• Journal of Power System Engineering
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• v.20 no.4
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• pp.52-62
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• 2016

Nowadays, emissions of a vehicle are been getting by testing on a chassis dynamometer and a test modes. Also, fuel efficiency is calculated by carbon-balance method that is applying the emissions(CO, THC and $CO_2$) to the fuel calculation formular. In Korea, before 2014, the formular did not include the fuel factors (density, net heat value and carbon weight fraction), but the constants were based on the fuel properties of 2000s. So, this formular did not consider a characteristic of test fuel property that was changed when progressing fuel efficiency test. The characteristics of test fuel property which was distributed in domestic have a difference of quality depending on production regions and oil-refining facilities. Because the fuel properties are variable value during refineries, crude oils and blending contents of a bio-fuel, vehicle fuel is changed for each test. Therefore, the fuel qualities need to apply for a fuel economy test. In this paper, changing patterns of a fuel properties were reviewed during history of fuel standards. Also, the appropriateness of the methods was discussed by calculating and comparing fuel economies with the fuel factors and the constants.

• 한국신재생에너지학회:학술대회논문집
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• 2008.10a
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• pp.188-191
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• 2008

There have been many methods for producing natural gas from gas hydrate reservoirs in permafrost and sea floor sediments. It is well knownthat the depressurization should be a best option for Class 1 gas hydrate deposit, which is composed of tow layers: hydrate bearing layer and an underlying free gas. However many of gas hydrate reservoirs in sea floor sediments are classified as Class 2 that is composed of gas hydrate layer and mobile water, and Class 3 that is a single gas hydrate layer. The most appropriate production methods among the present methods such as thermal stimulation, inhibitor injection, and controlled oxidation are still under development with considering the gas hydrate reservoir characteristics. In East Sea of Korea, it is presumed that the thick fractured shale deposits could be Class 2 or 3, which is similar to the gas hydrate discovered offshore India. Therefore it is needed to evaluate the possible production methods for economic production of natural gas from gas hydrate reservoir. Here we would like to present the production of natural gas from gas hydrate deposit in East Sea with industrial flue gases from steel company, refineries, and other sources. The existing industrial complex in Gyeongbuk province is not far from gas hydrate reservoir of East Sea, thus the carbon dioxide in flue gas could be used to replace methane in gas hydrate. This approach is attractive due to the suggestion of natural gas productionby use of industrial flue gas, which contribute to the reduction of carbon dioxide emission in industrial complex. As a feasibility study, we did the NMR experiments to study the replacement reaction of carbon dioxide with methane in gas hydrate cages. The in-situ NMR measurement suggeststhat 42% of methane in hydrate cages have been replaced by carbon dioxide and nitrogen in preliminary test. Further studies are presented to evaluate the replacement ratio of methane hydrate at corresponding flue gas concentration.

• Clean Technology
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• v.21 no.4
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• pp.229-234
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• 2015

Recently, there are increasing numbers of study regarding hydrogen fuels but researches on desulfurization of diesel are rare. In this study, we performed diesel desulfurization reactor design by computation fluid dynamics simulation. By analyzing the change in flow and sulfur concentration at the outlet according to the changes in flow rate, reactor length, and reactor diameter, we have found the minimum catalyst performance for the given flow rate condition and the relation between the reactor performance and the reactor size and shape. We also studied the effects of permeability of the packed bed on the flow and sulfur concentration distribution. The present work can be utilized to design a diesel desulfurization reactor for a fuel cell used in ships. Furthermore, the present work also can be used to design low sulfur diesel supply in oil refineries and therefore contribute to the development of clean petrochemical technology.

• Clean Technology
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• v.23 no.2
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• pp.140-147
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• 2017

In this study, we performed numerical simulation for the catalyst regeneration process of diesel desulfurization reactor. We analyzed the changes in regeneration process according to purge gas flow rate, catalyst permeability, reactor size, and heat loss of reactor. We have found that the regeneration process is very much affected by temperature changes whereas it is hardly affected by catalyst permeability and porosity. We also estimated the regeneration time according to purge gas flow rate and initial temperatures and have found that increasing purge gas temperature is more effect for fast regeneration. The present results can be utilized to design a regeneration process of diesel desulfurization reactor for a fuel cell used in ships. Furthermore, the present work also can be used to design low sulfur diesel supply in oil refineries and therefore contribute to the development of clean petrochemical technology.

• Fire Science and Engineering
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• v.33 no.2
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• pp.107-113
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• 2019

Recently, due to global warming, the trend shows an increase in number of lightning strikes which increase risk regarding industry infrastructures. Especially in case where the lightning strikes infrastructures including refinery, petorchemical plant facilities or storage tanks, it can cause power failures, electrical machine malfunction and damage which can lead to fire explosion and multiple calamities. Therefore, detailed case studies must be conducted through a systematic research regarding lightning strike accidents in order to understand its mechanism and devise preventive measures. This paper aims to study cases of explosion regarding waste water storage tanks in refineries and petrochemical plants in order to analyze its root cause and provide preventive measures for avoiding lightning related incidents.

