• Title/Summary/Keyword: Gas transport

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Pore-network Study of Liquid Water Transport through Multiple Gas Diffusion Medium in PEMFCs (고분자 연료전지의 다공성층 내에서의 액상수분 이동에 관한 공극-네트워크 해석 연구)

  • Kang, Jung-Ho;Lee, Sang-Gun;Nam, Jin-Hyun;Kim, Charn-Jung
    • 한국전산유체공학회:학술대회논문집
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    • 2011.05a
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    • pp.46-53
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    • 2011
  • Water is continuously produced in polymer electrolyte membrane fuel cell (PEMFC), and is transported and exhausted through polymer electrolyte membrane (PEM), catalyst layer (CL), microporous layer (MPL), and gas diffusion layer (GDL). The low operation temperatures of PEMFC lead to the condensation of water, and the condensed water hinders the transport of reactants in porous layers (MPL and GDL). Thus, water flooding is currently one of hot issues that should be solved to achieve higher performance of PEMFC. This research aims to study liquid water transport in porous layers of PEMFC by using pore-network model, while the microscale pore structure and hydrophilic/hydrophobic surface properties of GDL and MPL were fully considered.

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Nozzle effect on the formation of Methane hydrate

  • Seo, Hyang-Min;Park, Sung-Seek;Kim, Nam-Jin
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.10a
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    • pp.226-229
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    • 2008
  • When methane hydrate is artificially formed to store and transport large quantity of natural gas, its reaction time may be too long and the gas consumption in water becomes relatively low, the reaction rate between water and methane gas is low. Therefore, the present investigation focuses on the rapid production of hydrates and increases the gas consumption by injecting water into methane gas utilizing nozzle. the hydrate in water injection using a nozzle formed rapidly more than that in gas injection, and the gas consumption of methane hydrate in water injection is about three to four times greater than that in gas injection according to subcooling.

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Measurement of In-plane Gas Permeability of Gas Diffusion Layers in Proton Exchange Membrane Fuel Cells under Compressive Strain (고분자 전해질 연료전지 가스확산층의 압축상태 평면 기체투과율 측정)

  • Oh, Changjun;Lee, Yongtaek
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.28 no.9
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    • pp.367-372
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    • 2016
  • Gas diffusion layer (GDL) of PEMFCs plays a role that it diffuses the reactant gases to the catalyst layer on the membrane and discharge water from the catalyst layer to the channel. Physical parameters related to the mass transport of GDL are mostly from the uncompressed GDLs while actual GDLs in the assembled stacks are compressed. In this study, the relation of compression and strain of GDLs with various Polytetrafluoroethylene (PTFE) loading is measured experimentally and In-plane gas permeability is measured at the condition that the GDLs are in compressive strain. The gas permeability decreased with the loading of PTFE and the presentation of gas permeability under compressive stain is expected to improve the accuracy of modeling work of mass transport in the GDL.

Synthesis of $WS_2$ Solid Lubricant ($WS_2$ 고체 윤활제의 합성)

  • 신동우;윤대현;황영주;김성진;김인섭
    • Tribology and Lubricants
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    • v.13 no.4
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    • pp.60-65
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    • 1997
  • The tungsten disulfide $(WS_2)$ solid lubricant was synthesized by two different reaction processes, i.e., the reaction between $CS_2$ gas phase and solid $WO_3$powder, and the vapour phase transport method of tungsten and sulfur in a high vacuum. The chemical and physical characteristics of synthesized $WS_2$powder were analyzed in terms of the average particle size, morphology, crystalline phase etc. in comparison with those of commercial $WS_2$powder. The solid $WO_3$ powder with the average size of 0.2 ${\mu}{\textrm}{m}$ was reacted with $CS_2$gas flowed with$N_2$or 96%$N_2{\times}4%H_2$forming gas for 36 h and 24 h at 90$0^{\circ}C$ respectively. $WS_2$ crystalline phase was then formed through the intermediate phase of .$W_{20}O_{58}$ In the case of vapour phase transport method, the 3.5 wt% iodine was added as a vapour transport reagent into the composition of tungsten and sulfur powders maintaining a constant molar ratio of W:S=1:2.2. The mixture was then heat treated at 85$0^{\circ}C$ for 2 weeks in vacuum. The reaction product obtained showed the average size of 12 ${\mu}{\textrm}{m}$ and the hexagonal plate shape of typical solid lubricant with 2H-$WS_2$crystalline phase.

