• Title/Summary/Keyword: Marine sediments

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Gas hydrate stability field in the southwestern Ulleung Basin, East Sea (동해 울릉분지 남서부 해역에서의 가스 하이드레이트 안정영역)

  • Ryu Byong Jae;Don Sun woo;Chang Sung Hyong;Oh Jin yong
    • The Korean Journal of Petroleum Geology
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    • v.7 no.1_2 s.8
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    • pp.1-6
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    • 1999
  • Natural gas hydrate, a solid compound of natural gas (mainly methane) and water in the low temperature and high pressure, is widely distributed in permafrost region and deep sea sediments. Gas hydrate stability field (GHSF), which corresponds to the conditions of a stable existence of solid gas hydrate without dissociation, depends on temperature, pressure, and composition of gas and interstitial water. Gas hydrate-saturated sediment are easily recognized by the bottom simulating reflector (BSR), a strong-amplitude sea bottom-mimic reflector in seismic profiles. It is known that BSR is associated with the basal boundary of the GHSF, The purpose of this study is to define the GHSF and its occurrence in the southwestern part of Ulleung Basin, East Sea. The hydrothermal gradient is measured using the expandable bathythermograph (XBT) and the geothermal gradient data are utilized from previous drilling results for the adjacent area. By the laboratory work using methane and NaCl $3.0 wt{\%}$ solution, it is shown that the equilibrium pressures of the gas hydrate reach to 2,920.2 kPa at 274.15 K and to 18,090 kPa at 289.95 K for the study area. Consequently, it is interpreted that the lower boundary of the GHSF is about 210 m beneath 400-m-deep sea bottom and about 480 m beneath 1,100-m-deep sea bottom. The resultant boundary is well matched with the depth of the BSR obtained from the seismic data analysis for the study area.

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Estimation of Denitrification in the Ganghwa Tidal Flat by a Pore Water Model (공극수 모델로 추정한 강화도 갯벌의 탈질산화 작용)

  • Na, Tae-Hee;Lee, Tong-Sup
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.10 no.1
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    • pp.56-68
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    • 2005
  • We measured nitrate and other nutrients in sediment pore waters retrieved from three sites at the southern upper-tidal flats of the Ganghwa Island. Denitrification rate is estimated by applying a simple 1-D model to the nitrate profiles. Results from Jangwha and Dongmak sites are $7.8{\sim}9.4{\times}10^{-7}{\mu}mol{\cdot}cm^{-2}{\cdot}sec^{-1}$, and $1.4{\sim}3.6{\times}10^{-7}{\mu}mol{\cdot}cm^{-2}{\cdot}sec^{-1}$, respectively. Rates are comparable to those reported around the world in an order of magnitude. Denitrification was lower in summer. The rates were about 1.5 times higher at site where the surface sediments consist of relatively coarser particles. This implies that particle size would control the reactant supply to the subsurface sediment. One may claim the denitrification as an evidence of the biogeochemical purification function of tidal flat. However, the purification seems not a general attribute of a tidal flat when whole system is scrutinized by a thermodynamic criterion. Currently the term 'tidal flat' is used when describing the diverse coastal wetlands such as salt marshes, sandy tidal flats and muddy tidal flats, which exhibit quite different ecological functions. Thus it is worthy of mentioning that the classification of coastal wetlands on the basis of sedimentological characteristics and biogeochemical functions should facilitate our understanding.

A Study on the Inflowing Pollution Load and Material Budgets in Hampyeong Bay (함평만의 유입오염부하량 및 물질수지에 관한 연구)

