• Title/Summary/Keyword: Hazardous metal

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A Study on the Toys Assessment of Harmful Substances and Control (완구제품에 함유된 유해물질 및 관리방안에 대한 연구)

  • Kim, Seung-Don;Son, Ki-Sang
    • Journal of the Korean Society of Safety
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    • v.25 no.5
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    • pp.27-32
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    • 2010
  • This study is to investigate and compare domestic hazardous toys with harmful substances with foreign toys so that we can find out management criteria for in cognitive infants. Actually, commercially used toys have been collected and tested to find out more effective management standard. it is tried to produce evaluation criteria of environmentally harmful substance but variety of product is needed for overcoming actual barrier due to lot of difficulty huge cost, time, objectiveness. Therefore, This study does not cover all the above. Establishment of evaluation criteria for product harmfulness made by Government or Local government should be continued to improve. Foreign reference material for toy product in Europe, USA, Japan have been investigated and domestic product have been collected and tested for containing heavy metals, formaldehyde, phthalate in the study. All the test have been made in accordance with KSM ISO 2124 to measure heavy metal transfer into body. Toy product used for the study have been purchased in the real market and some of them contains harmful elements with over standard. Post management system such as RAPEX to control periodically should be established for plastic toy with low quality product.

A Study on the Hearing Disturbance Based on the Classification of Hazardous Occupation (위험직종(危險職種) 분류(分類)에 따른 난청(難聽)의 고찰(考察))

  • Park, Young-Il
    • The Journal of the Korean life insurance medical association
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    • v.2 no.1
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    • pp.122-127
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    • 1985
  • The basis for determining hearing disturbance adopted by the Life Insurance Industry is the loss of hearing power above 80 db on either or both sides, in accordance with the divide sixth method of audiometric test. Different types of small-to-medium-sized enterprises were chosen for the study of the extent of loss and the power of hearing. The following are the findings: 1. The disturbance percentage found among the types of occupation and different levels of age was found to be higher as the subject's ages increased. 2. The heavier the workload and the noisier the environment, the higher the percentage of disturbance. The average percentage of the subjects turned out to be 24.35%. Those engaged in sawing and wood-work showed 49%. Those engaged in machinery and equipment for transportation accounted for 42.6%. Those engaged in the metal products occupied 39.6%. The disturbance percentage among those engaged in such noisy works as press, pipe and sawing showed 32.52%. 28.46% of those workers with three to four years employment turned out to be disturbed in hearing. Of these, a high percentage of 43.9% showed disturbance in conversation or talk. 3. No hearing loss due to occupation beyond the Life Insurance standard of 80 db was found; therefore, the present status poses no problem. Constant attention, however, is needed.

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Control and Investigation for Hazardous Characteristics of Metal Working Fluids Used in Korea - A Study on the Control and Sampling Method for Airborne MWF mist - (우리나라에서 사용하는 광물유의 유해특성과 관리대책에 관한 연구 - 공기중 MWF 미스트의 측정방법과 관리대책 -)

  • Paik, Nam-won;Park, Dong-wook;Yoon, Chung-sik;Cho, Sook-ja;Kim, Shin-bum;Lim, Ho-sub
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.7 no.2
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    • pp.171-180
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    • 1997
  • The objectives of this study were both 10 discuss the sampling method for airborne metalworking fluids(MWF)' mist and 10 suggest measures to minimize worker's exposure to carcinogen contained in metalworking fluids. In order to measure airborne MWF mist, it seems to be appropriate to use NIOSH Method #0500(filler weight) rather than NIOSH Method # 5026(analysis by FTIR). Because MWF mist on PVC filter evaporated and migrated during sampling, worker's exposure to MWF could be underestimated. So, when evaluating worker's exposure to MWF mist, other environmental conditions also must be considered. Enclosure and local exhaust ventilation system seems to he the most effective measure and must be constructed with process facility. In order to control worker exposure to carcinogens contained in MWF, distillation type and condition for crude oil, PAH concentration in MWF, and viscosity index of MWF must legally be described.

