• Title/Summary/Keyword: Lead in air

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Morphology of Lead Titanate Prepared by Wet Chemical Methods (습식화학법으로 제조된 티탄산 납의 형상)

  • 최병철;이문호
    • Korean Journal of Crystallography
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    • v.3 no.1
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    • pp.1-8
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    • 1992
  • The morphology of lead titanate powders prepared by sol-gel and coprecipitation techniques was investigated as a function of firing temperature and soaking time. PbTiO3 precursor powders were derived from a mixed solution of lead nitrate and titanium tetrachloride at 40℃ to 43℃ and pH of 9.0 to 9.7, and fired at temperatures 350-1000℃ for 1-10h in air. An increase of particle size and agglomeration with increasing calcination temperature and duration could be observed. By annealing sol-gel derived powder at 700℃, the tially-formed acicular(and/or prismatic) primary particles transformed to polyhedral shape with soaking time, and further soaking caused coarsening the polyhedral particles with rounded edges. However, the morphology of the coprecipitated powders was not varied during crystallization.

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An Experimental Study of Environmental Effects on the Rolling Resistance of Bearing Surfaces Coated by Soft Metallic Films (연금속 박막이 코팅된 베어링 표면의 구름 저항 거동에 미치는 분위기의 영향에 대한 실험적 고찰)

  • 양승호;공호성;윤의성;김대은
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 1998.04a
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    • pp.47-54
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    • 1998
  • An experimental study was performed to discover the effect of environmental conditions on the rolling resistance behavior of pure silver and lead coated 52100 bearing steel. Pure silver and lead coating were produced by a thermal evaporation coating method. Experiments using a thrust ball bearing-typed rolling test-rig were performed under vacuum, dry air and controlled humidity conditions. Results showed that agglomeration of particles were prevented in vacuum environment and as it showed low and stable rolling resistance by shakedown phenomena. Also, humidity relates closely to the agglomeration of particles and increased the rolling resistance after the failure of coated layer.

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Development of wind tunnel test model of mid-rise base-isolated building

  • Ohkuma, Takeshi;Yasui, Hachinori;Marukawa, Hisao
    • Wind and Structures
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    • v.7 no.3
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    • pp.203-214
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    • 2004
  • This paper describes a method for developing a multi-degree-of freedom aero-elasto-plastic model of a base-isolated mid-rise building. The horizontal stiffness of isolators is modeled by several tension springs and the vertical support is performed by air pressure from a compressor. A lead damper and a steel damper are modeled by a U-shaped lead line and an aluminum line. With this model, the frequency ratio of torsional vibration to sway vibration, and plastic displacements of isolation materials can be changed easily when needed. The results of isolation material tests and free vibration tests show that this model provides the object performance. The peak displacement factors are about 4.5 regardless of wind speed in wind tunnel tests, but their gust response factor decreases with increment of wind speed.

Sol-Gel Template Synthesis and Phase Transitions of $PbZrO_3$ Nanotubes ($PbZrO_3$ 나노튜브의 졸-겔 형판 합성과 상전이)

  • Chang, Ki-Seog;Bu, Sang-Don
    • Journal of the Korea Institute of Military Science and Technology
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    • v.8 no.4 s.23
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    • pp.85-90
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    • 2005
  • We report the phase transition temperatures of the $PbZrO_3$ perovskite nanotubes made by sol-gel template synthesis. The lead zirconate($PbZrO{_3}$) nanotubes were prepared with a chelate sol-gel of zirconium tetrabutoxide($Zr(OBu){_4}$) and leadacetate($Pb(OAc){_2}-3H_2O$). $Whatman^(r)$ anodisc membranes, with a 200nm pore size, served as the template. After removing the template in the 6M-NaOH solution, the $PbZrO{_3}$ nanotubes so far have shown an anomalous transition temperature, $123.6^{\circ}C$ as measured by DSC with a small particle size, 15.4nm determined by X-ray analysis with the aid of Scherrer's equation.

Evaluation of Indoor Thermal Environment and Thermal Sensation in Traditional Ondol Room (전통온돌방의 실내온열환경 및 온열감에 관한 연구)

  • 김난행;손장열
    • Journal of the Korean housing association
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    • v.15 no.2
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    • pp.19-25
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    • 2004
  • The aim of the research was to evaluate the characteristics of indoor thermal environment and thermal sensation in the traditional Ondol room. Indoor thermal factors including air temperature, operative temperature, floor surface temperature, relative humidity, PMV, OT were measured, and survey was carried out to understand subjective responses of resident's related to indoor thermal environment in Ondol room. The analysed houses are: the Chung hyo dang(the head house of Ryu family in Andong) and the Pyeung won jung(the traditional house in Yesan). The purpose of the survey was to know the relationship between resident's sensation and thermal environmental indicators such as air temperature, relative humidity, floor surface temperature, OT. The experimental results have pointed out how Ondol room may lead to comfortable and uniform indoor thermal environments.

