• Title/Summary/Keyword: Gas Helium

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Effect of Gas Density on Self-Pulsation in Liquid-Gas Swirl Coaxial Injector (액체-기체 와류동축형 분사기의 자기-맥동에 대한 기체 밀도의 영향)

  • Ahn, Jonghyeon;Kang, Cheolwoong;Ahn, Kyubok
    • Journal of ILASS-Korea
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    • v.27 no.3
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    • pp.134-143
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    • 2022
  • When a recess is applied to a swirl coaxial injector that uses liquid and gas propellants, a self-pulsation phenomenon in which the spray oscillates at regular intervals may occur. The phenomenon is caused by the interaction between the liquid and gas propellants inside the injector recess region. The propellants' kinetic energies are expected to affect significantly the spray oscillation. Therefore, cold-flow tests using helium as a gas-simulating propellant were conducted and compared with the results of the previous study using air. Dynamic pressure was measured in the injector manifold and frequency characteristics were investigated through the fast Fourier transform analysis. In the experimental environment, the helium density was about seven times lower than the air density. Accordingly, the intensity of pressure fluctuations was confirmed to be greater when air was used. At the same kinetic energy condition, the perturbation frequency was almost identical in the low flow rate conditions. However, as the flow rate increased, the self-pulsation frequency was higher when helium was used.

High Temperature Corrosion of Alloy 617 in Impure Helium and Air for Very High-Temperature Gas Reactor (초고온가스로용 Alloy 617의 불순물 함유 헬륨/공기 중에서 고온부식 특성)

  • Jung, Sujin;Lee, Gyeong-Geun;Kim, Dong-Jin;Kim, Dae-Jong
    • Corrosion Science and Technology
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    • v.12 no.2
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    • pp.102-112
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    • 2013
  • A very high-temperature gas reactor (VHTR) is one of the next generation nuclear reactors owing to its safety, high energy efficiency, and proliferation-resistance. Heat is transferred from the primary helium loop to the secondary helium loop through an intermediate heat exchanger (IHX). Under VHTR environment Alloy 617 is being considered a candidate Ni-based superalloy for the IHX of a VHTR, owing to its good creep resistance, phase stability and corrosion resistance at high temperature. In this study, high-temperature corrosion tests were carried out at 850 - $950^{\circ}C$ in air and impure helium environments. Alloy 617 specimens showed a parabolic oxidation behavior for all temperatures and environments. The activation energy for oxidation was 154 kJ/mol in helium environment, and 261 kJ/mol in an air environment. The scanning electron microscope (SEM) and energy-dispersive x-ray spectroscopy (EDS) results revealed that there were a Cr-rich surface oxide layer, Al-rich internal oxides and depletion of grain boundary carbide after corrosion test. The thickness and depths of degraded layers also showed a parabolic relationship with the time. A corrosion rate of $950^{\circ}C$ in impure helium was higher than that in an air environment, caused by difference in the outer oxide morphology.

High-Temperature Corrosion Behavior of Alloy 617 in Helium Environment of Very High Temperature Gas Reactor (초고온가스로 헬륨 분위기에서 Alloy 617의 고온 부식 거동)

  • Lee, Gyeong-Geun;Jung, Sujin;Kim, Daejong;Jeong, Yong-Whan;Kim, Dong-Jin
    • Korean Journal of Metals and Materials
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    • v.50 no.9
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    • pp.659-667
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    • 2012
  • Alloy 617 is a Ni-base superalloy and a candidate material for the intermediate heat exchanger (IHX) of a very high temperature gas reactor (VHTR) which is one of the next generation nuclear reactors under development. The high operating temperature of VHTR enables various applications such as mass production of hydrogen with high energy efficiency. Alloy 617 has good creep resistance and phase stability at high temperatures in an air environment. However, it was reported that the mechanical properties decreased at a high temperature in an impure helium environment. In this study, high-temperature corrosion tests were carried out at $850^{\circ}C-950^{\circ}C$ in a helium environment containing the impurity gases $H_2$, CO, and $CH_4$, in order to examine the corrosion behavior of Alloy 617. Until 250 h, Alloy 617 specimens showed a parabolic oxidation behavior at all temperatures. The activation energy for oxidation in helium environment was 154 kJ/mol. The SEM and EDS results elucidated a Cr-rich surface oxide layer, Al-rich internal oxides and depletion of grain boundary carbides. The thickness and depths of degraded layers also showed a parabolic relationship with time. A normal grain growth was observed in the Cr-rich surface oxide layer. When corrosion tests were conducted in a pure helium environment, the oxidation was suppressed drastically. It was elucidated that minor impurity gases in the helium would have detrimental effects on the high-temperature corrosion behavior of Alloy 617 for the VHTR application.

Development of nitrogen and oxygen certified reference materials in 10 μmol/mol for the purity evaluation

  • Ahn, Byung Soo;Moon, Dong Min;Lee, Jin Bok;Kim, Jin Seog;Lee, Jin-Hong;Hong, Kiryong
    • Analytical Science and Technology
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    • v.33 no.2
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    • pp.68-75
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    • 2020
  • We have developed 10 μmol/mol nitrogen and oxygen certified reference materials (CRMs) in helium, as a SI-traceable gas standard for a quantifying of impurities in pure gases for the first time in Korea. The standard gas mixtures of nitrogen and oxygen were prepared in 5000 μmol/mol and sequentially were diluted to 250 μmol/mol and 10 μmol/mol according to the gravimetric preparation. In each dilution step, two cylinders of CRMs were prepared. The verification of internal consistency among the prepared gas mixtures was performed by using GC-TCD. The amount fractions and those expanded uncertainties (k = 2) of nitrogen and oxygen in the standard gas mixtures were (10.12 ± 0.08) μmol/mol and (10.18 ± 0.08) μmol/mol for nitrogen, and (9.88 ± 0.06) μmol/mol and (9.94 ± 0.06) μmol/mol for oxygen, respectively. We have conducted a purity assessment of two commercial helium gases using developed CRMs. As the results of the purity assessment, nitrogen and oxygen were detected by (1.66 ± 0.03) μmol/mol and (0.31 ± 0.02) μmol/mol, respectively, as the impurities in one of the pure helium.

