• 대한기계학회논문집A
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• 제24권1호
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• pp.156-162
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• 2000

Sensitized STS 304 stainless steel crack growth rate(CGR) in high temperature water was investigated under trapezoidal wave loading test using fracture mechanics techniques. The CGR, due to stress corrosion cracking(SCC), were systematically measured as a function of the stress intensity factor and stress. holding time under trapezoidal wave loading. In high temperature water, CGR was enhanced by a synergistic effects in combination with an aggressive environment and mechanical damage. The CGR, $(da/dN)_{env}$ was basically described as a summation of the environmentally assisted crack growth rate $(da/dN)_{SCC}$, $(da/dN)_{CF}$ and fatigue crack growth rate in air $(da/dN)air,. The CGR, $(da/dN)_{env}$, increased linearly with increasing stress holding time. The CGR, $(da/dN)_{SCC}$ decreased linearly with increasing stress holding time. Fracture surface mode varied from trans-granular cracking to inter-granular cracking with increasing stress holding time.

• 한국환경보건학회지
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• 제29권3호
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• pp.65-71
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• 2003

The injection concentration of corrosion inhibitor increases under the pH 7, temperature of 2$0^{\circ}C$, and alkalinity of 35 mg/l (as CaCO$_3$), the corrosion rate gradually decreased. When the corrosion inhibitor of 10 mg/l is injected, the corrosion rate for carbon steel pipe, galvanized steel pipe, and copper pipe reduces for 37, 66 and 61 % respectively that it is more efficient on galvanized steel pipe and copper pipe. As a result of examination of corrosion rate at pH 6, 7, and 8 when injecting 10 mg/l of corrosion inhibitor under the conditions of 2$0^{\circ}C$ in water temperature and 35 mg/l (as CaCO$_3$) in alkalinity, the efficiency of the corrosion inhibitor increases as the pH increases. For carbon steel pipe, it does not show much a difference with the change of the pH condition, but galvanized steel pipe and copper pipe clearly show the corrosion rate depending on the change of the pH condition. The efficiency of corrosion inhibitor is low as the concentration of residual chlorine is high, but it does not show a great influence at 0.4 mg/l or less. For each pipe type, in the case of carbon steel pipe, the range of increase of corrosion speed following the residual chloride is higher than the other pipe types. In the meantime, the effect following the residual chlorine in copper pipe is low.

• 한국재료학회지
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• 제14권4호
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• pp.251-259
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• 2004

In the development of the advanced spent fuel management process based on the molten salt technology, it is essential to choose the optimum material for the process equipment handling molten salt. Corrosion behavior of Ni 200 and Ni-base alloys in molten salt of LiCl-$Li_2$O under oxidation atmosphere was investigated in the temperature range of $650～800^{\circ}C$ for 24～312 hrs. The order of corrosion rate was Ni 200 > Inconel 690 > Inconel 601 > Inconel 600. Inconel 600 alloy showed the highest corrosion resistance among the examined alloys, but Ni 200 exhibited the highest corrosion rate. Corrosion products of Inconel 600 and Inconel 601 were $Cr_2$$O_3$ and $NiFe_2$$O_4$. In case of Inconel 690, a single layer of $CrO_2$$O_3$ was formed in the early stage of corrosion and an outer layer of $NiFe_2$O$_4$ and inner layer of $Cr_2$$O_3$ were formed with increase of corrosion time. Inconel 600 showed local corrosion behavior and Inconel 601, 690 showed uniform corrosion behavior.

• 대한기계학회논문집A
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• 제25권5호
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• pp.772-778
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• 2001

In this study, corrosion fatigue characteristics of 12Cr alloy steel were investigated in 3.5wt.% NaCl solution of 150$^{\circ}C$ and 4.5bar. Behavior of corrosion fatigue cracks was measured by the indirect compliance method and compared with the results in distilled water and in air. 1) 12Cr alloy steel was susceptible to temperature. Its susceptibility was increased as the temperature was increased. 2) The crack growth characteristics of 12Cr alloy steel in distilled water were similar to 3.5wt.% NaCl solution. 3) The temperature of solution affects to the crack growth characteristics of 12Cr alloy steel. In corrosion solutions of 4.5bar, 150$^{\circ}C$, fracture surfaces of corrosion fatigue crack growth at a/W=0.3 was showed the trans-granular fracture suface. As the crack grew up, it was changed to inter-granular type. In condition of high temperature, The crack growth behaviors of 12Cr alloy steel were remarkable.

• Corrosion Science and Technology
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• 제15권3호
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• pp.113-119
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• 2016

Corrosion science faces new challenges in various nuclear environments. Three main areas may be identified where increases of knowledge and understanding have been done and are still needed to face the technical needs: (i) the extension of the service time of nuclear power plants from 40 years, as initially planned, to 60 years and probably more as expected now, (ii) the prediction of long term behaviour of metallic materials in nuclear waste disposal where the corrosion processes have to be predicted over large periods of time, some thousands years and more, (iii) the choice of materials for use at very high temperatures as expected in Generation IV power plants in environments like gas (helium), supercritical water, liquid metals or salts. Service time extension, deep geological waste repositories and high temperature reactors sustain researches and developments to model corrosion phenomena at various scales, from atoms to components.

