• Title/Summary/Keyword: Inert gas

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Thermal Spalling and Resistance to Slag Attack in Porous High Alumina Ceramic (According to Pore Size) (고Alumina질 다공성 세라믹스의 내열충격성 및 내Slag성 (기공크기에 따른))

  • 김병훈;나용한
    • Journal of the Korean Ceramic Society
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    • v.30 no.9
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    • pp.747-753
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    • 1993
  • The investigation was carried out to study the behaviors of the pore size and porosity, the mechanical strength, the resistance to thermal spallings and slag attacks according to particle sizes of starting raw materials in porous high Alumina ceramics. This porous ceramics have been used in processing of the clean steel by the blowing of the inert gas. The required properties in the practice are the suitable pores size, the sharp pores distribution for a uniform blowing of the gas, the strong corrosion resistance to slags and molten metals and the resistance to thermal spalling. The optimized properties in porous high alumina ceramics of the specimen No. 3 was found to be the very low slag intrusion and the superior resistance to thermal spalling because of the suitable pore size of 2.5${\mu}{\textrm}{m}$, the porosity of 30% and the high sinterability.

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Rearrangement of Benzyl-type Radical in Corona Discharge of 2,6-Dichlorotoluene

  • Yoon, Young-Wook;Lee, Seung-Woon;Lee, Sang-Kuk
    • Bulletin of the Korean Chemical Society
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    • v.31 no.9
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    • pp.2479-2482
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    • 2010
  • Using a pinhole-type glass nozzle equipped for a corona-excited supersonic expansion (CESE), precursor 2,6-dichlorotoluene seeded in a large amount of inert carrier gas helium was discharged to produce jet-cooled but electronically excited benzyl-type radicals. The visible vibronic emission spectrum was recorded with a long-path monochromator to observe vibronic bands in the $D_1{\rightarrow}D_0$ electronic transition of benzyl-type radicals. The spectral analysis revealed the generation of not only the 2,6-dichlorobenzyl radical as a typical product, but also the o-chlorobenzyl radical as an unexpected species, which indicates the possible molecular rearrangement in eliminating a chlorine atom from the benzene ring. A possible mechanism is proposed for the formation of the o-chlorobenzyl radical from the precurs or in the gas phase.

Thermal Analysis on Triple-Passage Heat Exchangers for a Continuous Hot-Steel Tube Cooling System

  • Ko, Bong-Hwan;Park, Seung-Ho
    • International Journal of Air-Conditioning and Refrigeration
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    • v.10 no.1
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    • pp.10-18
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    • 2002
  • The objective of present study is to analyze a concentric triple-passage heat exchanger for an optimal design of a continuous hot steel-tube cooling system, where a hot-steel tube line is passing through an antioxidant gas with a constant speed. Velocities and temperatures of the inert gas flowing between inner and outer tubes are calculated theoretically for laminar and numerically for turbulent flow regimes. From their profiles Nusselt numbers and friction factors are calculated (or various ratios of inner/outer tube radii and relative velocities. With these Nusselt numbers triple-passage heat exchangers are investigated for their thermal characteristics. It is shown that heat transfer coefficients based on ratios of average heat fluxes from inner and outer tubes might result in great errors for the temperature distributions of the flows, since local heat transfer coefficients for flows through an annulus are dependent on local wall heat flux ratios.

Cold spray technology as a potential additive manufacturing (3D 프린팅 공정 관점의 저온분사 기술)

  • Kim, Hyeong-Jun;Yun, Sang-Hun
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2017.05a
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    • pp.90-90
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    • 2017
  • Cold spray (Cold gas dynamic spray, kinetic spray) is the latest spray coating process that is known as solid state deposition process. In cold spray, inert gases (typically nitrogen and helium) accelerate powder particles prior to impact onto the substrate. Accelerating particles start to deposit onto the substrate after reaching certain critical velocities depending on the coating materials and substrate. Since process gas temperatures are kept below to melting temperature of the coating materials, it is possible to spray temperature sensitive materials such as copper and titanium, nanocrystal materials, and amorphous metals without affecting the phase change and oxide formation. It is also possible to deposit thick coatings because cold spray coatings present compressive residual stresses. This ability to deposit thick coatings is suitable to repair or rebuild parts as an additive manufacturing process. In this presentation, cold spray is introduced and compared to other additive manufacturing processes such as laser and electron beam based processes. It is also presented some applications especially in the view point of additive manufacturing process.

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Straightening of the micro wires (극세선의 직선화 처리에 관한 연구)

  • Kim W. K.;Kim B. H.;Kim H. Y.;Kim N. S.;Shin H. K.;Hong N. P.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2004.10a
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    • pp.83-88
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    • 2004
  • Micro wires manufactured by the straightening progress are widely used in bio-medical and semi-conductor fields. In this study, we have developed a novel straightener which uses the direct heating method for straightening. In order to avoid the surface oxidization, during the heating process, we supplied the inert gas(Ar) and examined the effect of the gas flow rate. The effect of the tension and the current applied to the tungsten micro wires were thoroughly studied. From various experiments, it was found that when the tension is $500{\sim}600gf$ and the current is about 1.5A, we obtained higher straightness(${\approx}1{\mu}m/1000{\mu}m$) and roundness ($<{\pm}2{\mu}m/100{\mu}m$).

