• Journal of the Korean Chemical Society
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• v.55 no.4
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• pp.697-702
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• 2011

The new layered perovskite manganites $La_{0.5}Sr_{1.5}Mn_{0.5}Cr_{0.5-x}Fe_xO_4$ (x=0.15, 0.3) have been prepared by standard ceramic method. The powder X-ray diffraction studies show that the phases crystallize with tetragonal unit cell in the space group I4/mmm. The electrical transport properties suggest that the phases show insulating behaviour and the electrical conduction in the phases occurs by a 3D variable range hopping mechanism. The magnetic properties suggest that both the phases are antiferromagnetic.

• Journal of the Korean Institute of Intelligent Systems
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• v.17 no.5
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• pp.598-603
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• 2007

To solve the rule explosion problem in multi-input fuzzy system, a method of converting a given fuzzy system to 2 layered hierarchical fuzzy system has been reported, where at the 1st layer, linearly independent fuzzy rule vectors generated from the given fuzzy system are used and, at the 2nd layer, linear combinations of these independent fuzzy rule vectors are used. In this paper, the steapest descent algorithm is presented to learn the fuzzy rule vectors and related coefficients for the equivalent 2 layered hierarchical structure. By simulation of learning of ball and beam control system, the feasibility of proposed learning scheme is shown.

• Journal of Powder Materials
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• v.25 no.6
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• pp.514-522
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• 2018

Layered-double hydroxide (LDH)-based nanostructures offer the two-fold advantage of being active catalysts with incredibly large specific surface areas. As such, they have been studied extensively over the last decade and applied in roles as diverse as light source, catalyst, energy storage mechanism, absorber, and anion exchanger. They exhibit a unique lamellar structure consisting of a wide variety of combinations of metal cations and various anions, which determine their physical and chemical performances, and make them a popular research topic. Many reviewed papers deal with these unique properties, synthetic methods, and applications. Most of them, however, are focused on the form-factor of nanopowder, as well as on the control of morphologies via one-step synthetic methods. LDH nanostructures need to be easy to control and fabricate on rigid substrates such as metals, semiconductors, oxides, and insulators, to facilitate more viable applications of these nanostructures to various solid-state devices. In this review, we explore ways to grow and control the various LDH nanostructures on rigid substrates.

• Geomechanics and Engineering
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• v.17 no.1
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• pp.97-107
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• 2019

Based on the results of Han et al. (2016), in the failure zone ahead of the tunnel face it can be obviously identified that a shear failure band occurs in the lower part and a pressure arch happens at the upper part, which was often neglected in analyzing the face stability of shield tunnel. In order to better describe the collapse failure feature of the tunnel face, a new improved failure mechanism is proposed to evaluate the face stability of shield tunnel excavated in layered soils in the framework of limit analysis by using spatial discretization technique and linear interpolation method in this study. The developed failure mechanism is composed of two parts: i) the rotational failure mechanism denoting the shear failure band and ii) a uniformly distributed force denoting the pressure arch effect. Followed by the comparison between the results of critical face pressures provided by the developed model and those by the existing works, which indicates that the new developed failure mechanism provides comparatively reasonable results.

• Advances in nano research
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• v.10 no.4
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• pp.373-383
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• 2021

In this work, silver nitrate complexes of sulfanilamide-5-methyl-2-thiophene carboxaldehyde (SMTCA) ligand intercalated Zn/Al-layered double hydroxide [Ag-SMTCA-LDH] were synthesized for the potential application as an antimicrobial system. The SMTCA ligand was synthesized by reacting sulfanilamide and 5-methyl-2-thiophene carboxaldehyde in methanol and further complexation with silver nitrate metal ions [Ag-SMTCA]. The structural analyses of synthesized compounds confirmed an intercalation of Ag-SMTCA into Zn/Al-NO₃-LDH by flake/restacking method. SMTCA, Ag-SMTCA and Ag-SMTCA-LDH were characterized by ¹H nuclear magnetic resonance (¹H NMR) spectroscopy, Fourier-transform infrared (FTIR), ultraviolet-visible (UV-Vis) spectrophotometer, scanning electron microscopy (SEM) and transmission electron microscopy (TEM), X-ray diffraction (XRD), and thermogravimetric analysis (TGA). It was found that Ag-SMTCA-LDH exhibited good antimicrobial activity against both gram-positive (Bacillus subtilis, [B. subtilis], Staphylococcus aures, [S. aureus]) and gram-negative (Escherichia coli, [E. coli], Pseudomonas aeruginosa [P. aeroginosa]) bacteria as well as excellent antioxidant activity.

