• Title/Summary/Keyword: In Situ Degradation

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Evaluating Green Network based on Pixel of Landsat TM Satellite Image (Landsat TM 위성영상 픽셀 기반의 녹지 연계망 평가)

  • Lee, Dong-Youn;Um, Jung-Sup
    • Spatial Information Research
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    • v.18 no.2
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    • pp.1-12
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    • 2010
  • At present, monitoring programmes for green network have been mainly based on field sampling, which relies on attributes of an area at one point in time, reflecting an emphasis on the small number of in-situ data. One of the major disadvantages of traditional field monitoring is that it is costly, laborious and time consuming due to the large number of samples required. The aim of this research was to evaluate green network based on pixel of Landsat TM satellite image. An empirical study for a case study site was conducted to demonstrate how a standard remote sensing technology can be used to assist in monitoring the green network based on pixel. The pixel-based analysis made it possible to identify area-wide patterns of green network subject to many different type of artificial structures, which cannot be acquired by traditional field sampling. It was demonstrated that the degradation trends of green network could be used effectively as an indicator to restrict further development of the sites since the quantitative data generated from remote sensing can present area-wide visual evidences by permanent record. It is anticipated that this research output could be used as a valuable reference to support more scientific and objective decision-making in monitoring green network.

Compatibilization of PC/SAN Blends via Ultrasound-irradiated Melt Mixing (초음파가 조사되는 용융 혼합에 의한 폴리카보네이트/스티렌-아크릴로니트릴 혼합물의 상용화)

  • 김형수
    • Polymer(Korea)
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    • v.28 no.3
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    • pp.225-231
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    • 2004
  • High intensity ultrasound was irradiated to induce mechano-chemical degradation during melt processing of polycarbonate (PC) and styrene-co-acrylonitrile (SAN) in an intensive mixer. It was found that macroradicals of PC and SAM can be generated during ultrasound assisted melt processing; which, in turn, provides a useful route to achieve in-situ compatibilization for the blends of PC and SAM by their mutual coupling. Effectiveness of compatibilization was assessed by investigating phase morphology and mechanical properties of the blends. It was observed that domain size was reduced and the stability of morphology was well maintained even after annealing treatment of the blends. In audition, the enhancement of mechanical properties such as elongation at break and tensile strength was evident, which added further confirmation on the desirable feature that sonication of melt-blends is able to enhance intermolecular interaction by promoting chemical bonds between dissimilar polymers without use of any compatibilizers.

In-situ TiO2 Formation and Performance on Ceramic Membranes in Photocatalytic Membrane Reactor (광촉매 반응기용 세라믹 막에의 TiO2 층 형성과 성능평가)

  • Ahmad, Rizwan;Kim, Jin Kyu;Kim, Jong Hak;Kim, Jeonghwan
    • Membrane Journal
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    • v.27 no.4
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    • pp.328-335
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    • 2017
  • Fabricating photocatalytic composite membrane with a mesoporous and tailored morphological structure would have significant implication for environmental remediation. In this study, we reported hybrid $TiO_2$ immobilized photocatalytic membrane and its application for the treatment of dye solution. Photocatalytic film with high porosity and homogeneity was fabricated by graft copolymer as polymer template. Hybridization of membrane filtration with photocatalysis was successfully achieved by photocatalytic membrane reactor developed. Result showed that membrane permeability was significantly reduced after immobilizing the $TiO_2$ film on bare $Al_2O_3$ support. The membrane characterization indicated that well organized $TiO_2$ film was successfully formed on $Al_2O_3$ support. Benefiting from the controlled morphology of $TiO_2$ film, the composite membrane exhibited almost complete degradation of organic dye within 5 h of filtration under UV illumination. Langmuir-Hinshelwood model explained degradation of organic dye. First-order rate constant was approximately six times with $TiO_2$ immobilized composite ceramic membrane, higher than the one with the bare $Al_2O_3$ support (0.0081 vs. $0.0013min^{-1}$).

Mechanical Properties on Poly Lactic Acid based Graft Copolymer with Polyethylene Glycol Acrylate (Polyethylene Glycol Acrylate를 이식 공중합 기반의 Poly Lactic Acid에 관한 기계적 특성)

  • Kim, Ki-Jun;Sung, Wan-Mo;Kim, Joo-Han;Jung, Hyung-Hak
    • Journal of the Korean Applied Science and Technology
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    • v.34 no.3
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    • pp.643-649
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    • 2017
  • Biodegradable enzymes such as lipase and proteinase can hydrolyze not only fatty acid esters and triglycerides, but also aliphatic polyesters. We measured the biodegradability that biodegradable enzymes have an important role in the degradation of natural aliphatic poly material such as PLA, corn starch, and polyethylene glycol in the natural environment. However, we investigated on the biodegradability of PLA, PLA and Polyethylene acrylate blended, and PLAcoPolyethylene polymerized with PLA graft copolymer Polyethylene glycol acrylate. When prepared biodegradable polymers. the Mechanical properties of them were measured on Biodegradability, thermal properties, real time in-situ electrical monitoring of polymers resin. Therefore BOD and biodegradation of PLAcoPolyethylene was graft copolymerized with PLA and polyethylene acrylate were measured at a lower rate than the other samples.