Effects of Noble Gas on the Sonolytic Decomposition (초음파분해반응에 있어서 희가스의 영향)

  • 임봉빈;김선태
    • Journal of Environmental Science International
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    • v.11 no.7
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    • pp.749-755
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    • 2002
  • The effects of noble gas (such as helium, neon, argon, krypton, and xenon) on the sonolytic decomposition of water and 2-methyl-2-propanol(t-butanol) with 200 KHz high power ultrasound were investigated. The physical properties of the noble gas have an effect on the formation rate of products $(H_2O_2,\;H_2,\;O_2)$ and the decomposition rate on the sonolytic decomposition of water. The pyrolysis products, such as methane, ethane, ethylene, and acetylene are formed during the sonolytic decomposition of t-butanol. From the estimation of the ratio $[C_2H_4+C_2H_2] / [C_2H_6]$, the cavitation temperature would be varied by the used noble gas. In all cases for the sonolytic decomposition of water, t-butanol, and diethyl phthalate, the decomposition rates were xenon > krypton > argon > neon > helium with a significant difference and were closely correlated with the formation rate of OH radical and high temperature inside the cavitation bubble under each noble gas.

Investigation on vapor-cooled current leads operating in pulse mode (펄스 모드로 작동하는 증기냉각 전류 도입선에 관한 연구)

  • 인세환;정상권
    • Progress in Superconductivity and Cryogenics
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    • v.4 no.1
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    • pp.66-72
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    • 2002
  • This paper describes numerical modeling for thermal characteristic of vapor-cooled current leads under pulse operation. The transient thermal analysis considers the temperature difference between a helium gas (low and a copper lead and temperature dependent properties of helium gas, copper and stainless steel. This numerical modeling was compensated and validated by an experiment with commercially available 100 A vapor-cooled current leads. A proper overloading factor was suggested for the current leads under pulse operation through this modeling, which can significantly reduce heat input to a cryostat.

A Study on the Extinction Concentration of Inert Gas for Extinction Performance Estimation of Kerosene (등유의 소화성능 평가를 위한 불활성 가스의 소화농도에 관한 연구)

  • Choi, Jae-Wook
    • Journal of the Korean Society of Safety
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    • v.22 no.3 s.81
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    • pp.34-38
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    • 2007
  • The experiment was done to investigate extinguishing concentrations of different inert gases of verying concentrations made in contact with Kerosene. The experimental results obtained are as follows; at a standard amount of air flow was 40L/min, the extinguishing concentration of Argon, Nitrogen, Carbon dioxide and Helium for Kerosene were 36.5%, 27.3%, 17.4%, 12.3%, respectively. And, according to these results, Helium of 12.3% showed the lowest extinguishing concentration.

Laser-induced plasma emission spectra of halogens in the helium gas flow and pulsed jet (헬륨 가스 플로우와 가스 펄스 젯에서 할로겐족 원소들의 레이저유도 플라즈마 방출 스펙트럼)

  • Lee, Yonghoon;Choi, Daewoong;Gong, Yongdeuk;Nam, Sang-Ho;Nah, Changwoon
    • Analytical Science and Technology
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    • v.26 no.4
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    • pp.235-244
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    • 2013
  • Detection of halogens using laser-induced breakdown spectroscopy (LIBS) in open air is very difficult since their strong atomic emission lines are located in VUV region. In NIR region, there are other emission lines of halogens through electronic transitions between excited states. However, these lines undergo Stark broadening severely. We report the observation of the emission lines of halogens in laser-induced plasma (LIP) spectra in NIR region using a helium gas flow. Particularly, the emission lines of iodine at 804.374 and 905.833 nm from LIPs have been observed for the first time. In the helium ambient gas, Stark broadening of the emission lines and background continuum emission could be suppressed significantly. Variations of the line intensity, plasma temperature, and electron density with the helium flow rate was investigated. Detection of chlorine and bromine in flame retardant of rubbers was demonstrated using this method. Finally, we suggest a pulsed helium gas jet as a practical and ecomonical helium gas source for the LIBS analysis of halogens in open air.

An experimental study on the concentration distribution of helium and air mixture in the direct injection type engine (헬륨$\cdot$공기흡합기농도분포에 관한 실험적 연구)

  • 김봉곤;하종률;권순석
    • Journal of the korean Society of Automotive Engineers
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    • v.12 no.1
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    • pp.33-39
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    • 1990
  • This study has been conducted by experiments for distribution of concentration of helium gas, which is jetted into stationary atmosphere at the normal temperature and pressure. It is able to obtain the data for concentration of helium and air mixtures by the use of hot wire probe which has fast response. At an up stream, the concentration gradient which is attained is steep. At a down stream, the mixing time of helium and air is gradually shortened with the lapse of time in front of a jet. The arrival frequency of a jet in an unsteady area is mostly constant from 0% to 100% up to 80mm, but the time which is reaching to 100% is gradually to lengthen as a descending downstream. After starting a jet and the point of 90%, the mixing time is especially to lengthen. This reason comes from the turbulent intensity which causes for mixing of helium and air. This time difference which causes according to lengthen a jet should be considered in the design of combustion chamber.

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