Preparation of Polyvinylpyrrolidone/AgBF4/Al(NO3)3 Electrolyte Membranes for Facilitated Gas Transport (기체 촉진수송을 위한 polyvinylpyrrolidone/AgBF4/Al(NO3)3 전해질 분리막 제조)

  • Yoon, Ki Wan;Kang, Sang Wook
    • Membrane Journal
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    • v.26 no.1
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    • pp.38-42
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    • 2016
  • Polyvinylpyrrolidone (PVP), which is glassy polymer to have amide functional group, was induced to fabricate the facilitated olefin transport membranes for olefin/paraffin separation. Separation performance for the mixed gas consisting of propylene and propane (50 : 50 vol%) was measured by gas chromatography and bubble flow meter. The properties of membranes were confirmed by scanning electron microscope and FT-IR. The results of long-term separation tests showed the selectivity of 15 and permeance of 1.3 GPU. The membranes was compared with poly(2-ethyl-2-oxazoline) $(POZ)/AgBF_4/Al(NO_3)_3$ membranes and the characteristics were confirmed as polymer matrix for facilitated transport membranes.

The analysis of electron transport coefficients in $CF_4$ molecular gas by multi-term approximation of the Boltzmann equation (다항근사 볼츠만 방정식에 의한 $CF_4$ 분자가스의 전자수송계수 해석)

  • Jeon, Byung-Hoon;Park, Jae-June;Ha, Sung-Chul
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11b
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    • pp.141-144
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    • 2001
  • An accurate cross sections set are necessary for the quantitatively understanding and modeling of plasma phenomena. By using the electron swarm method. we determine an accurate electron cross sections set for objective atoms or molecule at low electron energy range. In previous paper, we calculated the electron transport coefficients in pure $CF_4$ molecular gas by using two-term approximation of the Boltzmann equation. And by using this simulation method. we confirmed erroneous calculated results of transport coefficients for $CF_{4}$ molecule treated in this paper having 'C2v symmetry' as $C_{3}H_{8}$ and $C_{3}F_{8}$ which have large vibrational excitation cross sections which may exceed elastic momentum transfer cross section. Therefore, in this paper, we calculated the electron transport coefficients(W and $ND_L$) in pure $CF_4$ gas by using multi-term approximation of the Boltzmann equation by Robson and Ness which was developed at lames-Cook university, and discussed an application and/or validity of the calculation method by comparing the calculated results by two-term and multi-term approximation code.

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The analysis of electron transport coefficients in CF$_4$ molecular gas by multi-term approximation of the Boltzmann equation (다항근사 볼츠만 방정식에 의한 CF$_4$분자가스의 전자수송계수 해석)

  • 전병훈;박재준;하성철
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11a
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    • pp.141-144
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    • 2001
  • An accurate cross sections set are necessary for the quantitatively understanding and modeling of plasma phenomena. By using the electron swarm method, we determine an accurate electron cross sections set for objective atoms or molecule at low electron energy range. In previous paper, we calculated the electron transport coefficients in pure CF$_4$ molecular gas by using two-term approximation of the Boltzmann equation. And by using this simulation method, we confirmed erroneous calculated results of transport coefficients for CF$_4$ molecule treated in this paper having 'C2v symmetry'as C$_3$H$_{8}$ and C$_3$F$_{8}$ which have large vibrational excitation cross sections which may exceed elastic momentum transfer cross section. Therefore, in this paper, we calculated the electron transport coefficients(W and ND$_{L}$) in pure CF$_4$ gas by using multi-term approximation of the Boltzmann equation by Robson and Ness which was developed at James-Cook university, and discussed an application and/or validity of the calculation method by comparing the calculated results by two-term and multi-term approximation code.e.

