• 한국미생물·생명공학회지
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• 제28권1호
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• pp.26-32
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• 2000

Electrostatic forces contribute to the high degree of enzyme transition state complementarity in enzyme catalyzed reaction and such forces are modified by the solvent through its dielectric constant and polar properties. The contributions of electrostatic interaction to the formation of ES complex and the stabilization of transition state of the trypsin catalyzed reaction were probed by kinetic studied with high pressure and solvent dielectric constant. A good correlation has been observed between the increase of catalytic efficiency of trypsin and the decrease of solvent dielectric constant. Activation volume linearly decreased as the dielectric constant of solvent decreased, which means the increase in the reaction rae. Moreover, the decrease of activation volume by lowering the solvent dielectric constant implies a solvent penetration of the active with and a reduction of electrostatic energy for the formation of dipole of the active site oxyanion hole. When the 야electric constant of the solvents was lowered to 4.7 unit, the loss of activation energy and that of free energy of activation were 2.262 KJ/mol and 3.169 KJ/mol, respectively. The results of this study indicate that the high pressure kinetics combined with solvent effects can provide unique information on enzyme reaction mechanisms, and the controlling the solvent dielectric constant can stabilize the transition state of the trypsin-catalyzed reaction.

• 세라미스트
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• 제22권1호
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• pp.56-69
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• 2019

Recent advances in low-power sensors and transmitters are driving the search for standalone power sources that utilize unused ambient energy. These energy harvesters can alleviate the issues related to the installation and maintenance of sensors. Particularly piezoelectric energy harvesters, with the ability to convert ambient mechanical energy into useful electricity, have received significant attention due to their high energy density, low cost and operational stability over wide temperature and pressure conditions. In order to maximize the generated electrical power, the natural frequency of the piezoelectric energy harvester should be matched with the dominant frequency of ambient vibrations. However, piezoelectric energy harvesters typically exhibit a narrow bandwidth, thus, it becomes difficult to operate near resonance under broadband ambient vibration conditions. Therefore, the resonating of energy harvesters is critical to generate maximum output power under ambient vibration conditions. For this, energy harvesters should have broadband natural frequency or actively tunable natural frequency with ambient vibrations. Here, we review the most plausible broadband energy harvesting techniques of the multi-resonance, nonlinearity, and self-resonance tuning. The operation mechanisms and recent representative studies of each technique are introduced and the advantages and disadvantages of each method are discussed. In addition, we look into the future research direction for the broadband energy harvester.

• Structural Engineering and Mechanics
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• 제52권6호
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• pp.1177-1191
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• 2014

Reinforced concrete (RC) shear walls are one of the most commonly used lateral-load resisting systems in high-rise buildings. RC Parallel redundancy walls studied herein consist of two parts nested to each other. These two parts have different mechanical behaviors and energy dissipation mechanisms. In this paper, experimental studies of four 1/2-scale specimens representing this concept, which are subjected to in-plane cyclic loading, are presented and test results are discussed. Two specimens consist of a wall frame with barbell-shaped walls embedded in it, and the other two consist of a wall frame and braced walls nested each other. The research mainly focuses on the failure mechanism, strength, hysteresis loop, energy dissipation capacity and stiffness of these walls. Results show that the RC parallel redundancy wall is an efficient lateral load resisting component that acts as a "dual" system with good ductility and energy dissipation capacity. One main part absorbs a greater degree of the energy exerted by an earthquake and fails first, whereas the other part can still behave as an independent role in bearing loads after earthquakes.

• Journal of Photoscience
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• 제12권2호
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• pp.101-107
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• 2005

Infrared multiphoton dissociation of $CHCl_2F$ was studied using $CO_2$ laser excitation. Three products, $C_2Cl_2F_2$, $C_2ClF_3$, and $C_2HClF_2$, were identified by the analysis of the gas mixture from the photoreaction of $CHCl_2F$. The dependence of the reaction probability on added Ar gas pressure and excitation laser pulse energy was investigated. At low pressure (< 10 torr), the reaction probability increased as Ar pressure increased due to the rotational hole-filling effect, while it diminished with the increase of Ar pressure at high pressure (> > 20 torr) due to the collisional deactivation. The ratio of two products $(C_2ClF_3/C_2Cl_2F_2)$ decreased at low pressure (< 10 torr) and increased at high pressure (> 20 torr) with the increase of Ar pressure. The log-log plot of the reaction probability vs. laser pulse energy (${\\phi}$) was found to have a linear relationship, and its slope decreased as the added Ar pressure was increased. The reaction mechanisms for product formation have been suggested and validated by experimental evidences and considering the energetics. Fluorine-chlorine exchange reaction in the intermediate complex has been suggested to explain the formation of $C_2ClF_3$.