• International Journal of Highway Engineering
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• v.3 no.2 s.8
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• pp.113-121
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• 2001

Among the currently available binder specifications, Superpave Performance Grade asphalt specification is regarded as a superior specification on its theoretical background as well as pavement performance relationship. Many difficulties are expected; however, for Superpave implementation in Korea because of heavy burden of equipment cost as well as lack of trained personnel in asphalt industry, which may too much barrier to overcome in Korean situation. As an effort to improve qualify of asphalt binder, recently, people discuss about a possibility of constituting a performance-based asphalt specification using rather easy-to-measure asphalt properties. The objective of this paper is to determine the possibility of constituting a performance-based asphalt specification using an empirical asphalt properties, such as penetration ring and ball softening point rather than using fundamental properties of asphalt. Nine straight asphalts, that covers entire straight asphalt from all Korean refineries, and eighteen modified asphalts that were modified from two modifiers were included in the study. An analysis was made through a comparison between empirical properties and Superpave PG criteria. This study concluded that it may possible to constitute a pseudo-Superpave-like specification using an empirical asphalt properties as a specification criteria. Therefore, more systematic research is needed to constitute the asphalt specification.

• Journal of the Korean Applied Science and Technology
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• v.35 no.4
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• pp.1327-1337
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• 2018

Aviation fuel oil is more strictly controlled than other transport fuels because it can lead to major accidents in the event of a problem. The quality standards of the aircraft are specified by the domestic Korean Standard, the American Society for Testing and Materials and the International Air Transport Association, respectively. From 2016 to 2017, the quality analysis of 6 items such as aromatic content, sulfur content and distillation characteristics was carried out on the jet fuel produced at five domestic refineries. Domestic production of jet fuel has been shown to be in conformity with the quality standards and has been maintained at a constant level throughout the year. Compared with the specification of ASTM and IATA the aromatic content of domestic KS specification is set to be strictly 1.5 wt% higher than the ASTM and IATA setting specification, but it satisfies this specification sufficiently. In addition, other items such as sulfur content, distillation property and flash point satisfied both domestic and international specification.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.20 no.3
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• pp.147-155
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• 2010

This study was conducted to investigate the benzene exposure levels in coal chemical and petrochemical refining industries during BTX turnaround (TA) processes where benzene was being produced. Three companies producing benzene were selected, one coal chemical and two petrochemical industries. TA processes were classified into three stages: shut down, maintenance, and start up. Data was analyzed by classifying the refining method into 2 groups (Petrochemistry, Coal chemistry) for 823 workers. Comparing the data from petrochemical industries with data from a coal chemical refining industry, while benzene concentration levels of long-term samples during TA were not statistically different (p> 0.05), those levels of short-term samples were significantly different (p< 0.001). About 4.79 % of data in petrochemical industries exceed the occupational exposure limits (OELs) of benzene, 1 ppm. In a coal refining methods, about 15.7% exceeded the benzene OELs. The benzene concentrations in maintenance and start up stage of TA for petrochemical refineries were higher than those in a coal chemical refinery (p <0.01). These findings suggest that the coal chemical refining site requires more stringent work practice controls compare to petrochemical refining sites during TA processes. Personal protective equipments including organic respirators should be used by TA workers to protect them from benzene overexposure.

• Korean Journal of Environmental Agriculture
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• v.4 no.2
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• pp.88-94
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• 1985

In order to investigate the pollution potential of soils after the construction of Onsan Industrial Complex(non-ferrous metal refineries), concentrations of hazardous heavy metals were analyzed for soil samples collected from paddy, upland, orchard and forest soils around the Complex during the period of March 1978 to May 1979. The results are summarized as follows. 1) The concentrations of heavy metals (air-dry basis) for cultivated soil samples from 46 sites were obtained in the range of trace-9.3 ppm As, trace-0.6 ppm Cd, 4${\sim}$22 ppm Cu, trace-0.37 ppm Hg, 6${\sim}$43 ppm Pb and 27${\sim}$93 ppm Zn, which were regarded as non-polluted when compared with the whole Korea data for non-polluted paddy soils. 2) When the heavy metal concentrations were compared with respect to paddy, upland and orchard soils, no significant difference was observed in As, Cd, Cu and Zn whereas significant difference was observed in Hg and Pb. When they were compared with respect to region surrounding the Complex, no significant difference was observed in As, Cd, Hg whereas significant difference was observed in Cu and Pb. 3) Soil samples from several sites near Korea Zinc Refinery were contaminated with Cd, Pb and Zn, due to the accidental emission during its testing operation. Any further contamination was not observed after regular operation of the Refinery.

• Journal of the Korean Institute of Gas
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• v.23 no.6
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• pp.1-7
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• 2019

Most oil refineries and chemical plants have flare systems designed to mitigate pressure rises in process facilities in case of emergencies that require the release of large amounts of gas due to sudden process shutdowns such as power outages. However, the rise of the flame of the flare system causes civil complaints from residents around the factory due to visible pollution, and economic loss occurs in the company, which requires constant management. In this study, two items were diagnosed and analyzed in order to derive the optimal operation method of flare system. First, to detect the cause of the rise in flame height, the acoustic leak detector was used to check gas leaks in safety valves and pressure control valves. Second, to identify the cause of flame instability, the pulsation phenomenon was diagnosed through the CFD simulation and modeling experiments of the sealing drum. By confirming the leak at 4.3% of the safety valve and 10% of the pressure control valve, the cause of abnormal sparking was derived. The information presented in this study can be easily applied to any company that has a flare system, and is expected to prevent complaints and product loss.