• Title/Summary/Keyword: Local Corrosion

Search Result 245, Processing Time 0.023 seconds

Technological Trends in a local anodization (국부적 양극산화 기술 동향)

  • Kwang-Mo Kang;Sumin Choi;Yoon-Chae Nah
    • Journal of the Korean institute of surface engineering
    • /
    • v.56 no.2
    • /
    • pp.115-124
    • /
    • 2023
  • Anodization is an electrochemical process that electrochemically converts a metal surface into an oxide layer, resulting in enhanced corrosion resistance, wear resistance, and improved aesthetic appearance. Local anodization, also known as selective anodization, is a modified process that enables specific regions or patterns on the metal surface to undergo anodization instead of the entire surface. Several methods have been attempted to produce oxide layers via localized anodic oxidation, such as using a mask or pre-patterned substrate. However, these methods are often intricate, time-consuming, and costly. Conversely, the direct writing or patterning approach is a more straightforward and efficient way to fabricate the oxide layers. This review paper intends to enhance our comprehension of local anodization and its potential applications in various fields, including the development of nanotechnologies. The application of anodization is promising in surface engineering, where the anodic oxide layer serves as a protective coating for metals or modifies the surface properties of materials. Furthermore, anodic oxidation can create micro- and nano-scale patterns on metal surfaces. Overall, the development of efficient and cost-effective anodic oxidation methods is essential for the advancement of various industries and technologies.

The Kinetics of Anodic Dissolution and Repassivation on 316L Stainless Steel in Borate Buffer Solution Studied by Abrading Electrode Technique

  • Xu, H.S.;Sun, D.B.;Yu, H.Y.;Meng, H.M.
    • Corrosion Science and Technology
    • /
    • v.14 no.6
    • /
    • pp.261-266
    • /
    • 2015
  • The capacity of passive metal to repassivate after film damage determines the development of local corrosion and the resistance to corrosion failures. In this work, the repassivation kinetics of 316L stainless steel (316L SS) was investigated in borate buffer solution (pH 9.1) using a novel abrading electrode technique. The repassivation kinetics was analyzed in terms of the current density flowing from freshly bare 316L SS surface as measured by a potentiostatic method. During the early phase of decay (t < 2 s), according to the Avrami kinetics-based film growth model, the transient current was separated into anodic dissolution ($i_{diss}$) and film formation ($i_{film}$) components and analyzed individually. The film reformation rate and thickness were compared according to applied potential. Anodic dissolution initially dominated the repassivation for a short time, and the amount of dissolution increased with increasing applied potential in the passive region. Film growth at higher potentials occurred more rapidly compared to at lower potentials. Increasing the applied potential from 0 $V_{SCE}$ to 0.8 $V_{SCE}$ resulted in a thicker passive film (0.12 to 0.52 nm). If the oxide monolayer covered the entire bare surface (${\theta}=1$), the electric field strength through the thin passive film reached $1.6{\times}10^7V/cm$.

THINNED PIPE MANAGEMENT PROGRAM OF KOREAN NUCLEAR POWER PLANTS

  • Lee, S.H.;Lee, Y.S.;Park, S.K.;Lee, J.G.
    • Corrosion Science and Technology
    • /
    • v.14 no.1
    • /
    • pp.1-11
    • /
    • 2015
  • Local wall thinning and integrity degradation caused by several mechanisms, such as flow accelerated corrosion (FAC), cavitation, flashing and/or liquid drop impingements, are a main concern in carbon steel piping systems of nuclear power plant in terms of safety and operability. Thinned pipe management program (TPMP) had been developed and optimized to reduce the possibility of unplanned shutdown and/or power reduction due to pipe failure caused by wall thinning in the secondary side piping system. This program also consists of several technical elements such as prediction of wear rate for each component, prioritization of components for inspection, thickness measurement, calculation of actual wear and wear rate for each component. Decision making is associated with replacement or continuous service for thinned pipe components. Establishment of long-term strategy based on diagnosis of plant condition regarding overall wall thinning is also essential part of the program. Prediction models of wall thinning caused by FAC had been established for 24 operating nuclear plants. Long term strategies to manage the thinned pipe component were prepared and applied to each unit, which was reflecting plant specific design, operation, and inspection history, so that the structural integrity of piping system can be maintained. An alternative integrity assessment criterion and a computer program for thinned piping items were developed for the first time in the world, which was directly applicable to the secondary piping system of nuclear power plant. The thinned pipe management program is applied to all domestic nuclear power plants as a standard procedure form so that it contributes to preventing an accident caused by FAC.