• Steel and Composite Structures
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• 제37권2호
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• pp.175-191
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• 2020

In this article, for the first time, the seismic behavior of elliptic-braced moment resisting frame (ELBRF) is assessed through a laboratory program and numerical analyses of FEM specifically focused on the development of global- and local-type failure mechanisms. The ELBRF as a new lateral braced system, when installed in the middle bay of the frames in the facade of a building, not only causes no problem to the opening space of the facade, but also improves the structural behavior. Quantitative and qualitative investigations were pursued to find out how elliptic braces would affect the failure mechanism of ELBRF structures exposed to seismic action as a nonlinear process. To this aim, an experimental test of a ½ scale single-story single-bay ELBRF specimen under cyclic quasi-static loading was run and the results were compared with those for X-bracing, knee-bracing, K-bracing, and diamond-bracing systems in a story base model. Nonlinear FEM analyses were carried out to evaluate failure mechanism, yield order of components, distribution of plasticity, degradation of structural nonlinear stiffness, distribution of internal forces, and energy dissipation capacity. The test results indicated that the yield of elliptic braces would delay the failure mode of adjacent elliptic columns and thus, help tolerate a significant nonlinear deformation to the point of ultimate failure. Symmetrical behavior, high energy absorption, appropriate stiffness, and high ductility in comparison with the conventional systems are some of the advantages of the proposed system.

• Nuclear Engineering and Technology
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• 제55권5호
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• pp.1742-1756
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• 2023

The hydrogen behavior in a nuclear containment vessel is a significant issue when discussing the potential of hydrogen combustion during a severe accident. After the Fukushima-Daiichi accident in Japan, we have investigated in-depth the hydrogen transport mechanisms by utilizing experimental and numerical approaches. Computational fluid dynamics is a powerful tool for better understanding the transport behavior of gas mixtures, including hydrogen. This paper describes a Large-eddy simulation of gas mixing driven by a high-buoyancy flow. We focused on the interaction behavior of heat and mass transfers driven by the horizontal high-buoyant flow during density stratification. For validation, the experimental data of the Containment InteGral effects Measurement Apparatus (CIGMA) facility were used. With a high-power heater for the gas-injection line in the CIGMA facility, a high-temperature flow of approximately 390 ℃ was injected into the test vessel. By using the CIGMA facility, we can extend the experimental data to the high-temperature region. The phenomenological discussion in this paper helps understand the heat and mass transfer induced by the high-buoyancy flow in the containment vessel during a severe accident.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1990년도 봄 학술발표회 논문집
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• pp.72-77
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• 1990

Results are presented of the cyclic loading tests of there low-rise shear wall assembligies using high strength concrete. The possibilities of achieving an acceptable level of energy dissipation in one story shear walls, mainly by flexural yielding, are examined. Mechanisms of flexural and shear resistance are reviewed with emphasis on aspects of sliding shear. Detrimental effects of sliding shear are demonstrated together with improvement achieved by use of diagonal wall reinforcements. It is postulated that with suitably arranged diagonal wall reinforcements a predominantly flexural response mode with good energy dissipation characteristics can be achieved in low-rise shear walls.

• Current Photovoltaic Research
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• 제1권2호
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• pp.73-81
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• 2013

Heterojunction with Intrinsic Thin-layer (HIT) solar cells are currently an important subject in industrial trends for thinner solar cell wafers due to the low-temperature of production processes, which is around $200^{\circ}C$, and due to their high-efficiency of 24.7%, as reported by the Panasonic (Sanyo) group. The use of thinner wafers and the enhancement of cell performance with fabrication at low temperature have been special interests of the researchers. The fundamental understanding of the band bending structures, choice of materials, fabrication process, and nano-scale characterization methods to provide necessary understanding of the interface passivation mechanisms, emitter properties, and requirements for transparent oxide conductive layers is presented in this review. This information should be used for the performance characterization of the developing technologies for HIT solar cells.

• Nuclear Engineering and Technology
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• 제30권3호
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• pp.273-286
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• 1998

As there has arisen a concern that failure of the high burnup fuel under the reactivity-insertion accident(RIA) may occur at the energy lower than the expected, fuel behavior under the rod ejection accident in a typical Westinghouse-designed 950 MWe PWR was analyzed by using the three dimensional nodal transient neutronics code, PANBOX2 and the transient fuel rod performance analysis code, FRAP-T6. Fuel failure criteria versus the burnup was conservatively derived taking into account available test data and the possible fuel failure mechanisms. The high burnup and longer cycle length fuel loading scheme of a peak rod turnup of 68 MWD/kgU was selected for the analysis. Except three dimensional core neutronics calculation, the analysis used the same core conditions and assumptions as the conventional zero dimensional analysis. Results of three dimensional analysis showed that the peak fuel enthalpy during the rod ejection accident is less than one third of that calculated by the conventional zero dimensional analysis methodology and the fraction of fuel failure in the core is less than 4 %. Therefore, it can be said that the current design limit of less than 10 percent fuel failure and maintaining the core coolable geometry would be adequately satisfied under the rod ejection accident, even though the conservative fuel failure criteria derived from the test data are applied.

• Smart Structures and Systems
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• 제24권1호
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• pp.27-35
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• 2019

This paper proposes a quantitative criterion for optimization of actuator placement for the Prestress-Accumulation Release (PAR) strategy of mitigation of vibrations. The PAR strategy is a recently developed semi-active control approach that relies on controlled redistribution of vibration energy into high-order modes, which are high-frequency and thus effectively dissipated by means of the natural mechanisms of material damping. The energy transfer is achieved by a controlled temporary removal of selected structural constraints. This paper considers a short-time decoupling of rotational degrees of freedom in a frame node so that the bending moments temporarily cease to be transferred between the involved beams. We propose and test a quantitative criterion for placement of such actuators. The criterion is based on local modal strain energy that can be released into high-order modes. The numerical time complexity is linear with respect to the number of actuators and potential placements, which facilitates quick analysis in case of large structures.