Nutritional Factors Affecting Efficiency of a Bioremediation Process for Diesel-Contaminated Soil (경유오염 토양의 생물정화공정에 대한 영양인자의 영향 분석)

  • No, Sang-Cheol;Lee, Cheol-Hyo;Jang, Deok-Jin
    • KSBB Journal
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    • v.14 no.4
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    • pp.503-510
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    • 1999
  • In order to analyze nutritional factors affecting in situ bioremediation of diesel degradation and cell viability were studied by varying nutritional conditions. In column experiments packed with diesel-contaminated soil, nitrogen was found to be the major limiting nutrient. When nitrogen was added to soil at four different levels of C : N (100 : 5, 100 : 10, 100 : 15, and 100 : 20 mg N/kg dry soil), the greatest simulation of microbial activity occurred at the lowest, rather than the highest nitrogen addition. However, no significant effects was observed when phosphorus and air were added. No matter how the incubation mode varied, less than 50% of the diesel was remained after 7 days of treatment, presumably because the residual hydrocarbons were adsorbed on soil particles, adsorption

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Evaluation on Removal Efficiency of Methylene Blue Using Nano-ZnO/Laponite/PVA Photocatalyzed Adsorption Ball (Nano-ZnO/Laponite/PVA 광촉매 흡착볼의 메틸렌블루 제거효율 평가)

  • Oh, Ju Hyun;Ahn, Hosang;Jang, Dae Gyu;Ahn, Chang Hyuk;Lee, Saeromi;Joo, Jin Chul
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.9
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    • pp.636-642
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    • 2013
  • In order to overcome drawbacks (i.e., filtration and recovery) of conventional powder type photocatalysts, nano-ZnO/Laponite/PVA (ZLP) photocatalyzed adsorption balls were developed by using in situ mixing of nanoscale ZnO as a photocatalyst, and Laponite as both adsorbent and supporting media in deionized water, followed by the poly vinyl alcohol polymerization with boric acid. The optimum mixing ratio of nano-ZnO:Laponite:PVA:deionized water was found to be 3:1:1:16 (by weight), and the mesh and film produced by PVA polymerization with boric acid might inhibit both swelling of Laponite and detachment of nanoscale ZnO from ZLP balls. Drying ZLP balls with microwave (600 watt) was found to produce ZLP balls with stable structure in water, and various sizes (55~500 ${\mu}m$) of pore were found to be distributed based on SEM and TEM results. In the initial period of reaction (i. e., 40 min), adsorption through ionic interaction between methylene blue and Laponite was the main removal mechanism. After the saturation of methylene blue to available adsorption sites for Laponite, the photocatalytic degradation of methylene blue occurred. The effective removal of methylene blue was attributed to adsorption and photocatalytic degradation. Based on the results from this study, synthesized ZLP photocatalyzed adsorption balls were expected to remove recalcitrant organic compounds effectively through both adsorption and photocatalytic degradation, and the risks of environmental receptors caused by detachment of nanoscale photocatalysts can be reduced.

Effect of Oxygen on the Magnetic and Recording Characteristics of Magneto-Optical Disk (광자기 디스크의 기록 및 자기적 특성에 산소가 미치는 영향)

  • Choe, G.
    • Journal of the Korean Magnetics Society
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    • v.3 no.3
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    • pp.229-233
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    • 1993
  • The effects of differential partial pressures of oxygen during sputtering on the magnetic and recording characteristics of magneto-optical disks were investigated. Different flows of oxygen were deliberately introduced into the sputtering chamber to have a variety of partial pressures of oxygen during sputtering. A residual gas analyzer was employed to monitor the oxygen peak before, during, and after sputtering and to estimate the reacted oxygen amount. Most of the oxygen introduced into the chamaber was reacted during sputtering. As the partial pressure of oxygen increased, the oxygen content of the TbFeCoCr film increased also. The oxygen appeared to be bound as Tb-O, effectively decreasing the magnetically active Tb content of the film The coercivity decreased but the squareness of the Kerr hysteresis loops was still excellent. The perpendicular anisotropy was not significantly affected by oxygen amount. The carrier-to-noise ratio, includi!1g the write power sensitivity and bias field sensitivity did not change too much with oxygen content in the film The disks sputtered with oxygen showed better bias field sensitivity with lower write power threshold than the disk sputtered without oxygen, due to high demagnetization during domain formation. No significant degradation of coercivity for the disk sputtered oxygen was observed during an accelerated aging test.

