• Resources Recycling
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• v.3 no.3
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• pp.32-49
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• 1994

Hydration process is one of the basic carbonation system. Limestone sludge produced in Pohang Iron & Steel Co., Ltd. We tested for identify of hydration characteristics. The result obtained in this study can be summarized as follows; 1. The classify of limestone sludge is type of ground calcium carbonate(-3mm+325mesh)and the major mineral of calcite, and further more high grade(CaO 51%), fine powder(15~22$\mu\textrm{m}$). 2. Limestone sludge mixed two process sludge, first one is washing process sludge and the other one is wet collect kiln dust. The composition rate is about 8:2. Wet collect kiln dust is major mineral of calcite, too. But the sludge is assumed to one by quick lime, slaked lime and unreacted natural limestone. So, the ideal process is dividing of the washing process sludge and wet collect kiln dust. 3. We manufactured of slaked lime from limestone sludge. To investigate the effect of hydration reactor, the experiments was done with various reactor type as magnetic stirrer, shaking incubator and ultrasonic vibration reactor, respectively. Generally, ultrasonic vibration reactor is excellent hydration for limestone sludge and produced very fine slaked lime powder with ideal distribution. 4. The optimum condition is 10% pulp density, when the manufacture of fine slaked lime powder by ultrasonic vibration reactor. And hydration times to compare the results of the study with ultrasonic vibration reactor of generalized most short time(5~10 min). 5. Finally, the dispersive characteristics of slaked lime powder measured 1~5 $\mu\textrm{m}$ from limestone sludge were compared with those of natural limestone ones(10~20$\mu\textrm{m}$), in order to check applicability of slaked lime with hydration process from limestone sludge.

• Proceedings of the Korea Concrete Institute Conference
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• 2001.11a
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• pp.935-938
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• 2001

This paper reports the relation of concrete setting characteristic and lateral pressure in mass concrete wall such as side wall of LNG underground storage tank. In order to estimate the lateral pressure, initial setting time of low heat cement concrete with type of mineral admixture was measured for three concrete mixtures(W/P=41.6%) containing limestone powder, fly ash, and slag powder. As a result, the lateral pressure of the concrete containing limestone powder was the smallest than those of other concretes as well as the initial setting time.

• Proceedings of the Korea Concrete Institute Conference
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• 2010.05a
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• pp.199-200
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• 2010

This paper was estimated the diffusion coefficient through the chlorine ion diffusion coefficient of the high fluidity concrete using the limestone powder. Also, the micro void of high fluidity concrete examined according to the mixing ratio of the limestone powder by the mercury intrusion porosimetry.

• Journal of Korean Society on Water Environment
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• v.23 no.1
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• pp.81-86
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• 2007

This paper describes a study on the role of limestone which might affect the dissolution of phosphates when phosphate containing sediments are put under anaerobic conditions. A small quantity of calcium hydroxy-apatite, alone or mixed with limestone powder, was put in contact with aqueous solution of acetic acid or carbonic acid, and variations of phosphate concentration were determined time dependantly. The results showed that the concentration was remarkably low in the presence of limestone, signifying that the coexistence of limestone suppresses the dissolution of phosphate by organic acid and/or carbonic acid. Separate experiments conducted by developing an anaerobic condition, after mixing lake sediments with dried leaves and limestone, showed that the existence of limestone suppressed the dissolution of phosphate. These results show that the application of limestone might be a useful measure to prevent deterioration of water quality originated from eutrophication by inhibiting the internal loading of P in eutrophic water-bodies.

• Resources Recycling
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• v.3 no.3
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• pp.27-31
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• 1994

We tested the limestone sludge produced in Pohang Iron & Steel Co., Ltd. as a filler powder for the effective use of portland cement. Hydration process was investigated by measuring the hydration rate, the amounts of non-evaporable water and compressive strength of cement-limestone sludge paste prepared by mixing limes-tone sludge with cement. The results obtained in this study can be summarized as follows: 1. There is no significant difference between the cases of adding up to 10% limestone sludge and those of unmixed cement system. However the reaction rate increases in the 5% limestone sludge system(due to the effects of fine). 2. The compressive strength increases proportionally with increasing the measured amount of non-evaporable water, Adding 5% limestone sludge also increases the strength a little higher, and the compressive strength and calcium silicate hydrates. In the case of the mixed limestone sludge, $2\theta$=$11.7^{\circ}$ peak appears in the samples of 28 days hydration. This peak indicted the presence of calcium carboaluminate hydrate. Although limestone sludge is generally regarded as a inert materials, some kinds of cement can produce a calcium carboaluminate by reacting with aluminate in cement pastes.

• Proceedings of the Korea Concrete Institute Conference
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• 2010.05a
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• pp.385-386
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• 2010

This paper was examined the autogenous shrinkage properties through the fludity properties and autogenous shrinkage volume of high fluidity concrete using limestone powder.

