• 대한화학회지
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• 제54권1호
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• pp.23-26
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• 2010

Schiff 리간드인 (Z)-N-((Z)-2-(sec-butylimino)-1,2-diphenylethylidene)butan-2-amine을 벤질과 sec-부틸아민과의 축합반응에 의해 합성하였다. 일 주기 전이금속인 망간(II) 및 니켈(II)과 리간드와의 착물반응을 시도하였다. 리간드 및 착물의 특성을 FTIR, 원소분석 및 열무게분석으로 고체 상태에서, 그리고 NMR ($^1H,\;^{13}C$)로 용액 상태에서의 각각 조사하였다. 두 착물 모두 온화한 조건에서 methylaluminoxane (MAO) 존재 하에 부타디엔 올리고화 반응의 조촉매로 좋은 촉매활성을 보였다.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2002년도 하계학술대회 논문집 Vol.3 No.2
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• pp.597-600
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• 2002

Electrical properties of $\{(Sr_xCa_{1-x})_{0.95-y-z}Bi_2Pb_{0.05+y}\})Ti_{1.02}O_3$ ceramic were studied as a function of Sr/Ca ratio and Bi, Pb contents. Dielectric properties of specimens with different x, y, z values were explained in terms of ionic polarizability with Molecular Additionally Rules and Clausius-Mosotti equation. For the composition of $\{(Sr_{0.62}Ca_{0.38})_{0.90}Bi_{0.01}Pb_{0.09}\})Ti_{1.02}O_3$ and $\{(Sr_{0.62}Ca_{0.38})_{0.905}Bi_{0.015}Pb_{0.08}\})Ti_{1.02}O_3$, dielectric constant$({\varepsilon}_r)$, quality factor(Q) and temperature coefficient(TC) were 389, 3048, -1490 and 394, 1869, -1340 at 1MHz, respectively.

• 약학회지
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• 제46권5호
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• pp.313-319
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• 2002

Synthesis of 7$\beta$-[(Z)-2-(2-aminothiazol-4-yl)-2-(1-carboxy-1-methylethoxyimino)acetamido]-3-[[(3S, 5S)-5-[4-phenyl-5-(4-methylphenyl or 2-thiophenyl)-4H-l, 2, 4- triazol-3-yl]thiomethylpyrrolidin-3-yl]]thiomethyl-3-cephem-4-carboxylic acids (7a, 7b) were described. (2S, 4S)-4-acethylthio-2-[4-phenyl-5-(4-methylphenyl or 2-thiophenyl)-4 H-1, 2, 4-triazol-3-yl]thiomethyl-1-tert-butoxycarbonylpyrrolidines (4a, 4b) were prepared from trans-4-hydroxy-L-proline with (2S, 4R)-absolute configuration as starting material. 4-Phenyl-5-(4-methylphenyl or 2-thiophenyl)-4 H-l, 2, 4-triazol-3-thiols (2a, 2b) were prepared from p-toluic anhydride and 2-thiophene carboxylic acid hydrazide, respectively. p-Methoxybenzyl 7$\beta$-(Z)-2-(2-for-mamidothiazol-4-yl)-2-(1-tert-butoxycarbonylisopropylimino]acetamido-3-[[ (3S, 5S)-5-[4-phenyl-5-(4-methylphenyl or 2-thio phenyl)-4H-1, 2, 3-triazol-3-yl]thiomethyl-1- tert-butoxycarbonylpyrrolidin-3-yl]]thiomethyl-3-cephem-4-carboxylates (6a, 6b) were achieved by using p-methoxybenzyl ]7P-(Z)-2-(2-formamidothiazol-4-yl)-2-(tert-butoxycarbonylisopropylimino] acetamido-3-chloromethyl-3-cephem-4-carboxylate (5) and (2S, 4S)-4-acethylthio-2-[4-phenyl-5-(4-methyl phenyl or 2-thiophenyl)-4H-1, 2, 4-triazol-3-yl]thiomethyl-1-tert-butoxycarbonyl pyrrolidines (4a, 4b). Removal of formyl, Boc, and p-methoxybenzyl protecting groups were carried out by triflu oroacetic acid and anisole to give the target compounds.

