• Title/Summary/Keyword: H2H

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Fe-H…H-C Dihydrogen Bondings: Synthesis and Structure of trans-[FeH(NCSe)(dppe)2](dppe=Ph2 PCH2 CH2 PPh2 (Fe-H…H-C 이수소 결합: trans-[FeH(NCSe)(dppe)2](dppe=Ph2 PCH2 CH2 PPh2의 합성 및 구조)

  • Baek, Ji Yeong;Han, Won Seok;Lee, Sun Won
    • Journal of the Korean Chemical Society
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    • v.46 no.5
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    • pp.427-436
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    • 2002
  • Reaction of $trans-[FeHCl(dppe)_2]$ (1) with KSeCN led to the formation of $trans-[FeH(NCSe)(dppe)_2](2).$ Compound 2 $·CH_2Cl_2$ was structurally characterized by X-ray diffraction, in which the hydride ligand appears to be involved in the dihydrogen bonding of the type M-H${\cdot}$${\cdot}$${\cdot}$H-C.

The characteristics of Al-doped ZnO films deposited with RF magnetron sputtering system in various H2/(Ar+H2) gas ratios

  • Kim, Jwayeon;Han, Jungsu;Park, Kyeongsoon
    • Journal of Ceramic Processing Research
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    • v.13 no.spc2
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    • pp.407-410
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    • 2012
  • The properties of Al-doped ZnO (AZO) films were investigated as a function of H2/(Ar + H2) gas ratio using an AZO (2 wt% Al2O3) ceramic target in a radio frequency (RF) magnetron sputtering system. The deposition process was done at 200 ℃ and in 2 × 10-2Torr working pressure and with various ratios of H2/(Ar + H2) gas. During the AZO film deposition process, partial H2 gas affected the AZO film characteristics. The electron resistivity (~ 9.21 × 10-4 Ωcm) was lowest and mobility (~17.8 ㎠/Vs) was highest in AZO films when the H2/(Ar + H2) gas ratio was 2.5%. When the H2/(Ar + H2) gas ratio was increased above 2.5%, the electron resistivity increased and mobility decreased with increasing H2/(Ar + H2) gas ratio in AZO films. The carrier concentration increased with increasing H2/(Ar + H2) gas ratio from 0% to 7.5%. This phenomenon was explained by reaction of hydrogen and oxygen and additional formation of oxygen vacancy. The average optical transmission in the visible light wavelength region over 90% and an orientation of the deposition was [002] orientation for AZO films grown with all H2/(Ar + H2) gas ratios.

The LMI mixed ${H_2}/H_{\infty}$ control of inverted pendulum system using LFR (도립진자 시스템의 LFR에 의한 LMI 혼합 ${H_2}/H_{\infty}$ 제어)

  • 박종우;이상철;이상효
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.25 no.7A
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    • pp.967-977
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    • 2000
  • In this paper, we apply a mixed $H_2/H_{\infty}$ control to a generalized plant of inverted pendulum system represented by an LFR(Linear Fractional Representation). First, in order to obtain the generalized plant, the linear model of the inverted pendulum represented by an LFR(Linear fractional Representation) is derived. In LFR, we consider system uncertainties as three nonlinear components and a pendulum mass uncertainty. Augmenting the LFR model by adding weighting functions, we get a generalized plant. And then, we design a mixed $H_2/H_{\infty}$ controller for the generalized plant. In order to design the mixed $H_2/H_{\infty}$ controller, we use the LMI technique. To evaluate control performances and robust stability of the mixed $H_2/H_{\infty}$ controller designed, we compare it with the $H_{\infty}$ controller through the simulation and experiment. In the result, with the fewer feedback information, the mixed $H_2/H_{\infty}$ controller shows the better control performances and robust stability than the $H_{\infty}$ controller in the sense of pendulum angle.

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Study of reaction mechanism in pre-reforming for MCFC (MCFC의 예비 개질 반응 메커니즘 연구)

