• 한국수소및신에너지학회논문집
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• 제24권2호
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• pp.142-149
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• 2013

Carbon materials are mainly used as catalyst supports for polymer exchange membrane fuel cell (PEMFC). Catalyst supports are required specific characteristics of the carbon materials, such as large surface area and high electrical conductivity. Attempted were to improve electrical conductivity and to maintain high surface area of carbon materials using a microwave treatment. Microwave treatment, as a relatively new technique, takes short reaction time and reduce the consumption of the gases used for carbon treatment compared to a traditional heat treatment. Hybrid carbon (ACF/Graphene) as catalyst supports by microwave-irradiation method for PEMFC increase the cell performance because of increased electrical conductivity resulting in triple-phase contact and reduced the interfacial resistance. Scanning electron microscopy (SEM), transmission electron microscopy (TEM) and X-Ray Diffraction (XRD) were employed to analyze carbon materials. The performance of microwave-treated carbon materials was evaluated by measuring current-voltage (I-V) characteristics and electrode impedance.

• 한국수소및신에너지학회논문집
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• 제24권6호
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• pp.524-534
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• 2013

Gasoline direct injection(GDI) engine has a high thermal efficiency, but it has a problem to increase carbon emissions such as soot and $CO_x$. In this study, the objective is to analyze numerically a problem for adding the hydrogen during the intake stroke so as to reduce the injected amount of gasoline in GDI engines. For selection of the base model, the cylinder pressure of simulation is matched to experimental data. The numerical analysis are carried out by a CFD model with the hydrogen addition of 2%, 3% and 4% on the volume basis. In the case of 3% hydrogen addition, the injected gasoline amount is only changed to match the maximum pressure of simulation to that of the base model for additional study. It is found that the combustion temperature and pressure increase with the hydrogen addition. And NO emission also increases because of the higher combustion temperature. $CO_x$ emissions, however, are reduced due to the decrease of injected gasoline amount. Also, as the injected gasoline amount is reduced for the same hydrogen addition ratio, the gross indicated work is no significant, But NO and $CO_x$ emissions are considerably decreased. On the order hand, $CO_x$ emissions of two cases are more decreased and their gross indicated works are higher obtained than those of the base model.

• 한국수소및신에너지학회논문집
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• 제24권6호
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• pp.518-523
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• 2013

This paper describes the reduction of a hydrogen sulfide ($H_2S$) generated from a biogas plant. Micro bubble system is adopted to supply air into the water in the reaction chamber, which can increase the contact area of the supplied air to the reserving water. Two stage reaction chambers having two reaction rooms are designed and manufactured to enhance the reduction rate of a hydrogen sulfide. Sodium hydroxide (NaOH) is also considered to get rid of a hydrogen sulfide. Air volume rate to the water in a reaction chamber is maintained between 0.5 and $1.0m^3/min$. Throughout experimental measurement of the concentration of a hydrogen sulfide by changing the volume of supplied air into the water, reduction rate of a hydrogen sulfide increases as air volume increases. Adding sodium hydroxide to the water with the air supply can reduce effectively a hydrogen sulfide up to 99.5% from biogas. It is noted that a hydrogen sulfide generated by a biogas plant can reduce by supplying micro bubble air and sodium hydroxide effectively.

• 한국수소및신에너지학회논문집
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• 제24권2호
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• pp.128-135
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• 2013

The nuclear fuel cycle plant is composed of various subsystems such as a fuel storage and delivery system (SDS), a tokamak exhaust processing system, a hydrogen isotope separation system, and a tritium plant analytical system. Korea is sharing in the construction of the International Thermonuclear Experimental Reactor (ITER) fuel cycle plant with the EU, Japan, and the US, and is responsible for the development and supply of the SDS. Hydrogen isotopes are the main fuel for nuclear fusion reactors. Metal hydrides offer a safe and convenient method for hydrogen isotope storage. The storage of hydrogen isotopes is carried out by absorption and desorption in a metal hydride bed. These reactions require heat removal and supply respectively. Accordingly, the rapid storage and delivery of hydrogen isotopes are enabled by a rapid cooling and heating of the metal hydride bed. In this study, we designed and manufactured a vertical-type hydrogen isotope storage bed, which is used to enhance the cooling performance. We present the experimental details of the cooling performances of the bed using various cooling parameters. We also present the modeling results to estimate the heat transport phenomena. We compared the cooling performance of the bed by testing different cooling modes, such as an isolation mode, a natural convection mode, and an outer jacket helium circulation mode. We found that helium circulation mode is the most effective which was confirmed in our model calculations. Thus we can expect a more efficient bed design by employing a forced helium circulation method for new beds.

• 한국수소및신에너지학회논문집
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• 제24권5호
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• pp.413-420
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• 2013

Effect of inherent volatile matters in fuels on electrochemical reactions of anode was investigated for a single direct carbon fuel cell (DCFC). Raw coals used as power source in the DCFC release light gases into the atmosphere under the operating temperature of DCFC ($700^{\circ}C$) by thermal decomposition and only char remained. These exhausted gases change the gas composition around anode and affect the electrochemical oxidation reaction of system. To investigate the effect of produced gases, comparative study was conducted between Indonesian sub-bituminous coal and its char obtained through thermal treatment, carbonizing. Maximum power density of raw coal ($52mW/cm^2$) was appeared higher than that of char ($37mW/cm^2$) because the gases produced from the raw coal during thermal decomposition gave additional positive results to electrochemical reaction of the system. The produced gases from coals were analyzed using TGA and FT-IR. The influence of volatile matters on anodic electrolyteelectrode interface was observed by the equivalent circuit induced from fitting of impedance spectroscopy data.