  • Kim, Jong-Gu;Jang, Hyo-Sang
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.22 no.1
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    • pp.1-10
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    • 2016
  • In this paper, an analysis of the inflowing pollution load of the rivers in Hampyeong bay showed the average organic matter pollution loads of BOD, COD, and TOC to be 79.7 kg-BOD/day, 144.06 kg-COD/day, and 93.0 kg-TOC/day, respectively. The inflowing organic matter pollution load was the heaviest in Sonbul dike, followed by Jupo bridge and Yangman complex. With regard to season, the load characteristics were outstanding in July, the rainy period in the summer. The average inflowing pollution loads of nutrients were 20.9 kg-DIN/day, 17.1 kg-DIP/day, 148 kg-TN/day, and 37.4 kg-TP/day A comparison of the inflowing nutrients loads for each river showed the load to be the heaviest in Yangman complex, followed by Baegok bridge and Jupo bridge. In the experiment on the material budgets of Hampyeong bridge conducted using a box model, the detention time of fresh water was found to be 52.4 days, with the bay displaying the characteristics of a so dissolved inorganic nitrogen (DIN) in the nutrients material budgets, ${\Delta}DIN$ values were found to be negative, indicating the tendency of consumption and open sea leak by photosynthesis to be higher than the nitrogen that flowed in. As for dissolved inorganic phosphorus (DIP), ${\Delta}DIP$ showed positive values, indicating a tendency for accumulation as the supply through organic matter decomposition, elution load of sediments, and inflowing load of the river turned out to be higher than the consumption by phytoplankton and outflow to open sea.

Marine Terrace of Daebo-Guryongpo-Gampo, SE Korea(II) (대보-구룡포-감포 지역의 해안단구(II))

  • 최성자
    • Economic and Environmental Geology
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    • v.37 no.2
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    • pp.245-253
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    • 2004
  • The 36km-long Daebo-Campo coast has a well-developed marine terraces divided to six steps by elevation of paleoshoreline : 0.5 m(T1), 10 m(T2), 30 m(T3), 40 m(T4), 60 m(T5) and 75 m(T6). The 2$^{nd}$ and 3$^{nd}$ platforms in Daebo to Guryongpo are wider and more distinctive than those of Guryongpo to Gampo. The 3$^{nd}$ terrace of 30 m high is subdivided to two flights as lower(T3b) and upper(T3a) by old sea cliff. Platform age is unclear because of coral fossil free. However, the terrace age could be determined with convergent OSL ages from beach sediments on 2$^{nd}$ step(T2). OSL ages of the terrace of 10 m high range in 60-70 ka. It reveals that the 2$^{nd}$ -step platform correlates to Oxygen Isotope Time scale, substage 5a(ca. 80 ka), and that uplift rate is ca. 0.19 m/ka for 2$^{nd}$ terrace at Daebo-Campo coast. If considering equivalent uplift rate for all terraces since the Late Pleistocene, the 3$^{rd}$ and 4$^{th}$ terraces would be 5e substage and 7 stage. The 30 m-high terrace provides a good indicator for uplift at Daebo-Gampo coast since 125,000 yrs(MIS 5e). It suggests that the local neotectonic deformation might cause an optional uplift rate of ca. 0.19 m/ka along the SE coast of Korea.

The Characteristics of Oxygen Deficient Water Mass in Gamak Bay (가막만 빈산소 수괴의 특성)

  • Kim, Jeong-Bae;Lee, Sang-Yong;Yu, Jun;Choi, Yang-Ho;Jung, Chang-Su;Lee, Pil-Yong
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.9 no.4
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    • pp.216-224
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    • 2006
  • To clarify the formation process and characteristics of oxygen deficient water mass in Gamak Bay, oxygen deficiency was weekly observed from 17 June to 12 September 2005. Surface water temperature was significantly lower in the outer bay than in the inner bay, whereas the bottom water temperature was higher in the central area of bay than in the outer and inner bay. The vertical stratification of water mass was strongly formed during the period, and thermocline was observed between 3 and 5m deep. The oxygen deficiency in the bottom layer began to appear at early July in the inner bay and gradually spread to the center area of the bay in early August. The mean transparency and light attenuation coefficient($K_d$) in water mass was 4.0m and 0.47, respectively. Average concentrations of nutrient and chlorophyll ${\alpha}$ in the bottom layer were significantly higher than those in surface, and those concentrations were significantly higher in the inner bay than in the outer bay. During the formation of oxygen deficiency in the bottom layer, oxygen penetration depth in the bottom sediment were extremely shallow, and oxygen consumption rate in the bottom sediment were lower than that in the area where oxygen deficient water mass disappeared. Dissolved oxygen concentrations in the bottom layer are negatively correlated with nutrient concentrations, whereas those in the surface layer did not show a significant relationship with nutrient concentrations. Elevated loss of oxygen in the bottom water mass was attributed to the increase of the oxygen consumption rates in sediments and the decomposition of organic matter by microorganism.

