITO)/glass substrate by pulsed laser deposition (PLD), and then the transparent p-type $CuAlO_2$ active layer was formed by annealing. Structural and optical characterizations revealed that the transparent p-type $CuAlO_2$ layer with a thickness of around 200 nm had a non-crystalline structure, showing a quite flat surface and a high transparency above 65 % in the range of visible light. From the NO gas sensing measurements, it was found that the transparent p-type $CuAlO_2$ thin film gas sensors exhibited the maximum sensitivity to NO gas in dry air at an operating temperature of $180^{\circ}C$. We also found that these $CuAlO_2$ thin film gas sensors showed reversible and reliable electrical resistance-response to NO gas in the operating temperature range. These results indicate that the transparent p-type semiconductor $CuAlO_2$ thin films are very promising for application as sensing materials for gas sensors, in particular, various types of transparent p-n junction gas sensors. Also, these transparent p-type semiconductor $CuAlO_2$ thin films could be combined with an n-type oxide semiconductor to fabricate p-n heterojunction oxide semiconductor gas sensors.

• Carbon letters
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• 제1권1호
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• pp.17-21
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• 2000

Catalytic reduction and oxidation of NO over polyacrylonitrile based activated carbon fibers (PAN-ACF) under various conditions were carried out to develop removal process of NO from the flue gas. The effect of temperature, oxygen concentration and the moisture content for the reduction of NO with ammonia as a reducing agent was investigated. The reduction of NO increased with the oxygen concentration, but decreased with the increased temperature. The moisture content in the flue gas affects the reduction of NO as the inhibition of the adsorption of the other components and the reaction on the surface of ACE For the oxidation of NO to $NO_2$ over PAN-ACF without using a reducing gas, it showed the temperature and the oxygen concentration of the flue gas are the important factors for the NO conversion in which the conversion increased with oxygen concentration and decreased with the temperature increase and might be the alternative option for the selective catalytic reduction process.

• 한국가스학회지
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• 제4권2호
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• pp.1-6
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• 2000

가스중에 포함되어 있는 NOx를 안전하게 처리하기 위하여 침상전극을 취부한 플라즈마 반응기를 제작하여 장치의 특성을 실험적으로 조사하여 유효성을 검정하였다. 반응가스는 $NO/N_2$ 혼합가스와 $N_2/O_2$ 혼합가스를 이용하여 초기 NO농도를 설정하고, 유속을 2${\iota}$/min으로 공급하였다. NOx의 반응특성은 방전주입전력이 높을때는 NO의 농도가 감소하였으며, 산소의 농도 증가시에 NO의 분해가 용이하고 NO의 분해에너지 효율이 높았다. 또한 NO의 농도가 증가할 수록 NO의 분해에너지 효율은 높으나 분해율은 낮았다. 오존의 특성은 방전주입전력이 높을수록 오존의 생성이 증가하고, $NO/N_2$의 농도가 증가할 수록 오존의 생성량이 감소하였다.

• 한국가스학회지
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• 제24권4호
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• pp.39-47
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• 2020

배기가스 재순환(flue gas recirculation, 이하 FGR)은 질소산화물 저감에 효과적인 연소 기법으로 저공해 연소 분야에 다양하게 응용되고 있다. 이전 연구에 이어서 메탄/공기 대향류 예혼합화염에 FGR 기법 적용 시 나타나는 화염의 특성 변화 및 NOx 생성기구를 파악하기 위한 수치해석이 진행되었다. 배출되는 질소산화물(NOx)은 4가지 주요 반응경로(열적 NO, prompt NO, N₂H 및 N₂O)로 구분하여 배기가스 재순환율에 따른 각 NO 생성률을 상대적으로 나타내었다. 그 결과 열적 NO가 전체 NO 형성에 가장 크게 차지한 반면 N₂H의 영향은 미미하였다. 또한, 열적 NO의 기여를 검토하기 위하여 본 연구에 사용된 반응기구(UC San Diego mechanism)를 수정하여 재순환율 증가에 따른 NO 배출지수(EINO)를 비교하였다.