  • Lee, Woo-Hyung;Park, Yong-Ki
    • Industry Promotion Research
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    • v.3 no.2
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    • pp.1-8
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    • 2018
  • In this study, the reaction mechanism of ethane and the reaction rate equation suitable for hydrocarbon reforming were studied. Through the reaction mechanism analysis, it was confirmed that three reactions (CO2 + H2, C2H6 + H2, C2H6 + H2O) proceed during the reforming reaction of ethane, each reaction rate (CO2+H2($r=3.42{\times}10-5molgcat.-1\;s-1$), C2H6+H2($r=3.18{\times}10-5mol\;gcat.-1s-1$), C2H6+H2O($r=1.84{\times}10-5mol\;gcat.-1s-1$)) was determined. It was confirmed that the C2H6 + H2O reaction was a rate determining step (RDS). And the reaction equation of this reaction can be expressed as r = kS * (KAKBPC2H6PH2O) / (1 + KAPC2H6 + KBPH2O) (KA = 2.052, KB = 6.384, $kS=0.189{\times}10-2$) through the Langmuir-Hinshelwood model. The obtained equation was compared with the derived power rate law without regard to the reaction mechanism and the power rate law was relatively similar fitting in the narrow concentration change region (about 2.5-4% of ethane, about 60-75% of water) It was confirmed that the LH model reaction equation based on the reaction mechanism shows a similar value to the experimental value in the wide concentration change region.

Fuzzy H2/H Controller Design for Delayed Nonlinear Systems with Saturating Input (포화입력을 가지는 시간지연 비선형 시스템의 퍼지 H2/H 제어기 설계)

  • Cho, Hee-Soo;Lee, Kap-Rai;Park, Hong-Bae
    • Journal of the Korean Institute of Intelligent Systems
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    • v.12 no.3
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    • pp.239-245
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    • 2002
  • In this Paper, we present a method for designing fuzzy $H_2/H_{\infty}$ controllers of delayed nonlinear systems with saturating input. Takagi-Sugeno fuzzy model is employed to represent delayed nonlinear systems with saturating input. The fuzzy control systems utilize the concept of the so-called parallel distributed compensation(PDC). Using a single quadratic Lyapunov function, the globally exponential stability and $H_2/H_{\infty}$ performance problem are discussed. And a sufficient condition for the existence of fuzzy $H_2/H_{\infty}$ controllers is given in terms of linear matrix inequalities(LMIs). The designing fuzzy $H_2/H_{\infty}$ controllers minimize an upper bound on a linear quadratic performance measure. Finally, a design example of fuzzy $H_2/H_{\infty}$ controller for uncertain delayed nonlinear systems with saturating input.

Putative Histone H2A Genes from a Red Alga, Griffithsia japonica

  • Lee, Yoo-Kyung;Lee, Hong-Kum
    • ALGAE
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    • v.18 no.3
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    • pp.191-197
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    • 2003
  • Histones are important proteins that interact with the DNA double helix to form nucleosome. Two putative histone genes, GjH2A-1 and GjH2A-2 were isolated from a red alga Griffithsia japonica. The putative open reading frame of GjH2A-1 and GjH2A-2 shared high similarity with the previously reported amino acid sequences of histone H2As. They have a motif consisting of seven amino acids A-G-L-Q-F-P-V, which matches the histone H2A motif [AC]-G-L-x-F-P-V. Phylogenetic trees were constructed from amino acid sequences of 38 histone H2As. The histone H2As were divided into two groups: major H2As and H2A.F/Z variants. The major histone H2A group consisted of animals, fungi, plants + green algae, and red algae H2A subgroups. The animal histone H2A subgroup was divided into vertebrates, echinoderms, nematodes, insects, and segmented worms H2As. The putative red algal histone genes, GjH2A-1 and GjH2A-2, constituted an independent lineage. This is the first report on red algal histone genes.

Synthesis and Structures of $(NH_4)_{10}[Ni(H_2O)_5]_4[V_2P_2BO_{12}]_6{\cdot}nH_2O$ and $(NH_4)_{3.5}(C_3H_{12}N_2)_{3.5}[Ni(H_2O)_6]_{1.25}{[Ni(H_2O)_5]_2[V_2P_2BO_{12}]_6{\cdot}nH_2O$

