• Title/Summary/Keyword: Green emission

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Eu3+/Tb3+Co-Doped Cerium Oxide Transparent Nanocomposite for Color-Tunable Emission

  • Li, Xiaoyan;Yu, Yunlong;Guan, Xiangfeng;Luo, Peihui;Jiang, Linqin;Zheng, Zhiqiang;Chen, Dagui
    • Nano
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    • v.13 no.10
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    • pp.1850119.1-1850119.6
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    • 2018
  • $Eu^{3+}/Tb^{3+}$ co-doped nanocomposite containing $CeO_2$ nanocrystals was successfully prepared by an in situ sol-gel polymerization approach. High-resolution transmission electron microscopy demonstrated the homogeneous precipitation of $CeO_2$ nanocrystals among the polymethylmethacrylate (PMMA) matrix. The thermal stability and UV-shielding capability of the obtained nanocomposite were improved with increase of $CeO_2$ content. The tuning of the emissive color from green and yellow to red can be easily achieved by varying the dopant species and concentration. These results suggested that the obtained nanocomposite could be potentially applicable in transparent solid-state luminescent devices.

Advanced estimation and mitigation strategies: a cumulative approach to enteric methane abatement from ruminants

  • Islam, Mahfuzul;Lee, Sang-Suk
    • Journal of Animal Science and Technology
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    • v.61 no.3
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    • pp.122-137
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    • 2019
  • Methane, one of the important greenhouse gas, has a higher global warming potential than that of carbon dioxide. Agriculture, especially livestock, is considered as the biggest sector in producing anthropogenic methane. Among livestock, ruminants are the highest emitters of enteric methane. Methanogenesis, a continuous process in the rumen, carried out by archaea either with a hydrogenotrophic pathway that converts hydrogen and carbon dioxide to methane or with methylotrophic pathway, which the substrate for methanogenesis is methyl groups. For accurate estimation of methane from ruminants, three methods have been successfully used in various experiments under different environmental conditions such as respiration chamber, sulfur hexafluoride tracer technique, and the automated head-chamber or GreenFeed system. Methane production and emission from ruminants are increasing day by day with an increase of ruminants which help to meet up the nutrient demands of the increasing human population throughout the world. Several mitigation strategies have been taken separately for methane abatement from ruminant productions such as animal intervention, diet selection, dietary feed additives, probiotics, defaunation, supplementation of fats, oils, organic acids, plant secondary metabolites, etc. However, sustainable mitigation strategies are not established yet. A cumulative approach of accurate enteric methane measurement and existing mitigation strategies with more focusing on the biological reduction of methane emission by direct-fed microbials could be the sustainable methane mitigation approaches.

Carbonaceous Aerosols Generated from Wood Charcoal Production Plants in the South Korea Context

  • Magnone, Edoardo;Park, Seong-Kyu;Park, Jung Hoon
    • Journal of the Korean Wood Science and Technology
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    • v.47 no.3
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    • pp.277-289
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    • 2019
  • Herein, a case study discussing the effect of carbonaceous aerosol pollution, which is emitted during the charcoal kiln manufacturing processes or carbonization processes, on the atmospheric environment is presented . In South Korea, in situ analysis of different charcoal production plants specialized in the production of charcoal sauna indicate that the emitted organic carbon (OC) and elemental carbon (EC) aerosols are significantly influenced by the nature of the biomass and technological processes, i.e., treatment or emissions abatement systems for the exhaust effluent gases. In detail, total carbon (TC), which is calculated as the sum of OC and EC emission factors, varied widely from a charcoal production site to another ranging from 21.8 to 35.8 gTC/kg-oak, where the mean value for the considered production sites was approximately 28 gTC/kg-oak (N = 7 and sum = 196.4). Results indicate that the emission factors from a modern charcoal production process in South Korea are quantitatively lower in comparison with the traditional kiln. This study aims to propose advanced wood processes for the production of charcoal from the viewpoint of environmental protection policy and green engineering.

