• Title/Summary/Keyword: Local corrosion

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Investigation of the Corrosive Chemical Interaction on Antireflective Layers of Solar Cell Multilayers

  • Choe, Seong-Hyeon;Kim, Seon-Mi;Jin, Suk-Yeong;Park, Jeong-Yeong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.187-187
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    • 2011
  • Nowadays, the issue of solar cell durability in local weather and environment is a crucial issue. Above all, surface corrosion on solar cell multilayers is a major factor that determines the durability of commercial solar cells; corrosive chemical interactions between air, humidity and chemical species and solar cell multilayers can unfavorably affect the durability. Here, we study microscopic and spectroscopic surface techniques to investigate the corrosive interaction on the antireflective layers of solar cell multilayers under various conditions such as acid, base, constant temperature and humidity. Surface morphology and adhesion force were characterized with atomic force microscopy before and after chemical treatment. Chemical composition, and transmittance factors were studied with X-ray photoelectron spectroscopy, and ultraviolet-visible spectroscopy, respectively. Based on these studies, we suggest the dominant factors in the corrosive chemical processes, and their influences on the structural, compositional, and optical properties of the antireflective layers.

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A Study on Hydrogen Embrittlement Research on Automotive Steel Sheets (자동차 강재의 수소취성 연구에 대한 고찰)

  • Yang, Won Seog;Seo, Ji Won;Ahn, Seung Ho
    • Corrosion Science and Technology
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    • v.17 no.4
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    • pp.193-201
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    • 2018
  • In order to suppress $CO_2$ emission and protect passengers in case of vehicle collision, continuous efforts are being made to increase the application ratio and tensile strength of advanced high strength steels used in the manufacturing of automotive body. Simultaneously, hydrogen embrittlement which was not a concern in the past has currently become a major issue due to microstructure that is sensitive to hydrogen uptake. The sensitivity increases with residual stress and hydrogen uptake content. Many automotive OEM companies and mill makers are setting specifications to control hydrogen embrittlement. The factors which lead to hydrogen embrittlement are material sensitivity, residual stress, and hydrogen concentration; researches are in progress to develop countermeasures. To reduce material sensitivity, mill makers add high energy trap elements or microstructure refinement elements. Automotive OEM companies design the car parts not to concentrate local stress. And they manage the levels to not to exceed critical hydrogen concentration. In this article, we have reviewed hydrogen embrittlement evaluation methods and corresponding solutions that are being studied in automobile manufacturing industries and mill makers.

Design Modification and Correlation Verification between Reattachment Flow of Dispersed Jet and Local Thinning of Feedwater Heater (충돌로 인해 분산된 2상 제트스팀의 재부착 현상과 국부 감육 상관관계 규명 및 설계개선에 관한 연구)

  • Kim, Hyung-Joon;Kim, Kyung-Hoon;Hwang, Kyeong-Mo
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.21 no.9
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    • pp.483-495
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    • 2009
  • Feedwater heaters of many nuclear power plants have recently experienced severe wall thinning damange, which will increase as operating time progresses. Several nuclear power plants in Korea have experienced wall thinning damage in the area around the impingement baffle-installed downstream of the high pressure turbine extraction stream line-inside number 5A and 5B feedwater heaters. At that point, the extracted steam from the high pressure turbine is two phase fluid at high temperature, high pressure, and high speed. Since it flows in reverse direction after impinging the impingement baffle, the shell wall of the number 5 high pressure feedwater heater may be affected by flow-accelerated corrosion. This paper describes operation of experience and numerical analysis composed similar condition with real high pressure feedwater heater. This study applied squared, curved and new type impingement baffle plates to feedwater heater same as previous study. In addition, it shows difference of pressure distribution and value between single phase and two phase based on experience and numerical analysis.

