A Study on The Comparison of Leaching Methods and Stability of Cement Mortar Solidified Cadmium sludge

시멘트고화에 의한 카드뮴슬러지의 안정성 및 용출실험방법 비교 검토

  • Published : 2002.09.01

Abstract

This study was Performed to evaluate the effective solidification of Cd sludge using cement and power plant fly ash as cement admixture, to identify the leaching characteristics of the heavy metal Cd sludge solidified, and to develope proper KLT(Korean Leaching Test) of hazardous waste. KLT was compared with EPT(Extraction Procedure Toxicity) and TCLP(Toxicity Characteristics Leaching Procedure). Fly ash contents ranged from 0% to 30% of cement weight. The experimental results showed that the optimum amount of fly ash replaced was 10% to 15% and KLT was less appropriate than EPA and TCLP. Also the purpose of the study was to suggest the modification factors on the leaching test currently used, based on the above mentioned aspects. The effects of pH, leaching time, leaching for agitating intensity, and leaching solvent were investigated. As the result of test, the leaching potential was relatively high when the pH and agitation intensity of leaching solution were 5 and 150rpm, respectively. Leaching time of six hours was found to be sufficient and the use of acetic acid as a leaching solvent is more useful in landfill site particularly.

Keywords

References

  1. 동화기술 페기물처리 정재춘(외 9인)
  2. 환경관리공단 자료집 v.9 유해폐기물처리기술 환경관리공단
  3. J of KSEE v.17 no.10 Comparision of Waste Leaching Methods Soon-Haing Cho(et al.)
  4. J of KSEE v.18 no.2 Suggestion on the for Modification of Korean Learning Procedure for Determining Specical Waste Young-Soo Choi
  5. J. of Envir. Eng. v.120 no.6 Treatment of Metial Industrial Wastewater by Fly Ash and Cement Fixation C.H.Weng;C.P.Huang
  6. Cerm & Concr. Res. v.7 Hardening Property of Cement Mortaradding Heavy Metal Compounds amd Solubility and Heavy Metal from Hardenend Mortar C.Tashiro;H.Ztakahashi;N.Kanaya https://doi.org/10.1016/0008-8846(77)90090-4
  7. Environ. Sci. Technol. v.24 Immobilization Mechanisms in Solidification/Stabilization of Cd and Pb Salts Using Portland Cement Fixing Agents K.C.Frank;G.B.Lesile;C.Devi(etc.) https://doi.org/10.1021/es00076a012
  8. Purdue Ind. Waste Conf. Proc. v.221 Fixation Mechanisms in Solidification/Stabilizaion of Inorganic Hazardous Waste P.L.Bishop;S.B.Ransom;D.L.Gress
  9. J of KSee, v.19 no.7 A Studt on the Comparison of EP(EPA), Availability and KOEP Method Jung-Kwon Kim,(et.al)
  10. J of Korea Solid Wastes Engineering Society v.15 no.1 Learching Characteristics of Heavy Metals by Landfill of Soildified Sludge Dong-Jun Jeong(et al.)
  11. J of Korean Solid Wastes Engineering Society v.15 no.7 The Comparative Evaluationof Korean Leaching Test with TCLP Jun-Oh Jung,(et.al)
  12. Hazardous and Industrial Waste Management and Testing, 3nd sym. Application of a Dynamic Leaching Test to Solidified Hazardous Wastes P.L.Cote;D.Lsabel
  13. KS F 2403 콘크리트의 강도시험용 공시체를 제작 방법
  14. KS F 4004 콘크리트 벽돌
  15. 환경부고시 2000-4호 폐기물공정시험법
  16. Regulations for Identifying Hazardous Waste, Par 261 - Identification and Listing for Hazardous Waste EPA
  17. Standard Method for the Examination fo water and Wastewater(18th Edition)
  18. The Korean Journal of Sanitation v.16 no.1 The Characteristics of Compressive Strength and Leadchability on Solidfication of Chromium Tannery Sludge adding to Coal Fly Ash So-Young Ju(et al.)