Estimate and Environmental Assessment of Greenhouse Gas(GHG) Emissions and Sludge Emissions in Wastewater Treatment Processes for Climate Change (기후변화를 고려한 하수처리공법별 온실가스 및 슬러지 배출량 산정 및 환경성 평가)

  • Oh, Tae-Seok;Kim, Min-Jeong;Lim, Jung-Jin;Kim, Yong-Su;Yoo, Chang-Kyoo
    • Korean Chemical Engineering Research
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    • v.49 no.2
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    • pp.187-194
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    • 2011
  • In compliance with an international law about the ocean dumping of the sludge, the proper sewage treatment process which occurs from the wastewater treatment process has been becoming problem. Generally the sewage and the sludge are controlled from anaerobic condition when the sewage is treated and land filled, where the methane$(CH_{4})$ and the nitrous oxide $(N_{2}O)$ from this process are discharged. Because these gases have been known as one of the responsible gases for global warming, the wastewater treatment process is become known as emission sources of green house gases(GHG). This study is to suggest a new approach of estimate and environmental assessment of greenhouse gas emissions and sludge emissions from wastewater treatment processes. It was carried out by calculating the total amounts of GHG emitted from biological wastewater treatment process and the amount of the sludgegenerated from the processes. Four major biological wastewater treatment processes which are Anaerobic/Anoxic/Oxidation$(A_{2}O)$, Bardenpho, Virginia Initiative Plant(VIP), University of Cape Town(UCT)are used and GPS-X software is used to model four processes. Based on the modeling result of four processes, the amounts of GHG emissions and the sludge produced from each process are calculated by Intergovernmental Panel on Climate Change(IPCC) 2006 guideline report. GHG emissions for water as well as sludge treatment processes are calculated for environmental assessment has been done on the scenario of various sludge treatments, such as composting, incineration and reclamation and each scenario is compared by using a unified index of the economic and environmental assessment. It was found that Bardenpho process among these processes shows a best process that can emit minimum amount of GHG with lowest impact on environment and composting emits the minimum amount of GHG for sludge treatment.

Analysis on the Correction Factor of Emission Factors and Verification for Fuel Consumption Differences by Road Types and Time Using Real Driving Data (실 주행 자료를 이용한 도로유형·시간대별 연료소모량 차이 검증 및 배출계수 보정 지표 분석)

  • LEE, Kyu Jin;CHOI, Keechoo
    • Journal of Korean Society of Transportation
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    • v.33 no.5
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    • pp.449-460
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    • 2015
  • The reliability of air quality evaluation results for green transportation could be improved by applying correct emission factors. Unlike previous studies, which estimated emission factors that focused on vehicles in laboratory experiments, this study investigates emission factors according to road types and time using real driving data. The real driving data was collected using a Portable Activity Monitoring System (PAMS) according to road types and time, which it compared and analyzed fuel consumption from collected data. The result of the study shows that fuel consumption on national highway is 17.33% higher than the fuel consumption on expressway. In addition, the average fuel consumption of peak time is 4.7% higher than that of non-peak time for 22.5km/h. The difference in fuel consumption for road types and time is verified using ANOCOVA and MANOVA. As a result, the hypothesis of this study - that fuel consumption differs according to road types and time, even if the travel speed is the same - has proved valid. It also suggests correction factor of emission factors by using the difference in fuel consumption. It is highly expected that this study can improve the reliability of emissions from mobile pollution sources.

