• Title/Summary/Keyword: Liquid Coating

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Study on the Optimized Condition of the Slot-Die Coating Process (슬롯다이 코팅의 최적화 조건에 관한 연구)

  • Seo, Eung Soo;Ye, Jungwoo;Hwang, Joong Kook;Shim, Jaesool;Chai, Young Suck
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.39 no.9
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    • pp.937-945
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    • 2015
  • In this paper, we study the coating performance according to the slot-die conditions in the coating process. The quality of the slot-die coating depends on factors such as feeding speed of film, the viscosity of liquid, and the pressure applied to the slot-die. In this study, we determine the optimum conditions for a stable coating by performing 2-D and 3-D simulations. We carry out numerical simulations with respect to the feeding velocity of the film, the pressure of the slot-die inlet, and the viscosity of the coating liquid. Based on the results, the coating was the most reliable when the pressure of the inlet was $5kgf/cm^2$, the viscosity was about 100 cps and the velocity was 20 m/min.

Polarity-tuned Gel Polymer Electrolyte Coating of High-voltage LiCoO2 Cathode Materials

  • Park, Jang-Hoon;Cho, Ju-Hyun;Kim, Jong-Su;Shim, Eun-Gi;Lee, Yun-Sung;Lee, Sang-Young
    • Journal of the Korean Electrochemical Society
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    • v.14 no.2
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    • pp.117-124
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    • 2011
  • We demonstrate a new surface modification of high-voltage lithium cobalt oxide ($LiCoO_2$) cathode active materials for lithium-ion batteries. This approach is based on exploitation of a polarity-tuned gel polymer electrolyte (GPE) coating. Herein, two contrast polymers having different polarity are chosen: polyimide (PI) synthesized from thermally curing 4-component (pyromellitic dianhydride/biphenyl dianhydride/phenylenediamine/oxydianiline) polyamic acid (as a polar GPE) and ethylene-vinyl acetate copolymer (EVA) containing 12 wt% vinyl acetate repeating unit (as a less polar GPE). The strong affinity of polyamic acid for $LiCoO_2$ allows the resulting PI coating layer to present a highly-continuous surface film of nanometer thickness. On the other hand, the less polar EVA coating layer is poorly deposited onto the $LiCoO_2$, resulting in a locally agglomerated morphology with relatively high thickness. Based on the characterization of GPE coating layers, their structural difference on the electrochemical performance and thermal stability of high-voltage (herein, 4.4 V) $LiCoO_2$ is thoroughly investigated. In comparison to the EVA coating layer, the PI coating layer is effective in preventing the direct exposure of $LiCoO_2$ to liquid electrolyte, which thus plays a viable role in improving the high-voltage cell performance and mitigating the interfacial exothermic reaction between the charged $LiCoO_2$ and liquid electrolytes.

Synthesis of PSSQs Siloxane Resin Polymer Using Monomolecular Fluoro Silane

  • Bae, Jae Young;Mun, Han Jun;Kim, Tae Ho;Park, Hyun Ho
    • Elastomers and Composites
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    • v.55 no.2
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    • pp.103-107
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    • 2020
  • Herein, resin-formed polysilsesquioxanes (PSSQs) were synthesized using monomolecular fluoro silane as a precursor. The synthesized PSSQs exhibited anti-smudge performance and were used as coating liquid. Two structures were acquired by controlling the amount of the silane precursor and the K2CO3 catalyst; these materials were used to prepare the anti-smudge coating liquid solution. The synthesized product was analyzed by various methods such as nuclear magnetic resonance spectroscopy, X-ray diffraction analysis, gel permeation chromatography, and water contact angle measurement. The results confirmed that the as-synthesized PSSQs exhibited the ladder structure and had a molecular weight of 5,117 g/mol and water contact angle of 102.31°.

