• 제목/요약/키워드: Gaseous Phase

검색결과 213건 처리시간 0.023초

Lamp 형 오존발생기의 시작 및 특성에 관한 연구 (A Study on the Trial Manufacture and Characteristics of Lamp Type Ozonizer)

  • 김상구;송현직;강천수;박원주;이광식;이동인
    • 한국조명전기설비학회지:조명전기설비
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    • 제10권6호
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    • pp.62-72
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    • 1996
  • 본 연구에서는 광화학반응법을 이용하여 오존 발생기로서의 역할과 광원으로서의 기능을 동시에 수행할 수 있는 U자형 Lamp(Olamp)를 사용한 오존 발생기를 설계 및 제작하여 Olamp의 방전 특성, 스팩트럼 특성, 조도특성, 오존생성특성 및 살균특성을 연구검토한 결과 다음과 같은 결론을 얻을 수 있었다.(1)Olamp의 스펙트럼특성을 조사한 결과 오존을 생성하는 단파장 자외선과 조명으로 활용가능한 가시광선이 방사됨을 확인할 수 있었다.(2)Olamp의 조도는 한국산업표준규격 조도 기준에 의하여 "어두운 분위기중의 시식별작업 및 간헐적인 시작업"에 사용가능한 조도 특성을 얻을 수 있었다. (3)원료가스의 유량이 작을수록 오존생성농도는 상승하고 오존 발생량은 감소하였으며, 유량이 동일할 때 모의 공기를 사용한 경우보다 산소를 사용한 경우가 오존생성농도 및 오존발생량이 상승하였다.(4)오존발생량 및 오존생성수율은 초기 오존생성농도가 높을수록 상승하였다.(5)액상에서의 용존오존농도 특성은 반응장치의 교반속도 및 오존생성속도가 높을수록 상승하였다.(6)대장균(Escherichia coli)에 대한 살균특성을 조사한 결과, 97[%]이상의 살균 특성을 얻을 수 있었다. 얻을 수 있었다.

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Advances in the understanding of molybdenum effect on iodine and caesium reactivity in condensed phase in the primary circuit in nuclear severe accident conditions

  • Gouello, Melany;Hokkinen, Jouni;Karkela, Teemu
    • Nuclear Engineering and Technology
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    • 제52권8호
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    • pp.1638-1649
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    • 2020
  • In the case of a severe accident in a Light Water Reactor, the issue of late release of fission products, from the primary circuit surfaces is of particular concern due to the direct impact on the source term. CsI is the main iodine compound present in the primary circuit and can be deposited as particles or condensed species. Its chemistry can be affected by the presence of molybdenum, and can lead to the formation of gaseous iodine. The present work studied chemical reactions on the surfaces involving gaseous iodine release. CsI and MoO3 were used to highlight the effects of carrier gas composition and oxygen partial pressure on the reactions. The results revealed a noticeable effect of the presence of molybdenum on the formation of gaseous iodine, mainly identified as molecular iodine. In addition, the oxygen partial pressure prevailing in the studied conditions was an influential parameter in the reaction.

석탄연소중 발생되는 보일러 튜브의 화염측 부식특성 (Fireside Corrosion Characteristics in Coal-Fired Boiler Tube)

  • 김태형;서상일;박호영;김영주
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2006년도 제33회 KOSCO SYMPOSIUM 논문집
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    • pp.276-281
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    • 2006
  • Although fireside corrosion of heat transfer surfaces in coal fired steam generators has been a problem to some extent for a number of tears, with the advent of low NOx firing systems these surfaces can be exposed to conditions that will exacerbate wastage rates. Numerous reports of waterwall wastage in coal fired boilers have appeared in the literature. It is believed that wastage results both from gaseous phase attack of metal surfaces and from deposition of ash and unburned fuel. Gaseous phase attack is known to occur in the presence of reducing sulfur species such as $H_2S$ and in the presence of fuel chlorine. The highest wastage rates are thought to be due to deposition of unoxidized material and the presence of fuel chlorine. Localized wall and near wall conditions that may exacerbate wastage include reducing conditions, high temperatures, high heat fluxes, and a high fraction of unoxidized material deposited. So, this study is directed at developing an advanced corrosion model in coal-fired utility boilers.

