• Title/Summary/Keyword: trans-[FeH(NCSe)$(dppe)_{2}$

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Fe-H…H-C Dihydrogen Bondings: Synthesis and Structure of trans-[FeH(NCSe)(dppe)2](dppe=Ph2 PCH2 CH2 PPh2 (Fe-H…H-C 이수소 결합: trans-[FeH(NCSe)(dppe)2](dppe=Ph2 PCH2 CH2 PPh2의 합성 및 구조)

  • Baek, Ji Yeong;Han, Won Seok;Lee, Sun Won
    • Journal of the Korean Chemical Society
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    • v.46 no.5
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    • pp.427-436
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    • 2002

  • Reaction of $trans-[FeHCl(dppe)_2]$ (1) with KSeCN led to the formation of $trans-[FeH(NCSe)(dppe)_2](2).$ Compound 2 $·CH_2Cl_2$ was structurally characterized by X-ray diffraction, in which the hydride ligand appears to be involved in the dihydrogen bonding of the type M-H${\cdot}$${\cdot}$${\cdot}$H-C.

  • https://doi.org/10.5012/jkcs.2002.46.5.427 인용 PDF KSCI