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SBA-15 Supported Fe, Ni, Fe-Ni Bimetallic Catalysts for Wet Oxidation of Bisphenol-A

  • Mayani, Suranjana V.;Mayani, Vishal J.;Kim, Sang Wook
    • Bulletin of the Korean Chemical Society
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    • v.35 no.12
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    • pp.3535-3541
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    • 2014
  • Bisphenol A is considered as pollutant, because it is toxic and hazardous to living organisms even at very low concentrations. Biological oxidation used for removing this organic from waste water is not suitable and consequently application of catalytic wet oxidation has been considered as one of the best options for treating bisphenol A. We have developed Fe/SBA-15, Ni/SBA-15 and Fe-Ni/SBA-15 as heterogeneous catalysts using the advanced impregnation method for oxidation of bisphenol A in water. The catalysts were characterized with physico-chemical characterization methods such as, powder X-ray diffraction (PXRD), FT-IR measurements, N2 adsorption-desorption isotherm, thermo-gravimetric analysis (TGA), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and inductively coupled plasma optical emission spectroscopy (ICP-OES) analysis. This work illustrates activity of the catalysts for heterogeneous catalytic degradation reaction revealed with excellent conversion and recyclability. The degradation products identified were not persistent pollutants. GC-MS analysis identified the products: 2,4-hexadienedioic acid, 2,4-pentadienic acid and isopropanol or acetic acid. The leachability study indicated that the catalysts release very little metals to water. Therefore, the possibility of water contamination through metal leaching was almost negligible.

Physicochemical Properties of Landfill Mined Wastes from Old Landfill Site (불량 매립지에서 굴착된 폐기물의 물리화학적 특성평가)

  • 남궁완;이노섭;박준석;인병훈
    • Journal of Environmental Health Sciences
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    • v.28 no.2
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    • pp.99-108
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    • 2002
  • This study was carried out to evaluate the Physicochemical characteristics of mined waste(separated waste and soil) and to predict environmental effect of an old landfill site located at north of Seoul. Municipal solid waster(MSW) had been disposed of at the old landfill site used in this study for about 2 years(1990-1992). The old landfill site selected for this study had accepted mainly municipal solid waste. The landfill-mined waste contained separated waste (40.9%) and soil(59.1%) by wet weight basis. The separated waste consisted of combustible(91.0%) and non-combustible(9.0%). The combustible waste was mainly non-biodegradable plastics. The low heating value of the separated combustible waste, which is calculated by Dulong's equation, was as high as 3,470kcal/kg. According to the Korean Extraction Procedure, separated waste and soil were proved to be not hazardous. The total content of heavy metal in the separated waste and soil met standard of California State, USA. Therefore the separated waste may be relandfilled at a sanitary landfill site and/or burned up at an incinerator, and the separated old soil may be used ad landfill cover-soil at a sanitary landfill site. Water quality of two streams was grade IV, of which water could be used as industrial and agricultural water. The streams near the landfill site might not be contaminated by leachate from the old landfill site. It was estimated that organic matter in the old landfill site would not be actively biodegraded within a short period of time.

Decontamination Performance Assessment for the Plasma Arc Vitrification pilot plant on the basis of Trial Burn Results(I) - Decontamination Characteristics for Hazardous Metal, Radioactive surrogate and Radioactive Tracer in Off-gas (시험연소결과에 근거한 플라즈바 아크방식 유리화 시험 설비의 제염성능 평가(I) - 배기가스중의 유해중금속, 방사성핵종 모의물질 및 방사성핵종 제염특성 -)

  • Chae, Gyung-Sun;Park, Youn-Hwan;Min, Byong-Yun;Chang, Jae-Ock;Park, Jun-Yong;Jeong, Weon-Ik;Moon, Byung-Sik
    • Journal of Radiation Protection and Research
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    • v.25 no.2
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    • pp.99-107
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    • 2000
  • Through the results of off-gas analysis at 3 sampling points in Plasma Arc Melting vitrification pilot plant, it was evaluated the partitioning of spiked materials in off-gas and the decontamination characteristic of off-gas treatment system. Spiked materials are hazard_us heavy metals(Pb, Cd, Hg), radioactive surrogate(Co, Cs) and radioactive materials($^{60}Co,\;^{137}Cs$). Through the Trial burn tests, Decontamination factor of spiked materials in off-gas treatment system is calculated.

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A Study on The Comparison of Leaching Methods and Stability of Cement Mortar Solidified Cadmium sludge (시멘트고화에 의한 카드뮴슬러지의 안정성 및 용출실험방법 비교 검토)

  • 주소영;김광렬
    • Journal of environmental and Sanitary engineering
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    • v.17 no.3
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    • pp.21-30
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    • 2002
  • This study was Performed to evaluate the effective solidification of Cd sludge using cement and power plant fly ash as cement admixture, to identify the leaching characteristics of the heavy metal Cd sludge solidified, and to develope proper KLT(Korean Leaching Test) of hazardous waste. KLT was compared with EPT(Extraction Procedure Toxicity) and TCLP(Toxicity Characteristics Leaching Procedure). Fly ash contents ranged from 0% to 30% of cement weight. The experimental results showed that the optimum amount of fly ash replaced was 10% to 15% and KLT was less appropriate than EPA and TCLP. Also the purpose of the study was to suggest the modification factors on the leaching test currently used, based on the above mentioned aspects. The effects of pH, leaching time, leaching for agitating intensity, and leaching solvent were investigated. As the result of test, the leaching potential was relatively high when the pH and agitation intensity of leaching solution were 5 and 150rpm, respectively. Leaching time of six hours was found to be sufficient and the use of acetic acid as a leaching solvent is more useful in landfill site particularly.