• Journal of Microbiology and Biotechnology
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• 제23권11호
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• pp.1560-1568
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• 2013

Salmonella, a main cause of foodborne diseases, encounters a variety of environmental stresses and overcomes the stresses by multiple resistance strategies. One of the general responses to hyperosmotic stress is to import or produce compatible solutes so that cells maintain fluid balance and protect proteins and lipids from denaturation. The ProP and ProU systems are the main transport systems for compatible solutes. The OsmU system, recently identified as a third osmoprotectant transport system, debilitates excessive growth as well by reducing production of trehalose. We studied a fourth putative osmoprotectant transport system, YehZYXW, with high sequence similarity with the OsmU system. A Salmonella strain lacking YehZ, a predicted substrate-binding protein, did not suffer from hyperosmolarity but rather grew more rapidly than the wild type regardless of glycine betaine, an osmoprotectant, suggesting that the YehZYXW system controls bacterial growth irrespective of transporting glycine betaine. However, the growth advantage of ${\Delta}yehZ$ was not attributable to an increase in OtsBA-mediated trehalose production, which is responsible for the outcompetition of the ${\Delta}osmU$ strain. Overexpressed YehZ in trans was capable of deaccelerating bacterial growth vice versa, supporting a role of YehZ in dampening growth. The expression of yehZ was increased in response to nutrient starvation, acidic pH, and the presence of glycine betaine under hyperosmotic stress. Identifying substrates for YehZ will help decipher the role of the YehZYXW system in regulating bacterial growth in response to environmental cues.

• 센서학회지
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• 제6권3호
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• pp.200-206
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• 1997

열산화시킨 실리콘 웨이퍼 위에 저압화학기상성장법으로 $SiCl_{2}H_{2}$, $NH_{3}$ 및 $N_{2}O$ 기체를 사용하여 실리콘 옥시나이트라이드($Si_{x}O_{y}N_{z}$) 층을 제작하였다. 세 가지의 다른 조성이 기체 유속비($NH_{3}/N_{2}O$)를 각기 0.2, 0.5 및 2로 변화시키고 $SiCl_{2}H_{2}$의 기체 유속은 고정시킴으로써 얻어졌다. 엘립소메트리와 HFCV(High Frequency Capacitance-Voltage) 측정법을 채택하여 굴절율, 유전율 및 조성의 차이를 각각 조사했다. 실리콘 옥시나이트라이드는 내부에 포함된 실리콘 나이트라이드 성분량에 관계없이 용액 중에서 순수한 실리콘 나이트라이드와 유사한 안정성을 보유했다. 실리콘 옥시나이트라이드 층 알칼리이온 감지성의 크기 순서는 실리콘 나이트라이드 성분량에 영향을 받았다. 보다 나은 알칼리이온 감지성이 실리콘 옥시나이트라이드의 벌크 내에 있는 실리콘 디옥시드의 성분량을 증가시킴으로써 얻어졌다.

• 전자공학회논문지C
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• 제36C권1호
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• pp.49-58
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• 1999

본 논문에서는 통과 대역폭이 5KHZ, ripple이 0.1dB이하인 스위치드 캐패시터(Switched Capacitor) 필터를 $0.8{\mu}m$ single poly CMOS ASIC 표준 공정을 이용하여 집적화된 단일 칩으로 제작하였다. 제안된 5차 타원 저역 통과 필털의 구성은 MOS 스위치와 poly 캐패시터, 5개의 2단 CMOS op-amp로 구성하였다. 필터구현은 LC 수동형으로부터 연속전달함수 H(s)를 구하고 쌍선형 z변환을 통하여 이산전달함수 H(z)으로 바꾸어 2차 바이쿼드(biquad)를 종속 연결하는 빌딩블록 방식을 택하였다. 또한 op-amp의 구동범위를 고려하면서 캐패시터 면적을 감소시킨 스케일링 실시한 동일 특성의 필터를 제작하여 그 특성 변화를 비교, 분석하였다. 측정결과 ${\pm}2.5V$ 전원, 50KHz의 표본 주파수에서 2종의 필터 모두 4.96~4.98KHz의 통과 대역폭에 0.7~0.81dB의 리플, 35~38dB정도의 저지대역 이득감쇠 특성을 보였다.