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A Study on the Flame Extinguishing Characteristics of Inerting Gaseous Agents (불활성가스계 소화약제의 불꽃소화 특성에 관한 연구)

  • Kim, Sung-Min;Shin, Chang-Sub;Park, Jae-Man
    • Proceedings of the Korea Institute of Fire Science and Engineering Conference
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    • 2008.04a
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    • pp.148-150
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    • 2008
  • Halon gas agent has been widely used as the extinguishing agent for B class and C class fires because of its excellent extinguishing power. But Halon was found to contribute to the ozone layer destruction, eventually Halon designated as one of ozone-layer-destroying materials in the Montreal Protocol in 1987, In this study, in the context of such researches, we measured the characteristics of flame concentrations of inert gaseous agents by Cup-burner method.

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A Gas Phaes Kinetic Study of the Energy Transfer by using the High Power CO$_2$ Laser. (II). Decomposition of $BrCH_2CH_2CH_2CH_2Cl$

  • Lee, Yong-Sik;Kim, Yang-Sik;Jeoung, Sae-Chae;Choo, Kwang-Yul
    • Bulletin of the Korean Chemical Society
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    • v.9 no.3
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    • pp.161-164
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    • 1988
  • Infrared multiphoton decompositions (IRMPD) of $BrCH_2CH_2CH_2CH_2Cl$ were studied by using the pulsed $CO_2$laser. At 0.3 J laser energy the experimentally observed product ratios could be reasonably explained by the RRKM calculation with initial excitation energy of ca. 80 Kcal/mol. The pressure dependence of product yields led us to conclude that the collisional deactivation by the inert gas decreased the yield of low energy dissociation channel more significantly.

Effects of Surfactant on SF6 Gas Hydrate Formation Rate (가스 하이드레이트 형성 원리를 이용한 SF6 처리 기술에 관한 연구)

  • Lee, Bo-Ram;Lee, Hyun-Ju;Kim, Shin-Ho;Lee, Ju-Dong;Kim, Yang-Do
    • Korean Journal of Materials Research
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    • v.18 no.2
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    • pp.73-76
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    • 2008
  • [ $SF_6$ ] gas has been widely used as an insulating, cleaning and covering gas due to its outstanding insulating feature and because of its inert properties. However, the global warming potential of $SF_6$ gas is extremely high relative to typical global warming gases such as $CO_2$, CFCs, and $CH_4$. For these reasons, it is necessary to separate and collect waste $SF_6$ gas. In this study, the effects of a surfactant (Tween) on the formation rate of $SF_6$ gas hydrates were investigated. The $SF_6$ gas hydrate formation rate increased with the addition of Tween and showed a nearly 6.5 times faster hydrate formation rate with an addition of 0.2 wt.% Tween compared to an addition of pure water. This is believed to be due to the increased solubility of $SF_6$ gas with the addition of the surfactant. It was also found that $SF_6$ gas hydrate in the surfactant solution showed two-stage hydrate formation rates with a formation rate that increased rapidly in the 2nd stage.

Effect of Partial Oxidation of Wood and RDF in a Fluidized Bed (유동상 반응로 조건에서 목재와 RDF 부분 산화의 영향)

  • Kim, Tae-Hyun;Choi, Sang-Min
    • Journal of the Korean Society of Combustion
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    • v.13 no.2
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    • pp.23-32
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    • 2008
  • Gasification characteristics in the fluidized bed reactor are essential for the design of a gasification furnace to optimize the operation condition. Moisture content of the solid fuel is one of the important factors to influence directly the gasification characteristics. So it is necessary to investigate the effect of moisture content of solid fuel in partial oxidation condition. Gasification characteristics are investigated with results from thermogravimetric analyzer and lab-scale fluidized bed reactor for wood and RDF samples along with changing moisture contents. Additionally lab-scale fluidized bed reactor was run continuously and gas concentrations at the exit were measured. It is observed that the rate of reaction in partial oxidation condition is between the results from the combustion environment and from the inert condition. Moisture content in a particle slows down the heating rate of a particle. So, reaction is delayed by the moisture content. However, RDF samples those are easy to break-up don't show the effect of moisture content. The result of continuous operation condition shows that proper moisture content promotes gasification because steam from the particles helps gasification of the solid fuel. A simulation to predict the syn-gas composition was conducted by the Aspen Plus process simulator. The cold gas efficiency of the experiment was compared with results from the simulation.

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Production of Carbonized Rice Husk by a Cyclone Combustor(II) (사이클론 연소기를 이용한 탄화왕겨의 제조(II))

  • 김원태;노수영
    • Journal of Biosystems Engineering
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    • v.24 no.6
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    • pp.487-492
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    • 1999
  • One of effective utilization method of rice husk is to utilize it as culture material by carbonizing the rice husk. As a second part of a series to investigate the effective and continuous production of carbonized rice husk by a cyclone combustor, a non-slagging vertical cyclone combustor without vortex collector pocket was introduced. Isothermal and mixed firing with LPG and rice husk were undertaken in order to characterize the system. Inert rice husk was used during the isothermal test to find mass of rice husk collected. It was impossible to ignite rice husk itself over the experimental conditions considered in this experiment. Cyclone combustor was operated at temperatures of 1,273~1,473K. Detailed combustion data were obtained from a pilot unit with the air flow rate of 70m$^3$/h and rice husk feed of 2kg. The equivalence ratio ranged from 0.66 to 3.48. The auxiliary gas flow rate was varied from 3.22 to 12.86$\ell$/min. The weight reduction, pH and particle size distribution of carbonized rice husk were measured to evaluate the quality of carbonized rice husk. An analysis of exhaust gas emission was conducted to characterize the combustor. The required carbonized rice husk could be obtained at equivalence ratio of 1.68~2.17, combustor temperature of 1,273~1,373K and auxiliary gas flow rate of 3.22~6.43$\ell$/min. A method to reduce CO emissions should be employed.

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