• 제목/요약/키워드: LB films

검색결과 391건 처리시간 0.021초

전자 스핀 공명을 이용한 메로시아닌 색소 LB막의 특성 (Characteristics of Meroeyanine Dye LB Films Using Electron Spin Resonance Spectroscopy)

  • 신훈규;권영수
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1996년도 하계학술대회 논문집 C
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    • pp.1569-1571
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    • 1996
  • The role of ESR spectroscopy in the characterization of functional LB films is discussed. Optical absorption were performed on LB films of binary mixtures of three kinds of merocyanine dyes where DS and 6Me-DS form J-like aggregates but not DO in single component films. The observed optical absorption spectra of mixed films were markedly dependant on the combination of dyes. We found the formation of J-aggregates in a mixed merocyanine dyes containing a non J-aggregate forming dye DO, in a single component case. In structural studios, ESR is of particular important in the analysis of molecular orientation of LB films. Development of new functional LB films may provide more cases where ESR spectroscopy will clarify the nature of such films.

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지방산 LB막의 온도에 대한 전기전도도 특성 (Conductivity Characteristic for Temperature of Stearic acid LB films)

  • 이준호;김경환;권영수
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1998년도 추계학술대회 논문집 학회본부 C
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    • pp.884-885
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    • 1998
  • The electrical characteristics of Stearic acid Langmuir-Blodgett(LB) films were investigated to develop the gas sensor using LB films. The deposition status of LB films were verified I-V characteristic which was increased with an applied voltage for the number of layers and decreased as increasing the distance of electrode. The conductivity of Stearic acid LB films was $10^{-8}[S/cm]$, which is typical of semiconductor. The conductivity of LB films were increased as the temperature was increased. The activation energy was about 1[eV].

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지방산계 LB막의 유전 및 전기적 특성 (Dielectric and Electrical Characteristics of Fatty Acid LB films)

  • 최용성;김도균;장정수;권영수
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1998년도 추계학술대회 논문집 학회본부 C
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    • pp.819-821
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    • 1998
  • Arachidic acid(AA) was used as LB films and its dielectric and conduction characteristics were investigated. The relative dielectric constant(${\varepsilon}_{LB}$) of AA LB films obtained from capacitance-frequency properties was about $3.5{\sim}4.1$. And the conductivity(${\sigma}_{LB}$) of AA LB films obtained from Current-Voltage characteristics was about $2.6{\times}10^{-15}[S/cm]$. Also, the conduction mechanism of current in LB films was dependant on Schottky type and the barrier height obtained from Schottky plot was about 1.4[eV].

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폴리우레탄 LB단분자막의 표면구조 이미지와 전기적 특성 (Surface Structure and Electrical Properties of Polyurethane LB Monolayers)

  • 서정열;김도균;정상범;유승엽;신훈규;박재철;권영수
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 추계학술대회 논문집
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    • pp.320-323
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    • 2000
  • We attempted to fabricate polyurethane derivatives (PU-CN, PU-DCM) LB films by using LB method. Also, we investigated the monolayer behavior at the air-water interface by surface pressure-area ($\pi$-A) isotherms. And, the surface morphologies and the physicochemical properties of LB films were investigated by atomic force microscopy (AFM) and UV-vis spectroscopy, respectively. Also, the electrical properties of polyurethane derivatives LB films were investigated by using the conductivity and the dielectric constant. In the AFM images, we conclude that surface morphology of PU-DCM LB films is smooth and homogeneous and has optimal hydrophobicity and good stability, whereas PU-CN LB films give rougher surfaces with more excess material. In the I-V characteristics, the conductivity is different as to the polyurethane derivatives, it is considered that this phenomena could be described by the difference of lumophore pendant which was adhered at PU main chain.

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Disperse diazo black D(DBD) photopolymer의 박막 제작과 이의 물리적 특성에 관한 연구 (A manufacture of disperse diaso black D(DBD) photopolymer thin films and its Physical Properties)

  • 정용환;이호식;변대현;김태완
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1997년도 하계학술대회 논문집 C
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    • pp.1333-1335
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    • 1997
  • We have made disperse diazo black D(DBD) thin films using Langmuir-Blodgett(LB) and vacuum-evaporation technique. Physical and optical properties of the films were investigated. Solution was made with a concentration of $10^{-3}mol/{\ell}$ using chloroform. Moving wall apparatus, (NL-LB140S-MWC) was employed to make the LB films. X,Y and Z-type LB films were manufactured and studied UV/visible absorbance spectra and morphology of surface using atomic force microscopy(AFM). Vacuum-evaporated DB D thin films were made at a pressure of $10^{-5}$ torr. The absorption peaks were observed at 200 and 400 nm in the LB films and vacuum-deposited films. We have also studied photoluminescence spectrum of the DBD films.