An Experimental Study on a Solenoid Eddy Current Sensor to inspect Deteriorations in Overhead Distribution Lines (가공 배전선의 열화를 검출하기 위한 솔레노이드 와전류 센서의 실험적 연구)

  • 김성덕
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.13 no.1
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    • pp.77-85
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    • 1999
  • This paper deals with an experirrental study of a nondestructive testing system using a solenoid eddy currnet sensor to inspect deteriorations in overhead distribution lines, such as broken wires, severe local corrosion or zinc loss. Corrosion rrechanisrn for ACSR and ACSR-OC is discussed and characteristics for a solenoid sensor to insprt the georretrical pararreters of the coil and testing materials impOOance are briefly analyzed. A measurement system having a constant current source, a signal processing unit and a motor driver is impIemented. This instrument has such capabilities as detecting the sensor output and estimating dinHlsions of the testing conductors, continuously. As a result, it was shown that the eddy current sensor with an encircling coil could effectively estimate the diatreter change due to deteriorations in overhead distribution lines. lines.

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Sintering Behavior of 7xxx Series Al Blended Powder with Variation of Heating Rate (7xxx계 Al 혼합분말의 승온속도에 따른 소결거동)

  • Kang Shin Pil;Min Kyung Ho;Park Hyun Woo;Chang Si-Young;Kim Young Do
    • Journal of Powder Materials
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    • v.12 no.2 s.49
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    • pp.131-135
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    • 2005
  • 7xxx series Al alloy has the most attractive properties including its excellent high specific strength, stress corrosion cracking and corrosion-resistance. However, in case of the Al-Zn system, the liquid phase has a transient aspect because of the high solid solubility of Zn in Al. Therefore, transient liquid phase sintering behavior was observed during the sintering process. And the amount of liquid and its duration were influenced by the process variables including heating rate and final sintering temperature. At high heating rates($100^{\circ}C/min$), the liquid fraction increased during sintering because diffusion was minimized and therefore local saturation could easily occur. The sintered density increased with increasing heating rate.

Analysis of dislocation density in strain-hardened alloy 690 using scanning transmission electron microscopy and its effect on the PWSCC growth behavior

  • Kim, Sung-Woo;Ahn, Tae-Young;Kim, Dong-Jin
    • Nuclear Engineering and Technology
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    • v.53 no.7
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    • pp.2304-2311
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    • 2021
  • The dislocation density in strain-hardened Alloy 690 was analyzed using scanning transmission electron microscopy (STEM) to study the relationship between the local plastic strain and susceptibility to primary water stress corrosion cracking (PWSCC) in nuclear power plants. The test material was cold-rolled at various thickness reduction ratios from 10% to 40% to simulate the strain-hardening condition of plant components. The dislocation densities were measured at grain boundaries (GB) and in grain interiors of strain-hardened specimens from STEM images. The dislocation density in the grain interior monotonically increased as the strain-hardening proceeded, while the dislocation density at the GB increased with strain-hardening up to 20% but slightly decreases upon further deformation to 40%. The decreased dislocation density at the GB was attributed to the formation of deformation twins. After the PWSCC growth test of strain-hardened Alloy 690, the fraction of intergranular (IG) fracture was obtained from fractography. In contrast to the change in the dislocation density with strain-hardening, the fraction of IG fracture increased remarkably when strain-hardened over 20%. From the results, it was suggested that the PWSCC growth behavior of strain-hardened Alloy 690 not only depends on the dislocation density, but also on the microstructural defects at the GB.

Evaluation of the Burst Pressure for Rectangular Wall-thinning of CANDU Feeder Pipe (사각 감육을 고려한 중수로 공급자관 파열압력 평가)

  • Kwang Soo Kim;Min Kyu Kim;Doo Ho Cho;Jae Joon Jeong
    • Transactions of the Korean Society of Pressure Vessels and Piping
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    • v.17 no.1
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    • pp.28-35
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    • 2021
  • The flow accelerated corrosion (FAC) is one of significant aging and degradation mechanism and can affect structural integrity of CANDU feeder pipes. Pipe burst can occur under normal operation pressure (min. 10 MPa) if wall-thinning of the feeder pipe due to FAC is accumulated. Previous studies considered simple shapes of feeder pipe with local wall-thinning in order to conservatively assess structural integrity of wall-thinned feeder pipe. In this paper, a new FE model is developed, having an actual shape of the feeder pipe (double bent) as well as the actual wall-thinning shape and location based on the in-service inspection result. Then, the burst pressure assessment of the wall-thinned feeder pipe is performed using lower bound limit load analysis considering elastic-perfectly plastic material. In addition, an improved formulation to predict the burst pressure of the wall-thinned feeder pipe is presented and the safety margin is compared with an existing assessment method.