Synthesis and Properties of SrMoO4 Phosphors Doped with Various Rare Earth Ions for Anti-Counterfeiting Applications (위조 방지 분야에 응용 가능한 다양한 희토류 이온이 도핑된 SrMoO4 형광체의 제조 및 특성)

  • Moon, Tae-Ok;Jung, Jae-Yong;Cho, Shinho
    • Korean Journal of Materials Research
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    • v.30 no.8
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    • pp.406-412
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    • 2020
  • SrMoO4:RE3+ (RE=Dy, Sm, Tb, Eu, Dy/Sm) phosphors are prepared by co-precipitation method. The effects of the type and the molar ratio of activator ions on the structural, morphological, and optical properties of the phosphor particles are investigated. X-ray diffraction data reveal that all the phosphors have a tetragonal system with a main (112) diffraction peak. The emission spectra of the SrMoO4 phosphors doped with several activator ions indicate different multicolor emissions: strong yellow-emitting light at 573 nm for Dy3+, red light at 643 nm for Sm3+, green light at 545 nm for Tb3+, and reddish orange light at 614 nm for Eu3+ activator ions. The Dy3+ singly-doped SrMoO4 phosphor shows two dominant emission peaks at 479 and 573 nm corresponding to the 4F9/26H15/2 magnetic dipole transition and 4F9/26H13/2 electric dipole transition, respectively. For Dy3+ and Sm3+ doubly-doped SrMoO4 phosphors, two kinds of emission peaks are observed. The two emission peaks at 479 and 573 nm are attributed to 4F9/26H15/2 and 4F9/26H13/2 transitions of Dy3+ and two emission bands centered at 599 and 643 nm are ascribed to 4G5/26H7/2 and 4G5/26H9/2 transitions of Sm3+. As the concentration of Sm3+ increases from 1 to 5 mol%, the intensities of the emission bands of Dy3+ gradually decrease; those of Sm3+ slowly increase and reach maxima at 5 mol% of Sm3+ ions, and then rapidly decrease with increasing molar ratio of Sm3+ ions due to the concentration quenching effect. Fluorescent security inks based on as-prepared phosphors are synthesized and designed to demonstrate an anti-counterfeiting application.

A Study for Construction of CO2 Inventory Using GIS (지리정보시스템을 활용한 CO2 인벤토리 구축 방안에 관한 연구)

  • Oh, Sang-Hak;Kim, Dae-Wuk;Ryu, Ji-Won;Cha, Jae-Gyu;Jung, Eung-Ho
    • Journal of the Korean Association of Geographic Information Studies
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    • v.14 no.2
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    • pp.40-52
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    • 2011
  • In this study, $CO_2$ emission quantities by spatial characteristics using GIS were investigated for building a $CO_2$ emission inventory. Eventually, this study provides the guidelines to build the urban spatial structure for reducing greenhouse gas and contributes to the transition to environmental friendly green city. The attribute data for GIS were energy (electricity and gas) usage in the city of Daegu for 2009 and used for Tier 1 as suggested by the IPCC guideline to estimate amount of $CO_2$ emission. The spatial data were built based on land use types categorized by building purposes with connecting building registers to cadastral maps for Daegu city. Spatial $CO_2$ emission quantities could be calculated by combining $CO_2$ emission inventory for energy and GIS. Also, $CO_2$ emission characteristics were different by land use types.

Estimation of Greenhouse Gas Reduction Potential by Treatment Methods of Excavated Wastes from a Closed Landfill Site (사용종료매립지(使用終了埋立地) 폐기물(廢棄物)의 처리방법별(處理方法別) 온실(溫室)가스 저감량(低減量) 평가(評價))

  • Lee, Byung-Sun;Han, Sang-Kuk;Kang, Jeong-Hee;Lee, Nam-Hoon
    • Resources Recycling
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    • v.22 no.6
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    • pp.3-11
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    • 2013
  • This study was carried out to estimate greenhouse gas reduction potentials under treatment methods of combustible wastes excavated from closed landfill. The treatment methods of solid wastes were landfilling, incineration, and production of solid recovery fuel. The greenhouse gas reduction potentials were calculated using the default emission factor presented by IPCC G/L method of IPCC (Intergovernmental Panel on Climate Change). The composition of excavated waste represented that screened soil was the highest (65.96%), followed by vinyl/plastic (19.18%). This means its own component is similar to the other excavated waste from unsanitary landfill sites. Additionally, its bulk density was 0.74 $t/m^3$. In case of landfilling of excavated waste, greenhouse gas emission quantity was 60,542 $tCO_2$. In case of incineration of excavated waste, greenhouse gas emission quantity was 9,933 $tCO_2$. However, solid recovery fuel from excavated waste reduced 33,738 $tCO_2$ of the greenhouse gas emission quantity. Therefore, solid recovery fuel production is helpful to reduce of greenhouse gas emission.