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제어유의 문류품분효전에 미치는 형력의 영향 (A Study on the Effect of Pressure upon A.C Partial Discharge in Insulating Oil)

  • Sang-Hoon Kook
    • 대한전기학회논문지
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    • 제32권7호
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    • pp.227-233
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    • 1983
  • Noticing that action of gaseous phase in insulating oil concerns to the discharging characteristics, I investigated the smalness pressure effects on quantity of the partial discharge and discharging pulse frequency. Tests are carried out between the niddle points in insulating oil at pressure being changed by gradual charge of inert gas Ar. At pressure as low as of 0.1-0.5 torr pulse frequency and maximum partial discharge reach peak while at pressure haigher than 20 torr no pulse is observed. The fact that pulse frequency has peak value at certain presure, which is changed either by charging Ar or by adding oil, implies that the action of gaseous phase depends on pressure. Test results are that partial discharge pulse are governed by pressure of Ar-charged oil, and less partial discharge pulses correspond to smaller bubbles whereas more partial descharge pulses correspond to larger bubbles.

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불포화 토양내에서 가스상 오존 이동특성에 대한 Multiphase liquids의 영향

  • 정해룡;최희철
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2003년도 총회 및 춘계학술발표회
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    • pp.124-127
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    • 2003
  • Laboratory scale experiments on in-situ ozonation were carried out to delineate the effects of liquid phases, such as soil water and nonaqeous phase liquid (NAPL) on the transport of gaseous ozone in unsaturated soil. Soil water enhanced the transport of ozone due to water film effect, which prevent direct reaction between soil particles and gaseous ozone, and increased water content reduced the breakthrough time of ozone because of increased average linear velocity of ozone and decreased air-water interface area. Diesel fuel as NAPL also played a similar role with water film, so the breakthrough time of ozone in diesel-contaminated soil was significantly reduced compared with uncontaminated soil. However, ozone breakthrough time was retarded with increased diesel concentration, because of high reactivity of diesel fuel with ozone. In multiphase liquid system of unsaturated soil, the ozone transport was mainly Influenced by nonwetting fluid, diesel fuel in this study.

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Development and Current Status of Gaseous Nitrocarburizing

  • Bell, Tom
    • 열처리공학회지
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    • 제2권2호
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    • pp.68-83
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    • 1989
  • Physical metallurgy aspects of gaseous ferritic nitrocarburising are reviewed in the light of basic studies undertaken since 1975 which have illustrated inconsistencies between the iron-carbon-nitrogen ternary phase diagram at $570^{\circ}C$ and the experimental observation of the co-existence of the ${\varepsilon}$ carbonitride phase and ferrite. Thermodynamic investigations by Xu and Li together with those by Slycke et al are reviewed to illustrate compatability between a modified isothermal section of the Fe-C-N system and the formation and growth of a monophased ${\varepsilon}$ structure under a variety of processing conditions. The implications of the modified diagram in terms of innovations in industrial ferritic nitrocarburising practice are discussed, together with limitations on the control of the process. The importance of the developing technology of black nitrocarburising for enhanced wear, fatigue, and corrosion resistance is emphasised. Basic studies and industrial status of austenitic nitrocarburising treatments are also reviewed, which highlight the importance of substrate strengthening for high load bearing applications of anti-scuff thermochemical treatments.

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Open-Loop Responses of Droplet Vaporization to Linear Normal Acoustic Modes

  • Kim, S.Y.;W.S. Yoon
    • 한국추진공학회:학술대회논문집
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    • 한국추진공학회 2004년도 제22회 춘계학술대회논문집
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    • pp.155-164
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    • 2004
  • In order for studying pressure-coupled dynamic responses of droplet vaporization, open-loop experiment of an isolated droplet vaporization exposed to pressure perturbations in stagnant gaseous environment is numerically conducted, Governing equations are solved for flow parameters at gas and liquid phases separately and thermodynamic parameters at the interfacial boundary are matched for problem closure. For high-pressure effects, vapor-liquid interfacial thermodynamics is rigorously treated. A series of parametric calculations in terms of mean pressure level and wave frequencies are carried out employing a n-pentane droplet in stagnant gaseous nitrogen. Results show that wave instability in view of pressure-coupled vaporization response seems more susceptible at higher pressures and higher wave frequencies. Mass evaporation rate responding to pressure waves is amplified with increase in pressure due to substantial reduction in latent heat of vaporization. Augmentation of perturbation frequency also enhances amplification due to the reduction of phase differences between pressure perturbation and surface temperature fluctuation.