• 대기
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• 제29권2호
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• pp.197-211
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• 2019

The observational sensitivity of dual-polarization weather radar was quantitatively analyzed by using two different pulse widths. For this purpose, test radar scan strategy which consisted of consecutive radar scan using long (LP: $2{\mu}s$) and short (SP: $1{\mu}s$) pulses at the same elevation angle was employed. The test scan strategy was conducted at three operational S-band dual-polarization radars (KSN, JNI, and GSN) of Korea Meteorological Administration (KMA). First, the minimum detectable reflectivity (MDR) was analyzed as a function of range using large data set of reflectivity ($Z_H$) obtained from JNI and GSN radars. The MDR of LP was as much as 7~22 dB smaller than that of SP. The LP could measure $Z_H$ greater than 0 dBZ within the maximum observational range of 240 km. Secondly, polarimetric observations and the spatial extent of radar echo between two pulses were compared. The cross-polar correlation coefficient (${\rho}_{hv}$) from LP was greater than that from SP at weak reflectivity (0~20 dBZ). The ratio of $Z_H$ (> 0 dBZ) and ${\rho}_{hv}$(> 0.95) bin to total bin calculated from LP were greater than those from SP (maximum 7.1% and 13.2%). Thirdly, the frequency of $Z_H$ (FOR) during three precipitation events was analyzed. The FOR of LP was greater than that of SP, and the difference in FOR between them increased with increasing range. We conclude that the use of LP can enhance the sensitivity of polarimetric observations and is more suitable for detecting weak echoes.

• Computers and Concrete
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• 제34권1호
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• pp.33-48
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• 2024

This paper presents the detailed experimental and analytical investigation on the evolution of static (E_s) and dynamic modulus of elasticity (E_d) of concrete having 0%, 35%, and 50% FA used as partial cement replacement. Destructive and non-destructive tests were conducted on cylindrical specimens to evaluate the compressive strength and MoE of concrete in compression at the age of 28, 56, 90, and 150 days for all mixes. Experimental results show that the concrete having 35% FA achieved compressive strength and MoE similar to plain concrete at the age of 90 days, while 50% FA concrete attained satisfactory compressive strength and MoE at the age of 150 days. The comprehensive statistical analysis has been carried out in two ways on the basis of the experimental results. Firstly, the 28-day crushing strength of plain concrete in compression was used to design the models for the prediction of E_s and E_d of fly ash concrete at any age and percentage replacement of FA. Secondly, using the values of UPV and RHN, models have been developed to predict the age or time-dependent E_s and E_d of fly ash concrete. These models will be helpful in assessing the E_s and E_d of fly ash concrete without knowing the 28-day crushing strength of plain concrete in compression in the laboratory. Hence, the suggested models in the present study will be beneficial in conducting the health assessment of fly ash based concrete structures.

• 대한수학회보
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• 제50권4호
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• pp.1193-1200
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• 2013

The center of the Lie group $SU(n)$ is isomorphic to $\mathbb{Z}_n$. If $d$ divides $n$, the quotient $SU(n)/\mathbb{Z}_d$ is also a Lie group. Such groups are locally isomorphic, and their Weyl groups $W(SU(n)/\mathbb{Z}_d)$ are the symmetric group ${\sum}_n$. However, the integral representations of the Weyl groups are not equivalent. Under the mod $p$ reductions, we consider the structure of invariant rings $H^*(BT^{n-1};\mathbb{F}_p)^W$ for $W=W(SU(n)/\mathbb{Z}_d)$. Particularly, we ask if each of them is a polynomial ring. Our results show some polynomial and non-polynomial cases.

• Progress in Superconductivity
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• 제10권2호
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• pp.128-132
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• 2009

Polycrystalline samples of $(Ru_{0.8}Nb_{0.2})Sr_2(Gd_{1.5-x}Nd_xCe_{0.5})Cu_2O_z$($ 0{\leq}x{\leq}1.25$) have been synthesized by a solid-state reaction route. The X-ray diffraction data revealed that the Nd solubility limit can be placed between x=0.5 and x=0.75. The superconducting transition temperature decreased with increasing Nd content, confirming that Nd entered the lattice. Room-temperature thermoelectric power measurements showed that all the samples are in the underdoped state and the partial substitution of Nd for Gd resulted in a decrease in the carrier density on the superconducting layers.