Expressway Greenhouse Gas Reduction Effect Analysis According to the Electric Vehicle Supply (전기차 보급전망에 따른 고속도로 온실가스 저감효과 분석)

  • Lee, Jin Kak;Han, Dong Hee;Oh, Chang Kwon;Jung, Chul Ki;Oh, Kwan Kyo
    • Journal of Korean Society of Transportation
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    • v.31 no.5
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    • pp.37-47
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    • 2013
  • This Study analyzed the electric car effect on the Korea Expressway System in terms of year 2020 $CO_2$ emission. The analysis was based on the green car dissemination goal by the government and year 2010 emission statistics. Major contents performed in the study area were as follows. First, the greenhouse gases emitted from the highways were found to be approximately 17.3 million tons of $CO_2$ as of 2010. Analysis showed the emission would be 17.4 million tons in 2015 and 16.2 million tons in 2020. The results in the pattern reflect the effect of O/D on the KTBD and the trend of traffic increase from 2015 to 2020 followed by decrease in 2020. Second, in the case of greenhouse gas emission with the anticipated supply of electric cars, the amount of emission in 2015 will be 17.1 million tons, which is about 2.0% reduction compared to the lack of introduction of electric cars. The analysis also showed that in 2020, the amount of emission will be 14.2 million tons, which indicates the effect of reduction is 12.8% compared to non implementation of the program.

Synthesis and Luminescence Enhancement of Strontium Aluminate Green Phosphor via Spray Pyrolysis (분무열분해 공정을 이용하여 스트론튬 알루미네이트 녹색 형광체의 합성 및 발광 특성 개선)

  • Kim, Mi Na;Jung, Kyeong Youl
    • Korean Chemical Engineering Research
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    • v.49 no.5
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    • pp.594-599
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    • 2011
  • $SrAl_2O_4:Eu$ green phosphor was prepared by spray pyrolysis and its luminescence properties were controlled by replacing the Al sites with boron and using organic modifier or drying control chemical additive. It was clear that the substitution of B into the Al sites was helpful to obtain pure monoclinic $SrAl_2O_4$ phase and greatly enhance the emission intensity. In terms of the emission intensity, the optimal content of boron was about 1 at% with respect to the aluminum element. The luminescence intensity of $Sr_{0.9}Al_{1.98}B_{0.02}O_4:Eu_{0.1}$ phosphor could be improved by the use of 0.2 M organic additives in the spray solution. Futhermore, using 0.5 M dimethylformamide(DMF) as a drying control chemical with organic additives made it possible to improve about 172% the emission intensity of $Sr_{0.9}Al_{1.98}B_{0.02}O_4:Eu_{0.1}$ phosphor. According to XRD analysis, the organic additive and DMF used enhanced the crystallinity without any change in the crystal phase. When used only the organic additive without DMF, the surface area of the prepared $Sr_{0.9}Al_{1.98}B_{0.02}O_4:Eu_{0.1}$ phosphor became enlarged. The use of DMF with the organic additive resulted in significant reduction in the surface area. It was concluded that the increase of the crystallinity as well as the reduction of surface area mainly contribute to the improvement in the luminescence intensity of $Sr_{0.9}Al_{1.98}B_{0.02}O_4:Eu_{0.1}$ phosphor prepared using DMF and organic additives.