• 제목/요약/키워드: Hybrid membrane

검색결과 315건 처리시간 0.027초

해양심층수담수화를 위한 유무기계 분리막 개발(1) (Development of Hybrid Membrane composed of Organic and Inorganic Polymers for the Desalination of Deep Ocean Water (I))

  • 김현주;정동호;홍영기;송경헌
    • 한국해양공학회:학술대회논문집
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    • 한국해양공학회 2004년도 학술대회지
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    • pp.7-12
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    • 2004
  • Desalination system of revers osmosis(RO) membrane has been proven to be the most economical not only for the desalination of water containing salts, but also for the concentration of solute. RO membranes were traditionally made of inorganic polymers such. as cellulose acetate(CA), Polyamide(PA). To retain more minerals in deep ocean water, a new hybrid membrane composed of tourmaline film as organic material onto inorganic layer of CA polymer in asymmetric structure was developed for RO membrane process. The performance tests were carried out in the permeability of pure water and the rejection of NaCl solution to evaluate the adaptability for DOW desalination. The results of these basic tests show possibility to apply the new hybrid RO membrane for the desalination with function control.

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PVDF/h-BN hybrid membranes and their application in desalination through AGMD

  • Moradi, Rasoul;Shariaty-Niassar, Mojtaba;Pourkhalili, Nazila;Mehrizadeh, Masoud;Niknafs, Hassan
    • Membrane and Water Treatment
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    • 제9권4호
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    • pp.221-231
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    • 2018
  • A new procedure to produce poly(vinylidene fluoride)/boron nitride hybrid membrane is presented for application in membrane distillation (MD) process. The influence of hexagonal boron nitride (h-BN) incorporation on the performance of the polymeric membranes is studied through the present investigation. For this aim, h-BN nanopowders were successfully synthesized using the simple chemical vapor deposition (CVD) route and subsequent solvent treatments. The resulting h-BN nanosheets were blended with poly(vinylidene fluoride) (PVDF) solution. Then, the prepared composite solution was subjected to phase inversion process to obtain PVDF/h-BN hybrid membranes. Various examinations such as scanning electron microscopy (SEM), wettability, permeation flux, mechanical strength and liquid entry pressure (LEP) measurements are performed to evaluate the prepared membrane. Moreover, Air gap membrane distillation (AGMD) experiments were carried out to investigate the salt rejection performance and the durability of membranes. The results show that our hybrid PVDF/h-BN membrane presents higher water permeation flux (${\sim}18kg/m^2h$) compared to pristine PVDF membrane. In addition, the experimental data confirms that the prepared nanocomposite membrane is hydrophobic (water contact angle: ${\sim}103^{\circ}$), has a porous skin layer (>85%), as well competitive fouling resistance and operational durability. Furthermore, the total salt rejection efficiency was obtained for PVDF/h-BN membrane. The results prove that the novel PVDF/h-BN membrane can be easily synthesized and applied in MD process for salt rejection purposes.

대공간 연성 구조시스템의 종류와 발달과정 (The Type and Development for Structure System with Non-rigid Member)

  • 이주나;박선우;박찬수
    • 한국공간정보시스템학회:학술대회논문집
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    • 한국공간정보시스템학회 2004년도 춘계 학술발표회 논문집 제1권1호(통권1호)
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    • pp.148-157
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    • 2004
  • The structure systems with non-rigid member were classified by the composition type of line and surface members. As a result of the classification, there are 1-way cable structure, cable net and radial cable net structure in the line member system. And there are pneumatic structure and suspension membrane structure in surface member system. In addition, when the line and surface members are composed together, there is the hybrid membrane system which are divided into hanging type and supported type. In this paper, the Korean terms of structure systems with non-rigid member are recommended through this classification. In each the structure systems with non-rigid member, the examples were also investigated considering their historical developments. It present that the light weight structure system and the openness of space have pursued with the developments. So largely, cable net structure with membrane, membrane structure and hybrid structure have used in these days.