• Advances in concrete construction
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• v.14 no.2
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• pp.93-102
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• 2022

In this study, limestone powder (LS) and fly ash (FA) were used as powder materials in self-compacting concrete (SCC) in increasing quantities in addition to cement, so that the two powders commonly used in the production of SCC could be compared in the same study. Considering the reduction of the maximum aggregate size in SCC, 10 mm or 16 mm was selected as the coarse aggregate size. The properties of fresh concrete were determined by slump flow (including T₅₀₀ time), V-funnel and J-ring experiments. The experimental results showed that as the amount of both LS and FA increased, the slump flow also increased. The increase in powder material had a negative effect on V-funnel flow times, causing it to increase; however, the increase in FA concretes was smaller compared to LS ones. The increase in the powder content reduced the amount of blockage in the J-ring test for both aggregate sizes. As the hardened concrete properties, the compressive and splitting strengths as well as the modulus of elasticity were determined. Longitudinal and transverse deformations were measured by attaching a special frame to the cylindrical specimens and the values of Poisson's ratio, initiation and critical stresses were obtained. Despite having a similar W/C ratio, all SCC exhibited higher compressive strength than NVC. Compressive strength increased with increasing powder content for both LS and FA; however, the increase of the FA was higher than the LS due to the pozzolanic effect. SCC with a coarse aggregate size of 16 mm showed higher strength than 10 mm for both powders. Similarly, the modulus of elasticity increased with the amount of powder material. Inelastic properties, which are rarely found in the literature for SCC, were determined by measuring the initial and critical stresses. Crack formation in SCC begins under lower stresses (corresponding to lower initial stresses) than in normal concretes, while critical stresses indicate a more brittle behavior by taking higher values.

• Journal of the Mineralogical Society of Korea
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• v.20 no.4
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• pp.339-349
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• 2007

For various types of the Pungchon limestone, diverse mineral characters of the limestone including their size and morphology are investigated by using of ELS and SEM to examine the possibility of application as fillers to paper industry. Also, the measurement of zeta potential and the evaluation of coagulation properties in calcite suspension was made for fine powders of the limestone to examine the applicability and efficiency in wet-papermaking process. Fine powder of the Pungchon lime-stone, largely controlled by original mineral characters of ore in mineralogical aspects, exhibits some-what different trend in particle morphology according to ore types, and thereby, the size distribution, zeta potential and coagulation properties also become different. The examined whiteness, brightness, opacity and sheet strength in hand sheet also show remarkable differences according to ore types. These are seemed to be basically due to the results of combined effects of whiteness, site distribution, refractive index, and morphology of the limestone powder on the properties of hand sheet. Considering the investigated results, all types of the Pungchon limestone appear to be sufficiently applicable to paper industry. Especially, the mega-crystalline calcite type is evaluated to be overall suitable for the purpose of paper industry due to the higher values in whiteness and brightness. In addition the fine powder of micro-crystalline calcite type is assessed particularly to have a good quality in sheet strength by virtue of irregular particle shape.

• Composites Research
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• v.29 no.6
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• pp.328-335
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• 2016

The purpose of this study is to develop fiber reinforced cement matrix composite (ECC) produced with limestone powder in order to achieve high ductility of the composite, and to evaluate flexural performance of structural members made with ECC. Four kinds of mixture proportions were determined on the basis of the micromechanics and a steady state cracking theory considering the matrix fracture toughness and fiber-matrix interfacial characteristics. The mechanical properties of ECC, represented by strain-hardening behavior in uniaxial tension, were investigated. Also, strength property of the composite was experimentally evaluated. Two structural members made with ECC were produced and tested. Test results were compared with those of conventional concrete structural members. Increased limestone powder contents of ECC provides higher ductility of the composites while generally resulting in a lower strength property. ECC structural members exhibited higher flexural ductility, higher flexural load-carrying capacity and tighter crack width compared to conventional structural members.

• Resources Recycling
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• v.22 no.3
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• pp.36-42
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• 2013

According to the recent community-based structures enlargement, specification, and diversification. It needs appropriate construction materials in terms of intensity and environmental aspects. Thus, in manufacturing the cement using micro limestone powder which is main material. It is also expected to save energies and reduces $CO_2$, by using the blast furnace slag and fly ash which are mitigated environmental load construction materials that emerged. In this research, The durability aspect tries to be grasped considering the chemical property according to the coherence of the hydration product. Consequently, The compressive strength was measured over 30 Mpa on 3rd. In addition, according to the content of the limestone powder, the setting time is promoted. It has the feature expanded in the length change. And it is determined because the possibility of replacing the existing for construction material such as it is measured compared with the time to use the portland cement usually that flexural strength is high with the age 7 days ago, so it is sufficient.