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Assessment for Effect of Water Environment by Addition of Improvement Agents on Sediments (저질 개선제의 주입에 의한 수 환경에 미치는 영향 평가)

  • Kim Woo-Hang;Kim Do-Hee
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.10 no.1 s.20
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    • pp.69-73
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    • 2004
  • Control if Sediment is very important in prawn farm due to the eruption of toxic materials such as unionized $H_{2}S,\;NH_{3}\;and\;NO_3$. In this study, column test was conducted with filter media such as activated carbon, zeolite, oyster shell and iron chloride to evaluate the reduction of toxicity from sediment. ammonia-N($NH_3$) was effectively removed by Zeolite and oyster shell. It was indicated that ammonium ion($NH_4^+$) was removed by ion exchange of zeolite. And the ammonia in the column of oyster shell was existed as the form of $NH_4^+$, which is not toxic for prawn because oyster shell was stably kept at $8{\sim}9g$ of pH. Therefore, some of ammonia($NH_4^+$) was removed by oyster shell. Hydrogen sulfide and COD were effectively removed by adsorption of activated carbon and a partial removal of hydrogen sulfide was accomplished by Oyster shell. Phosphorous was removed by activated carbon, oyster shell and iron chloride. In prawn farm, the concentration of ammonia was increased with increase of pH by algae photosynthesis in the column of activated carbon, zeolite and iron chloride, but it was revealed that pH was stably kept in the column of oyster shell.

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Reduction of Autochthonous Organics in Masan Bay using a Simple Box Model (마산만의 자생 유기물 저감을 위한 단순 박스모델의 적용)

  • Hong, Sok-Jin;Lee, Won-Chan;Yoon, Sang-Pil;Park, Sung-Eun;Cho, Yoon-Sik;Kwon, Jung-No;Kim, Dong-Myung
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.13 no.2 s.29
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    • pp.111-118
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    • 2007
  • Simple box budgets models are useful tools to understand the phenomena of natural system and to provide an insight into the complex processes including physical, chemical and biological processes occurring in natural system. Budgets of fresh water, salt and nutrients were estimated in order to clarify the characteristics of seasonal material cycle in the Masan Bay. Outflow volume of freshwater into system was approximately $307.4\times10^3\sim1,210\times10^3\;m^3/day$. Inflow masses of DIP and DIN were approximately $410.8\sim795.7\;kg/day$ and $4081.4\sim6525.3\;kg/day$, respectively. DIN is expected to accumulate in the system. The removal of nutrients from bottom sediments will contribute to the reduction of 21.0% of COD concentration in the system.

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Biogeochemistry of Alkaline and Alkaline Earth Elements in the Surface Sediment of the Gamak Bay (가막만 표층퇴적물 중 알칼리 및 알칼리 토금속 원소의 생지화학적 특성)

  • Kim, Pyoung-Joong;Park, Soung-Yun;Kim, Sang-Su;Jang, Su-Jeong;Jeon, Sang-Baek;Ju, Jae-Sik
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.18 no.1
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    • pp.1-13
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    • 2012
  • We measured various geochemical parameters, including the grain size, loss on ignition(LOI), total organic carbon(TOC), total nitrogen(TN), total sulfur(TS) and metallic elements, in surface sediment collected from 19 stations in Gamak Bay in April 2010 in order to understand the sedimentary types, the origin of organic matters, and the distribution patterns of alkali(Li, Na, K, Rb) and alkaline earth(Be, Mg, Ca, Sr, Ba) elements. The surface sediments were mainly composed of mud. The concentrations of Chlorophyll-a, TOC, TN, TS and LOI in sediment were the highest at the cultivation areas of fish and shellfish in the northern and southern parts of the bay. The redox potential(or oxidation-reduction potential) showed the positive value in the middle part of the bay, indicating that the surface sediment is under oxidized condition. The organic materials in sediment at almost all of stations were characterized by the autochthonous origin. Based on the overall distributions of metallic elements, it appears that the concentrations of alkali and alkaline earth elements except Ba in sediment are mainly influenced by the dilution effect of quartz. The concentrations of Sr and Ba are also dependent on the secondary factors such as the effect of calcium carbonate and the redox potential.

