불포화 토양내에서 가스상 오존 이동특성에 대한 Multiphase liquids의 영향

  • 정해룡 (광주과학기술원 환경공학과) ;
  • 최희철 (광주과학기술원 환경공학과)
  • Published : 2003.04.01

Abstract

Laboratory scale experiments on in-situ ozonation were carried out to delineate the effects of liquid phases, such as soil water and nonaqeous phase liquid (NAPL) on the transport of gaseous ozone in unsaturated soil. Soil water enhanced the transport of ozone due to water film effect, which prevent direct reaction between soil particles and gaseous ozone, and increased water content reduced the breakthrough time of ozone because of increased average linear velocity of ozone and decreased air-water interface area. Diesel fuel as NAPL also played a similar role with water film, so the breakthrough time of ozone in diesel-contaminated soil was significantly reduced compared with uncontaminated soil. However, ozone breakthrough time was retarded with increased diesel concentration, because of high reactivity of diesel fuel with ozone. In multiphase liquid system of unsaturated soil, the ozone transport was mainly Influenced by nonwetting fluid, diesel fuel in this study.