Hydrogen Aging During Hole Expanding Tests of Galvanized High Strength Steels Investigated Using a Novel Thermal Desorption Analyzer for Small Samples

  • Melodie Mandy;Maiwenn Larnicol;Louis Bordignon;Anis Aouafi;Mihaela Teaca;Thierry Sturel
    • Corrosion Science and Technology
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    • v.23 no.2
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    • pp.145-153
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    • 2024
  • In the automotive industry, the hole expanding test is widely used to assess the formability of punched holes in sheets. This test provides a good representation of formability within the framework defined by the ISO 16630 standard. During hole expanding tests on galvanized high strength steels, a negative effect was observed when there was a delay between hole punching and expansion, as compared to performing both operations directly. This effect is believed to be caused by hydrogen aging, which occurs when hydrogen diffuses towards highly-work hardened edges. Therefore, the aim of this study is to demonstrate the migration of hydrogen towards work-hardened edges in high strength Zn-coated steel sheets using a novel Thermal Desorption Analyzer (TDA) designed for small samples. This newly-developed TDA setup allows for the quantification of local diffusible hydrogen near cut edges. With its induction heating and ability to analyze Zn-coated samples while reducing artifacts, this setup offers flexible heat cycles. Through this method, a hydrogen gradient is observed over short distances in shear-cut galvanized steel sheets after a certain period of time following punching.

Supplementation of Flow Accelerated Corrosion Prediction Program Using Numerical Analysis Technique (수치해석 기법을 활용한 FAC 예측 프로그램 보완)

  • Hwang, Kyeong-Mo;Jin, Tae-Eun;Park, Won;Oh, Dong-Hoon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.34 no.4
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    • pp.437-442
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    • 2010
  • Flow-accelerated corrosion (FAC) leads to thinning of steel pipe walls that are exposed to flowing water or wet steam. From experience, it is seen that FAC damage to piping at fossil and nuclear plants can result in outages that require expensive repairs and can affect plant reliability and safety. CHECWORKS have been utilized in domestic nuclear plants as a predictive tool to assist FAC engineers in planning inspections and evaluating the inspection data so that piping failures caused by FAC can be prevented. However, CHECWORKS may be occasionally ignore local susceptible portions when predicting FAC damage in a group of pipelines after constructing a database for all the secondary side piping in nuclear plants. This paper describes the methodologies that can complement CHECWORKS and the verifications of CHECWORKS prediction results using numerical analysis. FAC susceptible locations determined using CHECWORKS for two pipeline groups of a nuclear plant was compared with determined using the numerical-analysis-based FLUENT.

Derivation of the Cathodic Current Density around the HLW Canister Due to the Radiolysis of Groundwater (고준위 폐기물 처분용기 주변에서의 지하수의 방사분해에 의한 음 전류 밀도 유도)

  • Choi, Heui-Joo;Cho, Dong-Keun;Choi, Jong-Won;Hahn, Pil-Soo
    • Journal of Radiation Protection and Research
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    • v.31 no.2
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    • pp.105-113
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    • 2006
  • The oxidizing species are generated from the radiolysis of groundwater in the pore of buffer material around the canister used for the disposal of spent fuels. A mathematical model was introduced to calculate the cathodic current density induced by the oxidant around the canister, which determined the corrosion of carbon steel. An analytical solution was derived to get the cathodic current density in the cylindrical coordinate. The cathodic current densities from both the rectangular coordinate and cylindrical coordinate were compared with each other. The source terms and absorbed dose rate for the calculation of the radiolysis were calculated using the ORIGEN2 and MCNP computer code, respectively. The radius of the canister was determined with the new model in order to prevent the local corrosion. The results showed that the new solution made the cathodic current density around 25 % lower than the Marsh model.