The distributional characteristics of the major dissolved artificial radionuclides in the adjacent seas of Korea(I : Yellow Sea) (우리나라 주변해역 주요 인공방사성 핵종 분포 특성 (I: 황해))

  • Chung Chang Soo;Kim Young ill;Moon Deok Soo;Kim Suk Hyun;Park Jun Kun;Seo Seung Mo;Hong Gi Hoon
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.4 no.1
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    • pp.3-13
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    • 2001
  • Dissolved /sup 137/Cs, /sup 239.240/Pu, /sup 238/Pu and /sup 90/Sr contents in winter and spring of the Yellow Sea were determined to describe the distribution of artificial radionuclides. Surface water samples (100 liter) were collected by using a submerged pump, and subsurface samples (>10m depth) were collected using a 10L Niskin water sampler mounted to the Rosette sampler. The levels in the surface water ranged between 1.78~3.38 mBq kg/sup -1/ for /sup 137/Cs, 2.17~13.35 μBq kg/sup -1/ for /sup 239,240/Pu, and 1.97~3.96 mBq kg/sup -1/ for /sup 90/Sr, respectively. In particular, the concentration of /sup 239.240/Pu were 1/10 of those in the vicinity of Changjiang estuary (61~83 μBq kg/sup -1/). The difference of /sup 238.240/Pu concentration between surface and bottom water was <3.0 μBq kg/sup -1/in the Yellow Sea. It suggests that in the Yellow Sea which has shallow and high suspended sediments, /sup 239.240/Pu is preferentially removed from the water columm. The water column inventory of /sup 239.240/Pu in the Yellow Sea constitute about 0.7~0.9 % of the estimated fallout input to the area. The activity ratios of /sup 239.240/Pu//sup 137/Cs and /sup 137/Cs//sup 90/Sr ranged between 0.001~0.005, 0.79~1.65, respectively, and similar to those of open ocean which global fallout is the only source of artificial radionuclides. Therefore, it suggests that most of these artificial radionuclides in the Yellow Sea may be controlled by the atmospheric input.

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Joint Electromagnetic Inversion with Structure Constraints Using Full-waveform Inversion Result (완전파형역산결과를 구조적 제약 조건으로 이용한 고해상도 전자탐사 복합역산 알고리듬 개발)

  • Jeong, Soocheol;Seol, Soon Jee;Byun, Joongmoo
    • Geophysics and Geophysical Exploration
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    • v.17 no.4
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    • pp.187-201
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    • 2014
  • Compared with the separated inversion of electromagnetic (EM) and seismic data, a joint inversion using both EM and seismic data reduces the uncertainty and gives the opportunity to use the advantage of each data. Seismic fullwaveform inversion allows velocity information with high resolution in complicated subsurface. However, it is an indirect survey which finds the structure containing oil and gas. On the other hand, marine controlled-source EM (mCSEM) inversion can directly indicate the oil and gas using different EM properties of hydrocarbon with marine sediments and cap rocks whereas it has poor resolution than seismic method. In this paper, we have developed a joint EM inversion algorithm using a cross-gradient technique. P-wave velocity structure obtained by full-waveform inversion using plane wave encoding is used as structure constraints to calculate the cross-gradient term in the joint inversion. When the jointinversion algorithm is applied to the synthetic data which are simulated for subsea reservoir exploration, images have been significantly improved over those obtained from separate EM inversion. The results indicate that the developed joint inversion scheme can be applied for detecting reservoir and calculating the accurate oil and gas reserves.