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순산소 고율포기시스템 및 침지식 MBR융합공정에서 Biofouling 제어 및 원인물질 규명에 관한 연구 (The Study of Biofouling Control and Cause Material in Hybrid Process of Pure Oxygen and Submerged Membrane Bio-reactor)

  • 이상민;김미형
    • 한국물환경학회지
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    • 제27권1호
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    • pp.44-53
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    • 2011
  • Membrane bio-reactor (MBR) has several advantages over the conventional activated sludge process, including a high biomass, low sludge production, and better permeate quality. Therefore, the MBR have gained popularity for municipal and industrial wastewater treatment. However the MBR usually were used for sewage and low streng th wastewater treatment because of membrane fouling problem and limitation of oxygen transfer into biomass. In this study, the hybrid process combining MBR and pure oxygen was tested for high strength organic wastewater treatment in the COD loading range from 2 to $10kgCOD/m^3{\cdot}day$. The hybrid process, membrane coupled pure oxygen high compact reactor (MPHCR), had been operated for one year and operation parameters, the effect of COD loading, MLSS concentration and the location of membrane module were studied for membrane fouling characteristic. Also membrane resistance test and the component of foulant was analyzed to investigate what is specific foulant in the MBR.

스윕 가스-진공 하이브리드식 탈기막 공정을 활용한 암모니아 폐수처리 및 선택적 회수 (Ammonia Wastewater Treatment and Selective Recovery Using a Sweep Gas-Vacuum Hybrid Type Membrane Degassing Process)

  • 윤홍식;민태진;전민규;임성일;오세철;류경하;이충성;강보식
    • 한국산업융합학회 논문집
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    • 제26권6_2호
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    • pp.1171-1181
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    • 2023
  • In this study, a sweep gas - vacuum hybrid type membrane degassing process was proposed for ammonia wastewater treatment. In addition, the ammonia selective recovery of the hybrid type membrane degassing process was also investigated. As a result, the hybrid type membrane degassing process showed better degassing performance (54.9 mg NH3/m2min for 360 min) than the sweep gas type (32.3 mg NH3/m2min) or vacuum type (22 mg NH3/m2min). Additionally, the hybrid type membrane degassing process showed an excellent ammonia selectivity (103 times compared to Na+ Na+, 133 times compared to Ca2+). The ammonia selectivity was appeared to be due to the conversion characteristics of ammonium ion / dissolved ammonia depending on pH. The results in this study are expected to be used in the development of ammonia wastewater treatment and ammonia recovery in the future.

고분자전해질 연료전지용 유기/무기 복합 전해질 (Organic / inorganic composite membrane for Polymer Electrolyte Membrane Fuel Cell)

  • 최성호;홍현실;이흥찬;김유미;김건
    • 한국전기화학회:학술대회논문집
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    • 한국전기화학회 2003년도 연료전지심포지움 2003논문집
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    • pp.169-171
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    • 2003
  • Organic/inorganic hybrid membranes have been prepared and evaluated as polymer electrolytes in a polymer electrolyte membrane fuel cell (PEMFC). Previously, partially fluorinated poly (arylenether) was synthesized and the polymer was sulfonated by fuming sulfuric acid$(30\%\;SO_3)$. Modification of these polymers with coupling agent and inorganic materials was carried out to prepare membranes. Membranes cast from these materials were investigated in relation to the proton conductivity and weight loss at the room temperature. It was found that these membranes had a higher conductivity of $10^{-2}\;Scm^{-1}$ at the room temperature. But inorganic materials have leaked out from the hybrid membrane. If this problem is resolved, organic/inorganic hybrid membranes will become satisfactory Polymer electrolytes for the PEMFC.

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나노 공진기의 1차 고유진동수에 미치는 링클 영향 연구 (Study of Wrinkle Effect on Primary Natural Frequency of Nano-resonator)

  • 윤주일;강상욱
    • 한국소음진동공학회논문집
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    • 제22권12호
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    • pp.1157-1163
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    • 2012
  • Natural frequency of a nano-resonator via nano transfer printing is studied. Through a nano transfer printing, the hybrid metal/polymer membrane may evolve a wrinkle. Natural frequency of a wrinkled hybrid membrane decreases significantly, as the amplitude to wavelength ratio becomes larger. To address the design limit of a hybrid nano resonator, we perform parametric study using finite element analysis. Specifically, we study the effects of the Young's modulus ratio of the metal/polymer membrane, thickness ratio and wrinkle amplitude to wavelength ratio, respectively. The results from the parametric studies can serve as guideline to design hybrid nano resonators.