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Numerical study of oxygen transport characteristics in lead-bismuth eutectic for gas-phase oxygen control

  • Wang, Chenglong;Zhang, Yan;Zhang, Dalin;Lan, Zhike;Tian, Wenxi;Su, Guanghui;Qiu, Suizheng
    • Nuclear Engineering and Technology
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    • v.53 no.7
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    • pp.2221-2228
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    • 2021
  • One-dimensional oxygen transport relation is indispensable to study the oxygen distribution in the LBE-cooled system with an oxygen control device. In this paper, a numerical research is carried out to study the oxygen transport characteristics in a gas-phase oxygen control device, including the static case and dynamic case. The model of static oxygen control is based on the two-phase VOF model and the results agree well with the theoretical expectation. The model of dynamic oxygen control is simplified and the gas-liquid interface is treated as a free surface boundary with a constant oxygen concentration. The influences of the inlet and interface oxygen concentration, mass flow rate, temperature, and the inlet pipe location on the mass transfer characteristics are discussed. Based on the results, an oxygen mass transport relation considering the temperature dependence and velocity dependence separately is obtained. The relation can be used in a one-dimensional system analysis code to predict the oxygen provided by the oxygen control device, which is an important part of the integral oxygen mass transfer models.

The study of ionization and attachment coefficients in $CF_4$ molecular gas by Boltzmann equation (볼츠만 방정식에 의한 $CF_4$ 분자가스의 전리 및 부착계수에 관한 연구)

  • Song, Byoung-Doo;Ha, Sung-Chul;Jeon, Byoung-Hoon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.11a
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    • pp.628-631
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    • 2004
  • A tetrafluoromethane$(CF_4)$ is most useful gas in plasma dry etching, because it has a electron attachment cross-section. therefor it is important to calculate transport coefficients like electron drift velocity, ionization coefficient, attachment coefficient, effective ionization coefficient. and critical E/N. The aim of this study is to get these transport coefficients for information of the insulation strength and efficiency of etching process. Electron transport coefficients in $CF_4+Ar$ gas mixture are simulated in range of E/N values from 1 to 250 [Td] at 300[K} and 1 [Torr] by using Boltzmann equation method. The results of this method can be important data to present characteristic of gas for plasma etching and insulation, specially critical E/N is a data to evaluate insulation strength of a gas. and is presented in this paper for various mixture ratios of $CF_4+Ar$ gas mixture.

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Characterization of Two GAS1 Genes and Their Effects on Expression and Secretion of Heterologous Protein Xylanase B in Kluyveromyces lactis

  • Lian, Zhao;Jiang, Jing-Bo;Chi, Shuang;Guan, Guo-Hua;Li, Ying;Li, Ji-Lun
    • Journal of Microbiology and Biotechnology
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    • v.25 no.12
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    • pp.1977-1988
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    • 2015
  • β-1,3-glucanosyltransferases play essential roles in cell wall biosynthesis in yeast. Kluyveromyces lactis has six putative β-1,3-glucanosyltransferase genes. KlGAS1-1 and KlGAS1-2 are homologs of Saccharomyces cerevisiae gene GAS1. RT-qPCR indicated the transcription level of KlGAS1-1 was significantly reduced while heterologous protein (thermostable xylanase B) secretion was enhanced during medium optimization. To evaluate if these two events were related, and to improve xylanase B secretion in K. lactis, we constructed KlGAS1-1 and KlGAS1-2 single deletion strains and double deletion strain, respectively. KlGAS1-1 gene deletion resulted in the highest xylanase B activity among the three mutants. Only the double deletion strain showed morphology similar to that of the GAS1 deletion mutant in S. cerevisiae. The two single deletion strains differed in terms of cell wall thickness and xylanase B secretion. Transcription levels of β-1,3-glucanosyltransferase genes and genes related to protein secretion and transport were assayed. The β-1,3-glucanosyltransferase genes displayed transcription complementation in the cell wall synthesis process. KlGAS1-1 and KlGAS1-2 affected transcription levels of secretion- and transport-related genes. Differences in protein secretion ratio among the three deletion strains were associated with changes of transcription levels of secretion- and transport-related genes. Our findings indicate that KlGAS1-1 deletion is an effective tool for enhancing industrial-scale heterologous protein secretion in K. lactis.