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가스 질화침탄처리한 탄소강의 화합물층 성장 및 부식특성에 미치는 $CO_2$함량의 영향 (Effect of $CO_2$ Content on the Growth and Corrosion Characteristics of the Compound Layers in Gaseous Nitrocarburized Carbon Steels)

  • 김영희;김석동;윤희재
    • 열처리공학회지
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    • 제15권5호
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    • pp.219-227
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    • 2002
  • This study has been performed to investigate the effect of $CO_2$ content on the growth characteristics of the compound layer, porous layer and corrosion characteristics of carbon steels after gaseous nitrocarburizing in $70%-NH_3-CO_2-N_2$ at $580^{\circ}C$ for 2.5 hrs. The results obtained from the experiment were the thickness of the compound and porous layers increased with increasing $CO_2$ contents. At the same fixed gas composition the thickness of the compound and porous layer increased with increasing carbon content of the specimens. X-ray diffraction analysis showed that compound layer was mainly consisted of ${\varepsilon}-Fe_{2-3}(N,C)$ and ${\gamma}^{\prime}-Fe_4N$ as the increased with $CO_2$ contents in atmosphere, compound layer was chiefly consisted of ${\varepsilon}-Fe_{2-3}(N,C)$ phase. With increasing $CO_2$ content and total flow rate in gaseous nitrocarburizing, the amount of ${\varepsilon}-Fe_{2-3}(N,C)$ phase in the compound layer was increased. The current density of passivity decreased with increasing $CO_2$ content due to the development of porous layer at the out most surface of ${\varepsilon}-Fe_{2-3}(N,C)$.

Effects of Spiral Arms on the Gaseous Features of Barred Spiral Galaxies

  • 김용휘;김웅태
    • 천문학회보
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    • 제36권2호
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    • pp.57.1-57.1
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    • 2011
  • Using high-resolution numerical simulations, we investigate the formation of gaseous substructures and mass inflow rates in barred spiral galaxies in the presence of both bar and spiral potentials. The gaseous medium is assumed to be infinitesimally-thin, isothermal, unmagnetized, and non-self-gravitating. To consider various galactic situations, we vary the pattern speed and strength of spiral arms as well as the black hole mass. We find that spiral arms with pattern speed smaller than that of the bar remove angular momentum from the gas outside corotation which transports to the bar region, making the dust lanes strong and live long. When the arm pattern speed is identical to that of the bar, on the other hand, the gas outside corotation gains angular momentum and thus moves outward, without affecting the bar region. Overall gaseous morphologies in simulations match well with observed IR images of barred spiral galaxies such as NGC 1097, when the arms and bar are in phase at the corotation radius. The presence of spiral arms increases the mass inflow rate as well, making it larger than $0.01M_{\odot}/yr$ when MBH is $4{\times}10^7M_{\odot}$, possibly explaining AGN activities in Seyfert galaxies.

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강한 음향장에 구속된 고압 액적의 연소 (Unsteady Vaporization of Burning Droplet at High Pressure Environments With Linear Acoustic Mode)

  • 김성엽;신현호;윤웅섭
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2004년도 추계학술대회
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    • pp.1122-1127
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    • 2004
  • an isolated droplet combustion exposed to pressure perturbations in stagnant gaseous environment is numerically conducted. Governing equations are solved for flow parameters at gas and liquid phases separately and thermodynamic parameters at the interfacial boundary are matched for problem closure. For high-pressure effects, vapor-liquid interfacial thermodynamics is rigorously treated. A series of parametric calculations in terms of mean pressure level and wave frequencies are carried out employing a n-pentane droplet in stagnant gaseous air. Results show that the operating pressure and driving frequency have an important role in determining the amplitude and phase lag of a combustion response. Mass evaporation rate responding to pressure waves is amplified with increase in pressure due to substantial reduction in latent heat of vaporization. Phase difference between pressure and evaporation rate decreases due to the reduced thermal inertia at high pressure. In addition to this, augmentation of perturbation frequency also enhances amplification of vaporization rate because the time period for the pressure oscillation is much smaller than the liquid thermal inertia time. The phase of evaporation rate shifts backward due to the elevated thermal inertia at high acoustic frequency.

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