Journal of the Korean Chemical Society (대한화학회지)

Korean Chemical Society (대한화학회)
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Fe-H…H-C Dihydrogen Bondings: Synthesis and Structure of trans-[FeH(NCSe)(dppe)2](dppe=Ph2 PCH2 CH2 PPh2

Fe-H…H-C 이수소 결합: trans-[FeH(NCSe)(dppe)2](dppe=Ph2 PCH2 CH2 PPh2의 합성 및 구조

  • Baek, Ji Yeong (Department of Chemistry (BK21), Sungkyunkwan University) ;
  • Han, Won Seok (Department of Chemistry (BK21), Sungkyunkwan University) ;
  • Lee, Sun Won (Department of Chemistry (BK21), Sungkyunkwan University)
  • Published : 2002.10.20
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Abstract

Reaction of $trans-[FeHCl(dppe)_2]$ (1) with KSeCN led to the formation of $trans-[FeH(NCSe)(dppe)_2](2).$ Compound 2 $·CH_2Cl_2$ was structurally characterized by X-ray diffraction, in which the hydride ligand appears to be involved in the dihydrogen bonding of the type M-H${\cdot}$${\cdot}$${\cdot}$H-C.

trans-[FeHCl$(dppe)_2$](1)과 KSeCN의 반응으로부터 trans-[FeH(NCSe)$(dppe)_2$](2)가 합성되었다. 화합물 2-$CH_2Cl_2$의 구조가 X-ray회절법으로 규명되었다. 화합물 2 내에서 수소 리간드가 M-H${\cdots}$H-C유형의 이수소 (dihydro gen) 결합에 참여하고 있다.

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