Study on Stress Recovery Length of 7-Wire Strand due to Local Damage (강연선의 국부적 손상에 따른 응력 회복길이 분석 연구)

  • Seo, Dong-Woo;Kim, Byung-Chul;Jung, Kyu-San;Na, Wongi;Park, Ki-Tae
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.18 no.12
    • /
    • pp.150-156
    • /
    • 2017
  • This study examined the stress recovery length due to the local damage of a 7-wire strand, which is applied widely to PSC (Post Tensioned Concrete) bridges and cable-stayed bridges. The 7-wire strand is a multiple stranded steel of PC prestressing strand. Owing to the nature of the material, it is damaged continuously after completion with corrosion being the main cause of damage. On the other hand, due to its structural characteristics, it is difficult to grasp the degree of damage inside the cable and the pattern of stress variation. In the case of cables applied to bridges, the parts that are susceptible to corrosion are generated depending on the water supply and installation shape, which may cause local damage. This study analyzed the tendency of performance degradation and stress recovery length according to local damage of a 7-wire strand, which is applied mainly to bridge post-tensioning or stay cables. This study developed a computer-based simulation model that was validated with experimental results. The model developed in this study can be used to evaluate the safety level and estimate the remaining life span of P SC bridges or cable-stayed bridges.

Structural Characteristics and Field Application of 'Delta Deck' Composite Bridge (복합소재 교량 바닥판 '델타데크'의 구조적 특성과 현장적용)

  • 이성우;박신전;김병석;정규상
    • Proceedings of the Computational Structural Engineering Institute Conference
    • /
    • 2004.04a
    • /
    • pp.201-208
    • /
    • 2004
  • To substitute conventional reinforced-concrete bridge deck, glass composite precast bridge deck - Delta Deck/sup TM/, which possesses advantages of light weight, high strength, corrosion resistance and durability, is developed for the DB24 truck load. Pultruded composite bridge deck is designed and fabricated. To verify serviceability and structural safety, finite element analysis, structural testing such as flexural test, local fatigue test, flexural fatigue test and field tests are conducted. In this paper structural characteristics of developed deck and its field application in Korea is presented.

  • PDF

Characteristics of Pyrophyllite Aggregate fired at Low Temperature(II) (저온소성 납석질 벽돌의 특성에 관한 연구(저온소성 ladle용 벽돌의 개발연구 제이보))

  • 지응업;한기성;최상욱
    • Journal of the Korean Ceramic Society
    • /
    • v.12 no.2
    • /
    • pp.3-9
    • /
    • 1975
  • The continuous grading method of pyrophyllite particles was adopted to prepare the refractories for ladle. The optimum conditions of fabrication adjusting the binders, the amount of water, the forming pressure and the firing temperature were investigated. The various properties, such as strength, density, porosity, thermal shock, corrosion resistance to slag were measured and compared with properties of ladle bricks presently used at local steel plants. The specimen studied in the present investigation showed a rather superior properties to theconventional product available locally.

  • PDF

Relationship Between Local Wall Thinning and Velocity Components of Deflected Turbulent Flow Inside the Tee Sections of Carbon Steel Piping (탄소강 배관 티에서 편향 난류유동에 따른 속도성분과 국부감육의 상관관계)

  • Kim, Kyung-Hoon;Hwang, Kyeong-Mo;Kang, Deok-Won
    • Transactions of the Korean Society of Mechanical Engineers B
    • /
    • v.35 no.7
    • /
    • pp.717-722
    • /
    • 2011
  • The aim of this study is to identify the locations at which local wall thinning occurs and to determine the turbulence coefficients related to local wall thinning. Experiments and numerical analyses of the tee sections of different down-scaled piping components were performed and the results were compared. Numerical analyses of full-scale models of actual plants were performed in order to simulate the flow behaviors inside the piping components. In order to determine the relationship between the turbulence coefficients and the rate of local wall thinning, numerical analyses of the tee components in the main feedwater systems were performed. The turbulence coefficients obtained from the numerical analyses were compared with the local wear rate obtained from the measurement data. From the comparison of the results, the vertical flow velocity component (Vr) flowing to the wall after separating in the wall due to the geometrical configuration and colliding with the wall directly at an angle of some degree was analogous to the configuration of local wall thinning.