• Structural Engineering and Mechanics
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• v.77 no.5
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• pp.571-586
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• 2021

The present paper studies the influence of the inhomogeneous initial stresses in the bi-layered hollow cylinder and it is assumed that these stresses are caused by the hydrostatic pressures acting on the interior and outer free surfaces of the cylinder. The study is made by utilizing the version of the three-dimensional linearized theory of elastic waves in bodies with initial stresses for which the initial stress-strain state in bodies is determined within the scope of the classical linear theory of elasticity. For the solution to the corresponding eigenvalue problem, the discrete-analytical method is employed. Numerical results are presented and analyzed for concrete selected pairs of materials. According to these results and their analyses, it is established that, unlike homogeneous initial stresses, the influence of the inhomogeneous initial stresses on the torsional wave dispersion has not only quantitative but also qualitative character. For instance, in particular, it is established that as a result of the initial stresses caused by the hydrostatic pressure acting in the interior free surface of the cylinder, the cut-off frequency appears for the fundamental dispersive mode and the values of this frequency increase with the intensity of this pressure.

• Journal of Ocean Engineering and Technology
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• v.38 no.1
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• pp.30-42
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• 2024

This study examined the jack-up spudcan penetration for a new type of offshore wind substructure newly proposed using the jack-up concept to reduce construction costs. The jack-up spudcan for offshore wind turbines should be designed to penetrate a stable soil layer capable of supporting operational loads. This study evaluated multi-layered soil conditions using centrifuge tests: loose sand over clay and loose sand-clay-dense sand. The penetration resistance profiles of spudcan recorded at the centrifuge tests were compared with the ISO and InSafeJIP methods. In the tests, a spudcan punch-through effect slightly emerged under the sand-over-clay condition, and a spudcan squeezing effect occurred in the clay-over-sand layer. On the other hand, these two effects were not critically predicted using the ISO method, and the InSafeJIP result predicted only punch-through failure. Nevertheless, ISO and InSafeJIP methods were well-matched under the conditions of the clay layer beneath the sand and the penetration resistance profiles at the clay layer of centrifuge tests. Therefore, the ISO and InSafeJIP methods well predict the punch-through effect at the clay layer but have limitations for penetration resistance predictions at shallow depths and strong stratum soil below a weak layer.

• Proceedings of the Korea Concrete Institute Conference
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• 1996.10a
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• pp.480-485
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• 1996

A numerical method for perdicting the behavior of a reinforced concrete column under biaxial loading is proposed, using the layered finite element method. Concrete is assumed to exhibit strain softening and steel reinforcement is elastic-plastic. The bending theory assumptions are used and bond slip of reinforcement is meglected. To perdict the entire load-deformation characteristics, displacement control method is used. This method consider not only combined effect due to axial load and bending moment but also that due to bending moments. Predicted behaviors of reinforced concrete columns under biaxial loading through the numerical method proposed in this study show good agreements with test results.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.14 no.1
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• pp.39-48
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• 1994

An equivalent homogeneous 3-D linear composite analysis and accomponying finite element program is presented for elastomeric bearings. This study is limited to the 3-D layered system with linear, elastic, isoparametric small deformation. And we used method of multiscale to model the 3-dimensional configurations and overall response of the layered elastomeric bearings with global and local coordinates. The primary dependent variables for the theory have been selected that require only $C_o$ continuity of the finite element analysis. As a result, it is very simple and computationally economical. The presented theory can also be applied easily to the analysis of nonlinear behavior of layered systems. And those of past are not applicable to nonlinear analysis, because it uses superposition theory. Numerical examples are presented to verify the theory and to illustrate potential applications of the analysis.

• Journal of the Korean Ceramic Society
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• v.53 no.4
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• pp.417-428
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• 2016

In this review, an attempt is made to calculate one-dimensional (1-D) electron density profiles from experimentally determined (00l) XRD intensities and possible structural models as well in an effort to understand the collective intracrystalline structures of intercalant molecules of two-dimensional (2-D) nanohybrids with heterostructures. 2-D ceramics, including layered metal oxides and clays, have received much attention due to their potential applicability as catalysts, electrodes, stabilizing agents, and drug delivery systems. 2-D nanohybrids based on such layered ceramics with various heterostructures have been realized through intercalation reactions. In general, the physico-chemical properties of such 2-D nanohybrids are strongly correlated with their heterostructures, but it is not easy to solve the crystal structures due to their low crystallinity and high anisotropic nature. However, the powder X-ray diffraction (XRD) analysis method is thought to be the most powerful means of understanding the interlayer structures of intercalant molecules. If a proper number of well-developed (00l) XRD peaks are available for such 2-D nanohybrids, the 1-D electron density along the crystallographic c-axis can be calculated via a Fourier transform analysis to obtain structural information about the orientations and arrangements of guest species in the interlayer space.