The Effects of Welding Process Parameters on Weld bead Width in GMAW Processes (GMAW 공정 중 용접 변수들이 용접 폭에 미치는 영향에 관한 연구)

  • 김일수;권욱현;박창언
    • Journal of Welding and Joining
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    • v.14 no.4
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    • pp.33-42
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    • 1996
  • In recent years there has been a significant growth in the use of the automated and/or robotic welding system, carried out as a means of improving productivity and quality, reducing product costs and removing the operator from tedious and potentially hazardous environments. One of the major difficulties with the automated and/or robotic welding process is the inherent lack of mathematical models for determination of suitable welding process parameters. Partial-penetration, single-pass bead-on-plate welds were fabricated in 12mm AS 1204 mild steel flats employing five different welding process parameters. The experimental results were used to develop three empirical equations: curvilinear; polynomial; and linear equations. The results were also employed to find the best mathematical equation under weld bend width to assist in the process control algorithms for the Gas Metal Arc Welding(GMAW) process and to correlate welding process parameters with weld bead width of bead-on-plates deposited. With the help of a standard statistical package program. SAS, multipe regression analysis was undertaken for investigating and modeling the GMAW process, and significance test techniques were applied for the interpretation of the experimental data.

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Design of Low-Melting Metal Fuse Elements of Current Sensing Type Protection Device for Large Capacity Secondary Battery Protection System (대용량 이차전지 보호 시스템용 전류 감지 동작형 보호소자의 저융점 금속 가용체 설계)

  • Kim, Eun Min;Kang, Chang yong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.31 no.6
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    • pp.427-432
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    • 2018
  • High-capacity secondary batteries can cause explosion hazards owing to microcurrent variations or current surges that occur in short circuits. Consequently, complete safety cannot be achieved with general protection that is limited to a mere current fuse. Hence, in the case of secondary batteries, it is necessary for the protector to limit the inrush current in a short circuit, and to detect the current during microcurrent variations. To serve this purpose, a fuse can be employed for the secondary battery protection circuit with current detection. This study aims at designing a protection device that can stably operate in the hazardous circumstances associated with high-capacity secondary batteries. To achieve the said objective, a detecting fuse was designed from an alloy of low melting point elements for securing stability in abnormal current states. Experimental results show that the operating I-T and V-T characteristic constraints can be satisfied by employing the proposed current detecting self-contained low melting point fuse, and through the resistance of the heating resistor. These results thus verify that the proposed protection device can prevent the hazards of short circuit current surges and microcurrent variations of secondary batteries.

Seismic protection of LNG tanks with reliability based optimally designed combined rubber isolator and friction damper

  • Khansefid, Ali;Maghsoudi-Barmi, Ali;Khaloo, Alireza
    • Earthquakes and Structures
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    • v.16 no.5
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    • pp.523-532
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    • 2019
  • Different types of gas reservoir such as Liquid Natural Gas (LNG) are among the strategic infrastructures, and have great importance for any government or their private owners. To keep the tank and its contents safe during earthquakes especially if the contents are of hazardous or flammable materials; using seismic protection systems such as base isolator can be considered as an effective solution. However, the major deficiency of this system can be the large deformation in the isolation level which may lead to the failure of bearing system. In this paper, as a solution, the efficacy of an optimally designed combined vibration control system, the combined laminated rubber isolator and rotational friction damper, is investigated to evaluate the enhancement of an existing metal tank response under both far- and near-field earthquakes. Responses like impulsive and convective accelerations, base shear, and sloshing height are studied herein. The probabilistic framework is used to consider the uncertainties in the structural modeling, as well as record-to-record variability. Due to the high calculation cost of probabilistic methods, a simplified structural model is used. By using the Mont-Carlo simulation approach, it is revealed that this combined isolation system is a highly reliable system which provides considerable enhancement in the performance of reservoir, not only leads to the reduction of probability of catastrophic failure of the tank but also decrease the reservoir damage during the earthquake. Moreover, the relative displacement of the isolation level is controlled very well by this combined system.