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폴리우레탄 고분자 LB막의 표면구조 관찰 및 전기적 특성 (Observation of Surface Morphology and Electrical Properties of Polyurethane Polymer LB Films)

  • 서정열;신훈규;권영수
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제50권8호
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    • pp.371-375
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    • 2001
  • We attempted to fabricate polyurethane derivatives (PU-CN, PU-DCM) LB films by using LB method. Also, we investigated the monolayer behavior at the air-water interface by surface pressure-area (${\pi}$-A) isotherms. The surface morphologies and the physicochemical properties of LB films were investigated by atomic force microscopy(AFM) and UV-vis spectroscopy, respectively. And, the electrical properties of polyurethane derivatives LB films were investigated by using the conductivity and the dielectric constant. In the surface morphologies, physicochemical and electrical properties of polyurethane derivatives LB films, the properties is different as to the polyurethane derivatives, it is considered that this phenomena could be described by the difference of lumophore pendant which was adhered at PU main chain.

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전극 간격 변화에 대한 Stearic acid LB막의 전기 전도 특성 (Electrical Conduction Characteristics of Stearic Acid LB Films Using Distance of Electrode)

  • 이을식;김도균;최용성;장정수;권영수
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1998년도 하계학술대회 논문집 D
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    • pp.1506-1507
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    • 1998
  • Stearic acid LB films was deposited by LB technique. The deposition status of LB films were verified by UV absorbance which was increased in proportion to the number of layers. And, I-V characteristics were measured to investigate the response properties between LB films and organic gases using the distance of electrodes. The current was increased with the applied voltage but decreased as increasing the distance of electrodes. The conductivity of stearic acid LB films using the distance of electrodes was $10^{-8}$[S/cm], which corresponds to that of the semiconductor.

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Polyimide LB막의 전기적 특성 (The electrical properties of Polyimide Langmuir-Blodgett Film)

  • 박준수;이호식;김태완;손병철;강도열
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1995년도 춘계학술대회 논문집
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    • pp.111-114
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    • 1995
  • This paper describes the imidization of PAAS(polyamic acid alkylamine salts) Langmuir-Blodgett (LB) films and the electrical properties of PAAS and polyimide(PI) LB films, The imidization conditons were investigated by TGA(Thermal Gravi-tational Analysis). FT-IR and UV/ visible absorption spectra. A thermal imidiczation was peformed at 300$^{\circ}C$ for 1 hour. The electrical properties of the PAAS and polymide LB films were measured by current-voltate(L-V) characteristics It shows that the electrical condcutivity of PL LB films is about 10 $\^$-15/S/cm which is two orders of magnetiude lower than that of the PAAS LB films A Schottky effect was also observed in both films.

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LB 초박막 Hetero 구조에서 내장전계의 발생 (Generation of Inner Electrical Field in Hetero Structure of LB Ultra Thin Films)

  • 권영수;강도열
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1987년도 정기총회 및 창립40주년기념 학술대회 학회본부
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    • pp.511-514
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    • 1987
  • Langmuir-Blodgett (LB) films of TCNQ(tetracyanoquinodimethane) with alkyl radical($C_{12}TCNQ$) were prepared on the sample of Al/LB film/Al type where Al are electrode, and polarization in LB film and dipolar moment of molecules in the films were measured by TSC. $Al_2O_3$ layer was yielded on the electrode by natural oxidation in air. According to the cooperation of $Al_2O_3$ dielectric layer and the polarization of $C_{12}TCNQ$-LB film, the macroscopic electrical field was yielded in LB film and $Al_2O_3$ layer. The field strength in $C_{12}TCNQ$-LB films was evaluated at about $1{\times}10^6{\sim}5{\times}10^6\;V/cm$.

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Pyridinealdoxime 기능기 그룹을 가진 덴드리틱 거대분자를 이용한 LB막의 전기적 특성 (Electrical Properties of LB Films Using Dendritic Macromolecules Containing Pyridinealdoxime Functional Group)

  • 정상범;유승엽;박은미;김정균;박재철;권영수
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 하계학술대회 논문집
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    • pp.761-763
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    • 2001
  • Dendrimers represent a new class of synthetic macromolecules characterized by a regularly branched treelike structure. Dendrimer can be made with high regularity and controlled molecular weight. Peculiar features of the dendritic geometry are the large number of end groups as well as the shape persistence in higher generations, approaching spherical geometry. One of the most peculiar characteristics of dendritic macromolecules is their controlled molecular structure and orientation, which means that they have a practical application in achieving a highly organized molecular arrangement. We attempted to fabricate a G4-48PyA dendrimer LB films containing 48 pyridinealdoxime functional end group that could form a complex structure with metal ions. Also, we investigated the surface activity of dendrimer films at air-water interface. And we have studied the electrical properties of the ultra-thin dendrimer LB films. The electrical properties of the ultra-thin dendrimer LB films were investigated by studying the current-voltage(I-V) characteristics of metal/dendrimer LB films/metal (MIM) structure. And rectifying behavior of the devices was occurred in applied field.

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