• 한국수소및신에너지학회논문집
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• 제24권2호
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• pp.121-127
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• 2013

Tritium was attracted with high energy source in neutron fusion energy systems. A number of research was performed in tritium storage materials. The Korea was raised storage and delivery systems (SDS) of international thermonuclear experimental reactor (ITER) research. However, bottles of SDS would be important because of stability. The bottles have a welding zone, this zone will be vulnerable to hydrogen embrittlement. This zone have a high thermodynamic energy and heat deterioration. Therefore bottles were studied about hydrogen embrittlement to retain stability. The heat treatment of hydrogen was carried under pressure-composition-temperature (PCT) apparatus because of checking at real time. And then, mechanical properties were evaluated by tensile test and hardness test. In results of this study, hydrogen atmosphere condition is very important by tensile test and kinetics test. The samples were evaluated, that is more weak hydrogen pressure, increasing temperature and time. This results could be useful in SDS bottle designs.

• 한국수소및신에너지학회논문집
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• 제24권6호
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• pp.573-579
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• 2013

Hydrogen engine with homogeneous charged compression ignition can achieve high efficiency by high compression ratio and rapid chemical reaction rates spatially. However, it needs to expansion of the operation range with over-all load conditions which is very narrow due to extremely high pressure rise rate. The adoption of the lean boosting in a HCCI $H_2$ engine is expected to be effective in expansion of operation range since minimum compression ratio for spontaneous ignition is decreased by low temperature combustion and increased surround in-cylinder pressure. In order to grasp its possibility by using lean boosting in the HCCI $H_2$ engine, compression ratio required for spontaneous ignition, expansion degree of the operation range and over-all engine performance are experimentally analyzed with the boosting pressure and supply energy. As the results, it is found that minimum compression ratio for spontaneous ignition is down to the compression ratio(${\varepsilon}$=19) of conventional diesel engine due to decreased self-ignition temperature, and operation range is extended to 170% in term of the equivalence ratio and 12 times in term of the supply energy than that of naturally aspirated type. Though indicated thermal efficiency is decreased by reduced compression ratio, it is over at least 46%.

• 한국수소및신에너지학회논문집
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• 제28권3호
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• pp.287-294
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• 2017

EVs manufacturers typically target a range of 300 km on a fully charged battery. Many studies have been conducted to improve these disadvantages. As a results, the mileage of EVs is expected to increase significantly. However, as the distance traveled by EVs increases, current test method (SCT) have many difficulties. The biggest problem is that it takes a lot of time to test an EVs and greatly increases the error rate during the test period. In order to solve these problems, this paper discusses the fuel economy test method of EVs for energy efficiency and mileage. The comparison of test methods was achieved by chassis dynamometer test about EVs. These review of test methods are intended to both improve testing efficiency and provide a practical testing methodology that can be easily adapted to accommodate future testing enhancements. In conclusion, the results of MCT mode and SCT mode comparison show similar results within 3 %, confirming that the test method is appropriate. Also, as the CSCM distance becomes shorter in the MCT mode, the mileage becomes longer and the fuel economy becomes lower. As a result, the error from the SCT test results is expected to increase. In order to minimize the error of SCT measurement fuel economy, it is recommended to maximize the CSCM driving distance. However, since the timing of the EOT is not clearly known, it is reasonable to define the allowable range of the CSCE to be within 20 % of the MCT total mileage.

• 한국수소및신에너지학회논문집
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• 제28권3호
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• pp.238-245
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• 2017

Mg-Ni nanoparticles were synthesized by a physical vapor condensation method (DC arc-discharge) in a mixture of argon and hydrogen atmosphere, using compressed mixture of micro powders as the raw materials. The crystal phases, morphology, and microstructures of nanoparticles were analyzed by means of X-ray diffraction (XRD) and high-resolution transmission electron microscopy (HRTEM). It was found that the intermetallic compounds of $Mg_2Ni$ and $Mg_2Ni$ formed with existence of phases of Mg, Ni, and MgO in Mg-Ni nanoparticles. After one cycle of hydrogen absorption/desorption process (activation treatment), Mg-Ni nanoparticles exhibited excellent hydrogen absorption properties. $Mg_2Ni$ phase became the main phase by aphase transformation during the hydrogen treatments. The phenomenon of refinement of grain size in the nanoparticle was also observed after the hydrogen absorption/desorption processes, which was attributed to the effect of volume expansion/shrinkage and subsequent break of nanoparticles. Maximum hydrogen absorption contents are 1.75, 2.21 and 2.77 wt.% at 523, 573 and 623 K, respectively.

• 한국수소및신에너지학회논문집
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• 제28권3호
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• pp.300-307
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• 2017

This study is to investigate particle size and velocity profile of gasoline port injector using Phase Doppler Particle Analyzer (PDPA). In this experiment, a GV 250 Delphi port injector used for motorcycles was used for liquid injection. The injector consists of four holes and has a static flow rate of 2.13 g/s. The fuel used in the injection was N-heptane, which is similar to gasoline, as an alternative fuel. The test fuel was injected at an atmospheric temperature of $20^{\circ}C$ and an open atmosphere of 1 atm. The injection time was 10 ms and the injection pressure was 3.5 bar in PDPA experiment. The experimental target position was fiexd at 30, 50 and 75 mm from the nozzle tip and data were collected for a total of 10,000 samples. The experimental results show that the length diameter (D10), the Sauter mean diameter ($D_{32}$), and the mean droplet velocity (MDV) are $45-54{\mu}m$, $99-115{\mu}m$ and 15-21 m/s, respectively.