Finite Element Analysis for Wall Thinned Steam Generator Tubes (감육된 증기발생기 전열관의 유한요소 해석)

  • Seong, K.Y.;Ahn, S.H.;Nam, K.W.
    • Journal of Power System Engineering
    • /
    • v.10 no.3
    • /
    • pp.38-44
    • /
    • 2006
  • Failure assessment of steam generator tube are very important for the integrity of energy plants. In pipes of energy plants, sometimes, the local wall thinning may result from severe erosion-corrosion damage. Recently, the effects of local wall thinning on fracture strength and fracture behavior of piping system have been well studied. In this paper, the elasto-plastic analysis is performed by FE code ANSIS on steam generator tube with wall thinning. We evaluated the failure mode, fracture strength and fracture behavior from FE analysis. It was possible to predict the crack initiation point by estimating true fracture ductility under multi-axial stress conditions at the center of the thinned area.

  • PDF

ELECTRICAL BREAKDOWN INITIATION OF ANODIC FILMS DURING ANODIZING IN MOLTEN BISULPHATE MELT

  • Han, S.H.;Thompson, G.E.
    • Journal of the Korean institute of surface engineering
    • /
    • v.32 no.3
    • /
    • pp.341-343
    • /
    • 1999
  • The morphology and composition of anodic films, formed on aluminium at various current densities, in the range $1-100{\;}Am^{-2}$, in the molten bisulphate melt at different temperatures (418-498K), have been studied using transmission electron microscopy of ultramicrotomed film sections, and ion beam thinned films. The first sign of incipient breakdown revealed by transmission electron microscopy of stripped films, is always the appearance of dark regions about 1,000 nm in diameter, representing local overgrowth of the film. The breakdown mechanism is closely related to thermal effects, because temperature rises at regions representing local overgrowth in the stripped films were observed at voltages close to the breakdown voltage, likely arising through impact ionization.

  • PDF

Life-Cycle Cost-Effective Optimum Design of Steel Bridges Considering Environmental Stressors (환경영향인자를 고려한 강교의 생애주기비용 최적설계)

  • Lee, Kwang Min;Cho, Hyo Nam;Cha, Cheol Jun
    • Journal of Korean Society of Steel Construction
    • /
    • v.17 no.2 s.75
    • /
    • pp.227-241
    • /
    • 2005
  • This paper presents a practical and realistic Life-Cycle Cost (LCC) optimum design methodology for steel bridges considering the long-term effect of environmental stressors such as corrosion and heavy truck traffics on bridge reliability. The LCC functions considered in the LCC optimization consist of initial cost, expected life-cycle maintenance cost, and expected life-cycle rehabilitation costs including repair/replacement costs, loss of contents or fatality and injury losses, road user costs, and indirect socio-economic losses. For the assessment of the life-cycle rehabilitation costs, the annual probability of failure, which depends upon the prior and updated load and resistance histories, should be accounted for. For the purpose, Nowak live load model and a modified corrosion propagation model, which takes into consideration corrosion initiation, corrosion rate, and repainting effect, are adopted in this study. The proposed methodology is applied to the LCC optimum design problem of an actual steel box girder bridge with 3 continuous spans (40m+50m+40m=130m). Various sensitivity analyses are performed to investigate the effects of various design parameters and conditions on the LCC-effectiveness. From the numerical investigation, it has been observed that local corrosion environments and the volume of truck traffic significantly influence the LCC-effective optimum design of steel bridges. Thus, these conditions should be considered as crucial parameters for the optimum LCC-effective design.