A Study on Optimal Dye-coating Conditions to Reduce Dye-adsorption Time with Improved DSSC Efficiency

  • Seo, Yeong-Ho;Choe, Eun-Chang;Hong, Byeong-Yu
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.481.1-481.1
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    • 2014
  • Dye-sensitized solar cell (DSSC) has been extensively investigated as the next generation energy source. Despite attractive features of simple fabrication process and its economical efficiency, there are some problems such as low efficiency and low long-term stability. Many groups have attempted the proposed way to improve the cell efficiency and long-term stability such as low recombination rate between $TiO_2$ surface and electrolyte, the development of new dye molecules capable of light adsorption as broadly as possible, the fabrication of a solid-state DSSC by replacing the liquid electrolyte, and protective coating on glass. In this work, we confirmed new dye-coating conditions to maximize the dye adsorption between the dye and $TiO_2$ nanoparticle surface. The experiment results coating conditions with the coating temperature of $70^{\circ}C$, the dye concentration of 10 mM and the coating time of 3 min. Conditions have two times, three times cycle the experiment in progress efficiency rises.

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Liquid Crystal Orientation on LaGaO Thin Films Induced by a Brush Coating Process (브러시 코팅 공정에 의해 유도된 LaGaO 박막의 액정 배향)

  • Byeong-Yun Oh
    • Journal of IKEEE
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    • v.28 no.3
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    • pp.261-270
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    • 2024
  • In this study, a lanthanum gallium oxide (LaGaO) solution was prepared using a sol-gel method. By simply forming a LaGaO thin film through adjusting the curing temperature after applying the solution onto the substrate using a brush coating process, the potential for use as a liquid crystal (LC) alignment film in the LC display industry was validated. Through optical microscope observation, it was confirmed that the LC molecules were uniformly aligned as the curing temperature of the LaGaO thin film increased. It was confirmed that the LaGaO thin film cured at 230℃ had low pretilt angle, and that LaGaO particles were formed in a single direction as observed through an atomic force microscope. Through X-ray photoelectron spectroscopy, it was found that the LaGaO metal oxide thin film was well formed. Finally, it has been confirmed that LaGaO metal oxide has the potential as a novel LC alignment film material, as it exhibits excellent electrical and optical properties, along with high optical transmittance.

Comparative study of color reproducibility of zirconia using a dipping method and coating method (도포법 및 침전법을 이용한 지르코니아의 색조 재현성 비교 연구)

  • Lee, Hee-Jung;Kim, Jae-Hong;Kim, Woong-Chul;Kim, Ji-Hwan;Kim, Hae-Young
    • Journal of Technologic Dentistry
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    • v.35 no.3
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    • pp.185-192
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    • 2013
  • Purpose: The aim of this study was to compare with color reproducibility of the coating method and dipping method using a colour liquid. Methods: Two groups of square-shaped specimens ($10mm{\times}10mm$ in diameter, 1.5mm thickness) were prepared for analysis(n=15/group). The CM(Coating Method) group was fabricated as full zirconia specimens with the coating coloring method and Group DM(Dipping Method) was prepared as specimens of 0.7 mm-thick zirconia plate using the dipping coloring method and veneered with 0.8mm-thick porcelain. Color parameters were measured with ShadeEye $NCC^{(R)}$ spectrophotometer and color differences were calculated using the equation ${\Delta}E^*= \{({\Delta}L^*)^2+({\Delta}a^*)^2+({\Delta}b^*)^2\}^{1/2}$. Non-parametric statistical methods, the Mann-Whitney test, and the Kruskal-Wallis test were used to analyze the data. Type one error rate was set at 0.05. Results: Color difference values larger than 7 were observed between specimens with the coating method and the dipping method, which were detectable difference in a clinical setting. Conclusion: Cautious application of the coating coloring method in a clinical setting and further researches to standardize the coating method are needed.

Suppression of the surface nucleation of YBa$_2$Cu$_3$O$_7-y$ by CeO$_2$ coating of the top-seeded melt processed YBCO superconductors

  • Kim, Ho-Jin;Jun, Byung-Hyuk;Kim, Chan-Joong
    • Progress in Superconductivity and Cryogenics
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    • v.5 no.3
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    • pp.1-5
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    • 2003
  • The effect of CeO$_2$ coating on the surface nucleation of the top-seeded melt-growth processed YBCO superconductors was studied. It was effective that the coating of Y123 compact surfaces by CeO$_2$ powder suppressed the undesirable subsidiary YBa$_2$Cu$_3$O$_{7-y}$ (Y123) nucleation during melt processing. BaCeO$_3$ was formed in the CeO$_2$-coated layers, which might cause a CuO-excessive liquid at the partial melt stage of $Y_2$BaCuO$_{5}$(Y211) plus liquid, and thus the Y123 nucleation at the YBCO compact surfaces could be suppressed during the melt growth of Y123 grain. In addition, the CeO$_2$ refined the Y211 particles near the compact / coating interface. While the levitation forces of the top surfaces with and without CeO$_2$ coating were similar to each other, the levitation force of the interior of the CeO$_2$ coated sample was higher than that of the interior of the sample without CeO$_2$ coating, which was attributed to the suppression of subsidiary Y123 nucleation at the compact walls.s.s.

