• Journal of Hydrogen and New Energy
• /
• v.30 no.3
• /
• pp.243-250
• /
• 2019

In this study, to ensure the safety of the packaged hydrogen refueling system, the improvement plan was derived by using 3-dimensional CFD program (FLACS). We also confirmed the effectiveness of risk reduction and the suitability of safety standard. By ventilation performance evaluation according to the position of the vent, it demonstrated that the vent should be installed at the ceiling to safely ventilate without stagnation of the leaked gas. In case of ventilation system according to KGS standard, risk situation could be resolved after about 5 minutes in the worst leaked condition. The result showed that jet fire and explosion inside the packaged system could affect the surrounding facilities. This proves that the standard for installing flame detectors, emergency shut down system and protection wall is appropriate.

• Journal of Hydrogen and New Energy
• /
• v.30 no.3
• /
• pp.251-259
• /
• 2019

The aim of this study is to evaluate the economic feasibility of domestic on-site steam methane reforming (SMR) hydrogen refueling stations. We evaluated the levelized cost of hydrogen (LCOH) for the SMR hydrogen refueling stations, which have production capacities of 100 kg/day (SMR 100), 200 kg/day (SMR 200), and 500 kg/day (SMR 500) utilizing the scale factor. The main results indicated that the LCOH of SMR 100, SMR 200, and SMR 500 were 14,367 won/kg, 11,122 won/kg, and 8,157 won/kg, if the utilizations of hydrogen stations were 70%. These results imply that the production capacity of the domestic SMR hydrogen station should be greater than 500 kg/day to compete with other hydrogen stations when we consider the current sale price of hydrogen at the hydrogen stations.

• Journal of Hydrogen and New Energy
• /
• v.30 no.2
• /
• pp.111-118
• /
• 2019

Greenhouse gas emissions have a profound effect on global warming. Various environmental regulations have been introduced to reduce the emissions. The largest amount of greenhouse gases, including carbon dioxide, is produced in the steel industry. To decrease carbon dioxide emission, hydrogen-based iron oxide reduction, which can replace carbon-based reduction has received a great attention. Iron production generates various by-product gases, such as cokes oven gas (COG), blast furnace gas (BFG), and Linz-Donawitz gas (LDG). In particular, COG, due to its high concentrations of hydrogen and methane, can be reformed to become a major source of hydrogen for reducing iron oxide. Nevertheless, continuous COG cannot be supplied under actual operation condition of steel industry. To solve this problem, this study proposed to use two alternative COG-based fuel mixtures; one with natural gas and the other with biogas. Reforming study on two types of mixed gas were carried out to evaluate catalyst performance under a variety of operating conditions. In addition, methane conversion and product composition were investigated both theoretically and experimentally.

• Journal of Hydrogen and New Energy
• /
• v.30 no.2
• /
• pp.119-127
• /
• 2019

Reliable $H_2$ supply is necessary for entering a $H_2$ society. Among the various $H_2$ storage and transportation methods, liquid organic $H_2$ carrier (LOHC) is in the spotlight because of a lot of advantages compared to conventional one such as compressed $H_2$ and liquefied $H_2$. Therefore, we performed preliminary economic analysis of $H_2$ supply cost using LOHC for a $H_2$ production capacity of $300Nm^3\;h^{-1}$ employing itemized cost estimation and sensitivity analysis to evaluate economic viability of this technology in Korea.

• Journal of Hydrogen and New Energy
• /
• v.30 no.2
• /
• pp.147-154
• /
• 2019

In this study, effects of flow types and size of molten carbonate fuel cells (MCFCs) were investigated using CFD simulation. In the simulation, the current collector of MCFCs were assumed to be an porous media. With the area of $0.09m^2$, the effect of flow types such as Co-flow, Counter-flow, Cross-flow were studied. After that the effect of the size and flow direction was studied. Among three-flow types, MCFCs with co-flow type shows more uniform distribution and current density distribution.