Method development for detecting superoxide/hydroperoxyl radical

  • Kwon, Bum-Gun;Lee, Jai H.
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2001.11a
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    • pp.165-166
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    • 2001
  • HO$_2$ radical plays pivotal roles in the tropospheric $O_3$ formation chemistry. This radical oxidizes NO to NO$_2$ and thus HO$_2$ radical can lead to in-situ ozone formation. Numerous methods have been tried to measure concentrations of atmospheric HO$_2$ in gas phase. Detecting methods applied in the air are a chemical amplifier (Cantrell et al., 1996), FAGE (Fluorescence Assay with Gas Expansion) (Hard et al., 1984), and LIF (Laser-induced Fluorescence) (Stevens et al., 1994). These methods have been limited because of low sensitivity and interferences such as $O_3$, NO, and itself (Stevens et al.,1994). (omitted)

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NOx Formation Characteristics on Heat Loss Rate for CH4/Air Premixed Flames in a Perfectly Stirred Reactor (완전혼합 반응기에서 CH4/Air 예혼합화염의 열손실율에 따른 Nox 생성특성)

  • Hwang, Cheol-Hong;Lee, Kee-Man;Kum, Sung-Min
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.10 no.7
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    • pp.1465-1472
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    • 2009
  • The effect of heat loss rate on NOx formation of $CH_4/air$premixed flame were examined numerically in a perfectly stirred reactor. The following conclusions were drawn. Under the adiabatic wall condition, an increase in the residence time causes a remarkable increases in NOx emission. Under the heat loss conditions, however, NOx decreases significantly as the heat transfer coefficient and residence time increase. As the heat loss rate increases, Thermal NO mechanism and Re-burning NO mechanism play an important role in the NOx reduction, but Prompt NO mechanism and $N_2O$-intermediate NO mechanism lead to the increase in NOx production. Although the NOx formation is actually related to complex NOx mechanism with the changes in the heat transfer coefficient and residence time, it was found that NOx concentration can be represented by independent Thermal NO mechanism. From these results, new NOx correlation combined with the heat loss rate and residence time was suggested for predicting the NOx concentration in a practical $CH_4/air$premixed combustor.

The Influence of Long-range Transport on Springtime Nocturnal Ozone Enhancement in Seoul (봄철 서울지역 야간 오존농도 상승에 미치는 장거리 수송의 영향)

  • 오인보;김유근
    • Journal of Korean Society for Atmospheric Environment
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    • v.20 no.4
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    • pp.503-514
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    • 2004
  • In Seoul metropolitan area, nocturnal variation of surface ozone concentrations observed at 27 monitoring sites from 1998 to 2002 showed that high ozone levels occurred frequently during the spring. Frequency distributions for nighttime ozone indicated that elevated concentrations in spring were influenced by advection of different air mass compared to other seasons. Surface wind analysis during the spring revealed that relatively strong southwesterly winds were associated with nocturnal ozone enhancement, which can be attributed to the regional transport of ozone. In order to identify the origin of nocturnal ozone enhancement in spring, 3-day backward trajectories were calculated by HYSPLIT 4 for the episode days and then classified. The results showed that NW, W, and SW flows, indicating influence of polluted air masses from the China continent, have 51% in a]1 the episode days, which suggest that the nocturnal ozone enhancement can occur under the effect of long-range transport of ozone-laden air mass on a regional scale. Case study of nocturnal ozone maxima associated with long-range transport was discussed in more detail in the light of meteorological conditions. Southwesterly synoptic flow along the outer edge of moving high-pressure system was found to be the important cause of nocturnal ozone maxima in Seoul. This flow could lead to be long-range transport of ozone that had effectively accumulated in the stagnating portion of the system located eastern coast of China. Low atmosphere soundings, backward trajectories, and elevated ozone and CO levels at the back-ground tiles gave evidence for regional effects on nocturnal ozone enhancement In Seoul.

How about the IAQ in Subway Environment and Its Management?

  • Song, Ji-Han;Lee, Hee-Kwan;Kim, Shin-Do;Kim, Dong-Sool
    • Asian Journal of Atmospheric Environment
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    • v.2 no.1
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    • pp.60-67
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    • 2008
  • The spatial limitations of urban environments in general lead to invention and design of a wide range of underground transportation systems such as subways, underground roads and paths, etc. Among them, the application of subway systems in metropolitan cities is most commonly observed to ease those confronted difficulties on this purpose. It in turn leaves passengers and workers to be exposed to indoor air potentially polluted by various sources existing in this underground environment. Specifically when considering the IAQ in a subway station, there exist many IAQ-related parameters to be counted either as individual or as integrated exposures. In this study, a model system has been developed to manage the general IAQ in a subway station. Field survey and $CO_2$ measurements were initially conducted to analyze and understand the relationship between the indoor and outdoor air quality while considering the internal pollution sources such as passengers, subway trains, etc. The measurement data were then employed for the model development with other static information. For the model development, the algorithm of simple continuity was built and applied to model the subway IAQ concerned. In this paper, the recent updated draft version of model developed will be reported and demonstrated.

A Study for Efficiency of Storing Method and Vehicle Operation in Bonded Warehous at Airport (항공화물 보세창고의 화물 저장법과 이송 장비 운영의 효율성 개선)

  • Song, Kwon-Seop;Lee, Hu-Un;Chae, Jun-Jae
    • Journal of Korean Society of Industrial and Systems Engineering
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    • v.32 no.1
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    • pp.44-51
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    • 2009
  • A bonded warehouse is the warehouse located in bonded area. It functions not only as a general warehouse but also as a place for managing the work related to import and export bonded goods. As a general warehouse, it uses the rack system to store the goods and the folk lift truck to move the unitized goods. The operation of the storing system closely related to the efficiency of space uses in a warehouse and vehicle working. Thus, vehicle performance measured in distance units in the ware-house could be used as one of the key performance measure in warehouse system. This paper focuses on the operation efficiency of the bonded warehouse which uses rack system for the storing and the folk lift truck for moving goods. The method of load allocation for balancing the rack uses and vehicle operation for maximizing efficiency are the specific concerns in this paper. The simulation study is conducted to find a policy for efficient vehicle operation based on balanced rack utilization, and the favorable result for the system operation would lead the usable proposal in vehicle operation.