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Genomic DNA Extracted from Ancient Antarctic Glacier Ice for Molecular Analyses on the Indigenous Microbial Communities

  • Lee, Sang-Hoon;Bidle, Kay;Falkowski, Paul;Marchant, David
    • Ocean and Polar Research
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    • v.27 no.2
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    • pp.205-214
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    • 2005
  • From ancient Antarctic glacier ice, we extracted total genomic DNA that was suitable for prokaryotic 16S rDNA gene cloning and sequencing, and bacterial artificial chromosome (BAC) library and end-sequencing. The ice samples were from the Dry Valley region. Age dating by $^{40}Ar/^{39}Ar$ analysis on the volcanic ashes deposited in situ indicated the ice samples are minimum 100,000-300,000 yr (sample DLE) and 8 million years (sample EME) old. Further assay proved the ice survived freeze-thaw cycles or other re-working processes. EME, which was from a small lobe of the basal Taylor glacier, is the oldest known ice on Earth. Microorganisms, preserved frozen in glacier ice and isolated from the rest of the world over a geological time scale, can provide valuable data or insight for the diversity, distribution, survival strategy, and evolutionary relationships to the extant relatives. From the 16S gene cloning study, we detected no PCR amplicons with Archaea-specific primers, however we found many phylotypes belonging to Bacteria divisions, such as Actinobacteria, Acidobacteria, Proteobacteria $({\alpha},\;{\beta},\;and\;{\gamma})$, Firmicutes, and Cytophaga-Flavobacterium-Bacteroid$. BAC cloning and sequencing revealed protein codings highly identical to phenylacetic acid degradation protein paaA, chromosome segregation ATPases, or cold shock protein B of present day bacteria. Throughput sequencing of the BAC clones is underway. Viable and culturable cells were recovered from the DLE sample, and characterized by their 16S rDNA sequences. Further investigation on the survivorship and functional genes from the past should help unveil the evolution of life on Earth, or elsewhere, if any.

Reductive Degradation Kinetics and Pathways of Chlorophenolic Organic Pollutants by Nickel-Coated Zero Valent Iron (니켈로 코팅된 영가금속을 이용한 염소계 페놀화합물의 반응경로 및 반응율 평가)

  • Shin, Seung-Chul;Kim, Young-Hun;Ko, Seok-Oh
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.5
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    • pp.487-493
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    • 2006
  • Reductive dechlorination of chlorophenols by nickel coated iron was investigated to understand the feasibility of using Ni/Fe for the in situ remediation of contaminated groundwater. Zero Valent Iron(ZVI) was amended with Ni(II) ions to form bimetal(Ni/Fe). Dechlorination of five chlorophenol compounds and formation of intermediates were examined using Ni/Fe. Rate constant for each reaction pathway was quantified by the numerical integration of a series of differential rate equation. Experimental results showed that the sequence of hydrodechlorination rate constant was in the order of 2-CP>4-CP>2,4-DCP>2,4,6-TCP>2,6-DCP. The hydrodechlorination pathways for the conversion of each chlorophenol compound involves a full dechlorination to phenol via both concerted and stepwise mechanisms. Reaction pathways and corresponding kinetic rate constants were suggested based on the experiments and numerical simulations.

Integral Method of Stability Analysis and Maintenance of Slope (비탈면 안정해석과 유지관리의 통합해석기법)

  • Park, Mincheol;Yoo, Byeongok;Baek, Yong;Hwang, Youngcheol
    • Journal of the Korean GEO-environmental Society
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    • v.17 no.3
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    • pp.27-35
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    • 2016
  • Even if the various data analyzing methods were suggested to examine the measured slope behaviors, it is difficult to find methods or procedures for connecting the analyzed results of slope stability and measured slope data. This research suggests the analyzing methods combing the stability analysis and measured data based on progressive failure of slope. Slope failure analysis by time degradation were calculated by strength parameters composed of strength reduction coefficients, also which were compared to the measured data according to the variations of safety factor and displacement of slopes. The accumulated displacement curve were shown as 3rd degree polynomials by suggested procedures, which was the same as before researches. The reverse displacement velocity curves were shown as linear function for prediction of brittle slope failures, also they were shown as 3rd degree polynomials for ductile slope failures, which were the same as the suggested equation by Fukuzono (1985) and they were very similar behaviors to the in-situ failure cases.