• Journal of Hydrogen and New Energy
• /
• v.30 no.2
• /
• pp.155-162
• /
• 2019

The energy management technology for an independent fuel cell-battery hybrid system is developed for a household usage. To develop an efficient energy management technology, a simulation model is first developed. After the model is verified with experimental results, three energy management schemes are developed. Three control techniques are a fuzzy logic control (FLC), a state machine control (SMC), and a hybrid method of FLC and SMC. As the fuel cell-battery hybrid system is used for a house, battery state of charge (SOC) regulation is the most important factor for an energy management because SOC should be kept constant every day for continuous usage. Three management schemes are compared to see SOC, power split, and fuel cell power variations effects. Experimental results are also presented and the most favorable strategy is the state machine combined fuzzy control method.

• Journal of Hydrogen and New Energy
• /
• v.30 no.2
• /
• pp.170-177
• /
• 2019

Continuous solid circulation test at high temperature and high pressure conditions and batch type reduction-oxidation tests were performed to check feasibility of a 0.5 MWth chemical looping combustion system. Pressure drop profiles were maintained stable during continuous solid circulation up to 16 hours. Therefore, we could conclude that the solid circulation between an air reactor and a fuel reactor could be smooth and stable. The measured fuel conversion and $CO_2$ selectivity were high enough even at high capacity and even after cyclic tests. Therefore, we could expect high reactivity of oxygen carrier at real operation condition.

• Journal of Hydrogen and New Energy
• /
• v.30 no.2
• /
• pp.178-187
• /
• 2019

Due to the increasing demand of high rank coal, the use of low rank coal, which has economically advantage, is rising in various industries using carbonaceous solid fuels. In addition, the severe disaster of global warming caused by greenhouse gas emissions is becoming more serious. The Republic of Korea set a goal to reduce greenhouse gas emissions by supporting the use of biomass from the Paris International Climate Change Conference and the 8th Basic Plan for Electricity Supply and Demand. In line with these worldwide trends, this paper focuses on investigating the combustibility of high rank coal Carboone, low rank coal Adaro from Indonesia, Baganuur from Mongolia and, In biomass, wood pellet and herbaceous type Kenaf were simulated as kinetic reactivity model. The accuracy of the pore development model were compared with experimental result and analyzed using carbon conversion and tau with grain model, random pore model, and flexibility-enhanced random pore model. In row lank coal and biomass, FERPM is well-matched kinetic model than GM and RPM to using numerical simulations.

• Journal of Hydrogen and New Energy
• /
• v.30 no.2
• /
• pp.128-135
• /
• 2019

In this study, the mesoporous $SiO_2$ (5, 10, or 15 wt%) was incorporated into the polybenzimidazole matrix in order to improve the proton conduction as well as physiochemical properties of composite membrane. The chemical structure of mesoporous $SiO_2$ and crystallinity of as-prepared membranes were analyzed by Fourier-transform infrared (FT-IR) spectroscopy and X-ray diffraction (XRD) analysis, respectively. The thermal stability of the pristine $X_1Y_9$ and composite membranes were evaluated by thermogravimetric analyzer (TGA). On other side, the physical and chemical properties of the pristine $X_1Y_9$ and composite membranes were also determined by acid uptake and oxidative stability tests, respectively. With the incorporation of 15 wt% $SiO_2$, the composite membrane exhibits the higher proton conductivity that may be applicable for non-humidified high temperature fuel cell applications.

• Journal of Hydrogen and New Energy
• /
• v.30 no.2
• /
• pp.163-169
• /
• 2019

This study is a research to compare efficiency of new cooling system (chiller, pre-cooler) to that of the conventional system at the hydrogen refueling station (HRS). This study includes contents for thermodynamic comparison of cooling system for HRS and comparison of pros and cons of its components. So It is to establish design concept of cooling system of HRS supplying with fuel cell electric vehicle (FCEV). HRS is charging high pressure H2 (700 bar) to FCEV. However cooling system is need to prevent temperature rise in tank. This cooling system consists of pre-cooler and chiller system.