  • Yun, Ho-Seop;Do, Jung-Hwan
    • Korean Journal of Crystallography
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    • v.15 no.1
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    • pp.35-39
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    • 2004
  • Two new nickel vanadium borophosphate cluster compounds, $(NH_4)_{10}[Ni(H_2O)_5]_4[V_2P_2BO_{12}]_6{\cdot}nH_2O$ (1) and $(NH_4)_{3.5}(C_3H_{12}N_2)_{3.5}[Ni(H_2O)_6]_{1.25}{[Ni(H_2O)_5]_2[V_2P_2BO_{12}]_6{\cdot}nH_2O$ (2) have been synthesized and structurally characterized. Inter-diffusion methods were employed to prepare the compounds. The cluster anion $[(NH_4)\;{\supset}\;V_2P_2BO_{12}]_6$ is used as a building unit in the synthesis of new compounds containing $Ni(H_2O){^{2+}_5}$ in the presence of pyrazine and 1,3-diaminopropane. Compounds contain isolated cluster anions with general composition ${[Ni(H_2O)_5]_n[(NH_4)\;{\supset}\;V_2P_2BO_{12}]_6}^{-(17-2n)}$ (n = 2, 4). Crystal data: $(NH_4)_{10}[Ni(H_2O)_5]_4[V_2P_2BO_{12}]_6{\cdot}nH_2O$, monoclinic, space group C2/m (no. 12), a = 27.538(2) ${\AA}$, b = 20.366(2) ${\AA}$, c = 11.9614(9) ${\AA}$, ${\beta}$ = 112.131(1)$^{\circ}$, Z = 8; $(NH_4)_{3.5}(C_3H_{12}N_2)_b[Ni(H_2O)_6]_{3.5}{[Ni(H_2O)_5]_2[V_2P_2BO_{12}]_6{\cdot}nH_2O$, triclinic, space group P-1 (no. 2), a = 17.7668(9) ${\AA}$, b = 17.881(1) ${\AA}$, c = 20.668(1) ${\AA}$, ${\alpha}$ = 86.729(1)$^{\circ}$, ${\beta}$ \ 65.77(1)$^{\circ}$, ${\gamma}$ = 80.388(1)$^{\circ}$, Z = 2.

$H_{2}$/$H_{\infty}$ control of active suspension system (능동 현가 시스템을 위한 $H_{2}$/$H_{\infty}$ 제어기 설계)

  • 정우영;김상우;원상철
    • 제어로봇시스템학회:학술대회논문집
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    • 1996.10b
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    • pp.888-891
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    • 1996
  • The objective of a mixed H$_{2}$/H$_{\infty}$ controller of active suspension system is to achieve not only the general performance improvement(H$_{2}$) but also the worst case disturbance rejection(H$_{\infty}$). In this paper, a mixed H$_{2}$/H$_{\infty}$ controller for an active suspension system, comparing the performance with that of an H$_{2}$ controller and of an H$_{\infty}$ controller.ler.EX> controller.

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Mixed $H_2/H_{\infty}$ Controller Realization with Entropy Integral

  • Lee, Sang-Hyuk;Kim, Ju-Sik
    • International Journal of Control, Automation, and Systems
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    • v.1 no.2
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    • pp.206-209
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    • 2003
  • An $H_2$/$H_{\infty}$ -controller realization is carried out by considering an entropy integral. Using J-spectral factorization, the parametrizations of all $H_{\infty}$ stabilizing controllers are derived. By the relation of a mixed $H_2$/$H_{\infty}$ control problem and a minimum entropy/$H_{\infty}$ control problem, the mixed $H_2$/$H_{\infty}$-controller state-space realization is presented.

Destruction of Acetic Acid Using Various Combinations of Oxidants by an Advanced Oxidation Processes (다양한 산화반응을 조합한 고급산화공정의 아세트산 분해에 관한 연구)

  • Kwon, Tae Ouk;Park, Bo Bae;Moon, Jang Soo;Moon, Il Shik
    • Applied Chemistry for Engineering
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    • v.18 no.4
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    • pp.314-319
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    • 2007
  • The destruction of synthetic acetic acid wastewater was carried out using UV, $O_3$, $H_2O_2$, $Fe^{2+}$ oxidants in various combinations by the advanced oxidation processes. $UV/H_2O_2$, $UV/H_2O_2/Fe^{2+}$, $O_3$, $O_3/H_2O_2$, $UV/O_3/H_2O_2$, $UV/O_3/H_2O_2/Fe^{2+}$ processes were tested. $UV/H_2O_2/Fe^{2+}$, $O_3/H_2O_2$, $UV/O_3/H_2O_2$, $UV/O_3/H_2O_2/Fe^{2+}$ processes shows the most effective destruction efficiency at low pH (3.5) condition of wastewater, but $UV/H_2O_2$ and $O_3$ processes were observed less than 20%. Destruction efficiency was gradually increased with the reaction time in the $O_3/H_2O_2$ and $UV/O_3/H_2O_2$ processes, in case of the $UV/H_2O_2/Fe^{2+}$ and $UV/O_3/H_2O_2/Fe^{2+}$ processes shows rapid increasing of destruction efficiency within 90 min, then slightly decreasing with time. The destruction efficiencies of $UV/H_2O_2/Fe^{2+}$, $O_3/H_2O_2$, $UV/O_3/H_2O_2$ and $UV/O_3/H_2O_2/Fe^{2+}$ processes were observed 55, 66, 66 and 64%, respectively.