• 한국재료학회지
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• 제24권1호
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• pp.19-24
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• 2014

We report the nitrogen monoxide (NO) gas sensing properties of p-type CuO-nanorod-based gas sensors. We synthesized the p-type CuO nanorods with breadth of about 30 nm and length of about 330 nm by a hydrothermal method using an as-deposited CuO seed layer prepared on a $Si/SiO_2$ substrate by the sputtering method. We fabricated polycrystalline CuO nanorod arrays at $80^{\circ}C$ under the hydrothermal condition of 1:1 morality ratio between copper nitrate trihydrate [$Cu(NO_2)_2{\cdot}3H_2O$] and hexamethylenetetramine ($C_6H_{12}N_4$). Structural characterizations revealed that we prepared the pure CuO nanorod array of a monoclinic crystalline structure without any obvious formation of secondary phase. It was found from the gas sensing measurements that the p-type CuO nanorod gas sensors exhibited a maximum sensitivity to NO gas in dry air at an operating temperature as low as $200^{\circ}C$. We also found that these CuO nanorod gas sensors showed reversible and reliable electrical response to NO gas at a range of operating temperatures. These results would indicate some potential applications of the p-type semiconductor CuO nanorods as promising sensing materials for gas sensors, including various types of p-n junction gas sensors.

• 한국대기환경학회지
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• 제7권1호
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• pp.31-40
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• 1991

This study shows the correlation between $NO_x$ emission in the exhaust gas and various operation factors of dual fuel engine for Co-generation system. General tendency was shown that the thermal efficiency was lowered by the change of operation factors. However these were not confirmed on this experiment. Increasing T4 temperature (exhaust gas temperature at turbo-charger inlet) reduces $NO_x$ emission rate. The higher T4 temperature requires lower excess air as the excess air ratio is controlled by T4 temperature on gas mode operation. Another tendency was that $NO_x$ emission rate is reduced in case of increasing boost air temperature, quantity of pilot oil or bypassing flue gas through the exhaust gas boiler. The diameter of the fuel injection nozzle was changed smaller than design value and the injection timing was readjusted. Thus $NO_x$ emission rate could be reduced as retarding injection timing and changing hole diameter of fuel injection nozzle, however maxium engine out-put was decreased by changing fuel nozzle on the diesel mode operation.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2007년도 추계학술대회 논문집
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• pp.117-117
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• 2007

The physical and electrical properties of nitrided Hf-silicate films, incorporated by NO gas annealing, were investigated by XPS, NEXAFS, TEM and C-V measurement. We confirmed the nitrogen incorporation during NO gas annealing treatment effectively enhances the thermal stability of Hf-silicate. The suppression of phase separation was observed in Hf-silicate films with high nitrogen contents. The negative shift of threshold voltage is caused by the incorporation of nitrogen in the hafnium silicate films.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2007년도 춘계학술대회
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• pp.493-496
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• 2007

Korean Institute of Geosciences and Mineral Resources (KIGAM) has studied on gas hydrate in the Ulleung Basin, East sea of Korea since 1997. Most of all, a evidence for existence of gas hydrate, possible new energy resources, in seismic reflection data is bottom simulating reflection (BSR) which parallel to the sea bottom. Here we conducted the conventional data processing for gas hydrate data and Kirchhoff prestack depth migration. Kirchhoff migration is widely used for pre- and post-stack migration might be helpful to better image as well as to get the geological information. The processed stack image by GEOBIT showed some geological structures such as faults and shallow gas hydrate seeping area indicated by strong BSR. The BSR in the stack image showed at TWT 3.07s between shot gather No 3940 to No 4120. The estimated gas seeping area occurred at the shot point No 4187 to No 4203 and it seems to have some minor faults at shot point No 3735, 3791, 3947 and 4120. According to the result of depth migration, the BSR showed as 2.3km below the sea bottom.