Synthesis and Evaluation of Superhydrophobic ODA/PDMS Dip Coating on PET for Liquid-Solid Contact Electrification (액체-고체 접촉대전을 위한 PET 기판 기반 ODA/PDMS 딥 코팅 제조 및 평가)

  • Park, Sunyoung;Kang, Hyungyu;Byun, Doyoung;Cho, Dae-Hyun
    • Tribology and Lubricants
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    • v.37 no.2
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    • pp.71-76
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    • 2021
  • As opposed to using fossil fuels, we need to use eco-friendly resources such as sunlight, raindrops and wind to produce electricity and combat environmental pollution. A triboelectric nanogenerator (TENG) is a device that converts mechanical energy into electricity by inducing repetitive contact and separation of two dissimilar materials. During the contact and separation processes, electron flow occurs owing to a change in electric potential of the contacting surface caused by contact electrification and electrostatic induction mechanisms. A solid-solid contact TENG is widely known, but it is possible to generate electricity via liquid-solid contact. Therefore, by designing a hydrophobic TENG, we can gather electricity from raindrop energy in a feasible manner. To fabricate the superhydrophobic surface of TENGs, we employ a dip coating technique to synthesize an octadecylamine (ODA)- and polydimethylsiloxane (PDMS)-based coating on polyethylene terephthalate (PET). The synthesized coating exhibits superhydrophobicity with a contact angle greater than 150° and generates a current of 2.2 ㎂/L while water droplets fall onto it continuously. Hence, we prepare a box-type TENG, with the ODA/PDMS coating deposited on the inside, and place a 1.5 mL water droplet into it. Resultantly, we confirm that the induced vibration causes continuous impacts between the ODA/PDMS coating and the water, generating approximately 100 pA for each impact.

Characteristics on Spray Cooling Performance on the Micro-Porous Coated Surfaces (마이크로다공성 발열체 표면에서의 액체분무 냉각성능 특성)

  • Kim Yoon-Ho;Choi Chi-Hwan;Lee Kyu-Jung
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.18 no.4
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    • pp.304-311
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    • 2006
  • Experiments on evaporative spray cooling on the square plate heaters with plain or micro-porous coated surfaces were performed in this study. Micro-porous coated surfaces were made by using DOM [Diamond particle, Omegabond 101, Methyl-Ethyl-Keton] method. In case of purely air-jet cooling, the micro-porous coating doesn't affect the cooling capacity. In spray cooling three different flow patterns (complete wetting, evaporative wetting, dryout) are observed on both plain and micro-porous coated surfaces. The effects of various operating conditions, such as water flow rate, particle size, and coating thickness were investigated on the micro-porous coated surfaces. It is found that the level of surface wetting is an important factor to determine the performance of spray cooling. It depends on the balance between absorbed liquid amount by capillary force over porosity and the evaporative amount. The micro-porous coated surface has largest cooling capacity, especially in the evaporative wetting zone. It is found that the effects of liquid flow rate and coating thickness are significant in evaporative wetting zone, but are not in complete wetting and dryout zones.

A Study on Preparation of Alumina Membranes(2) (알루미나 한외여과막의 제조에 관한 연구(2))

  • 유재근;이응상
    • Journal of the Korean Ceramic Society
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    • v.31 no.4
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    • pp.359-366
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    • 1994
  • Tow types of supports were made using $\alpha$-Al2O3 powder and optimum conditions to prepare for supports were provided. Sol solution for coating was synthesized by sol-gel method with aluminum isopropoxide. Supports were coated and heat-treatemented, where the thickness of coating layer was controlled by dipping time. Flux and permeability of alumina membrane were measured by liquid and gas filtration apparatus and these were compared with the provided model. It was confirmed that the coating was done very well without micro~crack and defect.

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