• Corrosion Science and Technology
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• 제3권6호
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• pp.233-239
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• 2004

Primary water stress corrosion cracking of steam generator tubings occur on many tubes in pressurized water reactors(PWRs), and they are repaired using sleeves or plugs. In order to develop proper repair criteria, it is necessary to know the leak behavior of the tubes, which have stress corrosion cracks. Crack development tests were carried out on the tubes at room temperature, and leak rate and burst pressure were measured on the degraded tubes at room temperature and a high temperature. No leakage was detected on the tubes where 100 % through wall crack developed, at 1560 psi, which is an operating pressure difference of pressurized water reactors(PWRs). In some tests, leak rates of the tubes increased with time at a constant internal water pressure. A test tube showed a very small amount of leakage at 2700 psi in a high temperature pressure test at $282^{\circ}C$, but it disappeared after the pressure increased slightly. Even cracks are 100 % through wall, they need to open in order to reach a certain amount of leak rate at the operating pressure difference.

• 소성∙가공
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• 제33권3호
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• pp.208-213
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• 2024

Ni-based superalloys have exceptional performance in high-temperature strength, corrosion resistance, etc, and it has been widely used in various applications that require corrosion resistance at high-temperature operations. However, the relatively expensive cost of the Ni-based superalloys is one of the major hurdles. The corrosion-resisted alloy(CRA) clad materials can be a cost-effective solution. In this study, finite element analysis of the hot rolling process for manufacturing of the Alloy 625/API X65 steel CRA clad plates is conducted. The stress-strain curves of the two materials are measured in compressive tests for various temperature and strain rate conditions, using the Gleeble tester. Then, strain hardening behavior is modeled following the modified Johnson-Cook model. Finite element analysis of the hot rolled cladding process is performed using this strain rate and temperature dependent hardening model. Finally, the thickness ratio of the CRA and base material is predicted and compared with experimental values.

• 한국표면공학회지
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• 제56권6호
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• pp.443-450
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• 2023

SiC/SiC_f CMC is vulnerable to water vapor corrosion at a high temperature of 1500℃. So, EBC (Environmental Barrier Coating) materials are required to protect Si-based CMCs. Ytterbium silicates are reported to have coefficient of thermal expansion (CTE) similar to that of the base material, such as SiC/SiC_f CMC. When the EBC are materials exposed to high temperature environment, the interface between ytterbium silicates and SiC/SiC_f CMC is not separated, and the coating purpose can be safely achieved. For the perspective of EBC applications, thermally grown oxide (TGO) layer with different CTE is formed by the reaction with water vapor in EBC, which leads to a decrease in life time. In this study, we prepare two types of ytterbium silicates to observe the corrosion behavior during the expose to high temperature and water vapor. In order to observe this behavior, the steam-jet furnace is prepared. In addition, phase formation of these ytterbium silicates is analyzed with microstructures by the before/after steam-jet evaluation at 1500℃ for 100 h.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2010년도 추계학술대회 초록집
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• pp.82.2-82.2
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• 2010

The development of bipolar plate having high efficiency and chemical properties has a major impact on fuel cell applications commercialization. Even though graphite bipolar plate has high electric conductivity and chemical resistance, it has demerits about mass production and brittle property for commercialization. Hence, metallic bipolar plate can be substitute for fuel cell bipolar plate. Although its inadequate corrosion behavior under PEMFC environment lead to a deterioration of membrane by dissolved metal ions, metallic bipolar plate for PEMFC is more suitable for automotive and residential power generation system because of its high mechanical strength, low gas permeability and applicability to mass production. Therefore, several types of coating has been applied to prevent corrosion and oxide film growth and to achieve more high durability. This work presents durability of coated metal bipolar plate for low temperature PEMFC which made for fuel cell vehicle. This results showed surface treatment increase long-term durability, even electric conductivity and corrosion resistance.

• 항공우주시스템공학회지
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• 제11권2호
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• pp.43-50
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• 2017

한반도의 근해는 다양한 해양변화가 있으며, 작전을 수행하는 해군함정, 함재기, 해상운용 비행기, 공군의 전투기, 해안에 위치한 공항 및 비행장 등이 영향을 받는다. 특히 해양환경의 직접적인 영향인 염분은 가스터빈엔진과 같이 고온/고속으로 운용되는 장비에 연료의 황성분과 화학적 변화로 고온부식(Hot Corrosion)이 발생시킨다. 한계값으로 정의 할 수 없지만 염분에 의한 부식은 디미스터(공기흡입구) 높이가 7m 이하일 경우 해상에서 유입되는 염분이 증가하여 부식이 급격하게 증가하였다. 또한 서해보다 동해에서 작전임무를 수행하는 무기체계는 염분도, 풍량, 파고에 의해 비산되는 염분이 상대적으로 많아 부식율이 17% 증가함을 확인하였다. 해상에서 가스터빈엔진을 운용하는 해상무기체계는 염분유입을 최소화하기 위해 해상으로부터 13m이상에서 운용되어야 급격한 고온부식을 최소화 될 것으로 본다.