• Bulletin of the Korean Chemical Society
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• v.32 no.4
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• pp.1231-1236
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• 2011

Chiral discrimination is the ability to distinguish one enantiomeric form over another. The differential binding interaction between two molecules with the same helicity and those with the opposite helicity was investigated by using dispersion-corrected density functional theory. [5]helicene, tetrahydro[5]helicene and the polar D-${\pi}$-A compounds, 3,12-dimethoxy-7,8-dicyano-[5]helicene and 3,12-dimethoxy-7,8-dicyano-tetrahydro[5]helicene were the monomers considered in this study. In gas phase, the dimeric interaction from two helical molecules with the opposite handedness is greater than from those with the same handedness. The stable configurations of such dimers were identified. The most stable configuration tends to be the one with maximum contact between monomers.

• The KSFM Journal of Fluid Machinery
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• v.17 no.6
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• pp.69-73
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• 2014

To predict flow fields and chemical agent dispersion in urban area, wind tunnel experiments was performed. The agent was adopted MS (methyl salicylate) because the real chemical agent is unsafe. The exact concentration of methyl salicylate was generated by the commercial gas generator (STI-2500) and three different obstacle shapes were applied (i.e., rectangular, cylinder and pyramid). The concentration was measured with the qualified ion mobility sensor and gas chromatography. The data necessary for virtual test method of the real chemical agent were obtained.

• Journal of Environmental Science International
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• v.9 no.1
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• pp.57-64
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• 2000

The sensitivity analysis of two short-term models (ISCST3, INPUFF2.5) is performed to improve the model accuracy. It appears that the sensitivities on the changes of wind speed, stack height and stack inner diameter in the near distance from source, stability and mixing height in the remote distance form source, are significant. Also the gas exit velocity, stack inner diameter, gas temperature and air temperature which affect the plume rise have some effects on the concentration values of each model within the downwind distance where final plume rise is determined. And in modeling for the atmospheric dispersion of point pollutant source INPUFF2.5 can calculate amount, trajectory of puff and concentration versus time at each receptors. So, it is compatible to analyze distribution of point pollutants concentration at modeling area.

• Journal of the Korean Institute of Gas
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• v.16 no.5
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• pp.58-65
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• 2012

Various models are currently applied to predict the dispersion of leaked combustible gas and overpressure from a vapor cloud explosion(VCE). However, those models use simple approaches where topography and barriers of anti-leakage facilities and the effects of buildings were not sufficiently taken into considerations. For this reason, this study has proposed the dispersion process of leaked gas, distribution patterns, and flames and overpressure generated from gas explosions in 2D and 3D virtual spaces by reviewing more accurately analyzable computational fluid dynamics (CFD) model by considering various variables including combustion types of leaked substances, geometry of facility, warm currents, barriers, the influence of wind, and others. The CFD analysis results are anticipated to be usefully applied for the risk analysis of explosion and for the risk-based design.

• Journal of the Korean Institute of Gas
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• v.26 no.1
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• pp.20-26
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• 2022

The results of experimental, theoretical, and numerical analysis were compared regarding the concentrations and velocities of flammable gas jets generated by pressurized leakage of methane gas. The concentration was measured through experiments for the jet dispersion process, and the velocities was calculated by applying the self-similarity theory. And the velocities and concentrations were calculated using CFD tools - FLACS and CFX- compared with the results. The difference between self-similarity model and CFD is due to the buoyancy term, which increases as the distance from a leak source increases. The results are compared with dimensionless parameters using the leak source radius and velocity components along the leak axis.

• Journal of the Korean Society of Safety
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• v.32 no.5
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• pp.168-178
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• 2017

In order to prevent major and chemical accidents, some of the plants which would like to install and operate hazard chemicals handling facilities must submit Off-site Consequence Analysis due to recent arisen leak accidents since 2015. A lot of chemical industrials choose gas detectors as mitigation equipment to early detect gas vapor. The way of placement of gas detectors has two methods; Code-based Design(CBD) and Performance-based Design. The CBD has principles for gas detectors to be installed with consideration for the place that is expected to accumulate gas, and the leak locations according to legal standards and technical guidelines, and has a possibility to be unable to detect by these rules to locate gas detectors by vapor density information. The PBD has two methods; a Geographic Method and Scenario based Method. The Scenario-based Method has been suggested to make up for the Geographic Coverage Method. This Scenario-based Method draw the best optimum placement of gas detectors by considering leak locations, leak speed information, leak directions and etc. However, the domestic placement guidelines just refers to the CBD. Therefore, this study is to compare existing placement location of gas detectors by the domestic CBD with placement locations, coverages and the number of gas detectors in accordance with the Scenario-based Method. Also this study has measures for early detecting interest of Vapor Cloud and suitable placement of gas detectors to prevent chemical accidents. The Phast software was selected to simulate vapor cloud dispersion to predict the consequence. There are two cases; an accident hole size of leak(8 mm) from API which is the highst accident hole size less than 24.5 mm, and a normal leak hole size from KOSHA Guide (1.8 mm). Detect3D was also selected to locate gas detectors efficiently and compare CBD results and PBD results. Currently, domestic methods of gas detectors do not consider any risk, but just depend on domestic code methods which lead to placement of gas detectors not to make personnels recognize tolerable or intolerable risks. The results of the Scenario-based Method, however, analyze the leak estimated range by simulating leak dispersion, and then it is able to tell tolerable risks. Thus it is considered that individuals will be able to place gas detectors reasonably by making objectives and roles flexibly according to situations in a specific plant.

• Special Issue of the Society of Naval Architects of Korea
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• 2011.09a
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• pp.63-69
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• 2011

Exhaust gases of a vessel from a main engine, a diesel generator and an incinerator contain very harmful substances like soot, $SO_2$ and NOx. Careful design of funnel shape is required to prevent those harmful exhaust gases from influencing on accommodation and a fan room. Meanwhile, the exhaust gases are also hot enough to damage electronic devices like radar. Therefore the funnel design should be considered so that electronic devices are not directly exposed to the exhaust gas in the strong stern wind. This study may propose guidelines of optimum design criterion for the anti-thermal damage design of the electronic devices and anti-recirculating design of harmful exhaust gas near the accommodation. From CFD analyses, we can understand that the major factors affecting the exhaust gas dispersion are the large scale mixing by separation vortices and the sluggish flow in the recirculation region. We hope that the funnel flow analysis around ship's funnel is used for practical optimum funnel design to minimize the exhaust gas dispersion by adjusting the funnel shape, the position of the exhaust pipe, the shape of bulwark, the exhaust direction of air ventilated an engine room and the angle of the exhaust pipe.

• The Bulletin of The Korean Astronomical Society
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• v.40 no.1
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• pp.42.3-43
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• 2015

Using a large sample of 32,000 type 2 AGNs out to z = 0.2, we present the statistical results on the ionized gas outflows, based on the analysis of the velocity shift of narrow emission lines with respect to the systemic velocity measured from the stellar absorption lines. Considering the projection effect, the fraction of type 2 AGNs with the [O III] velocity offset, which is ~50%, is comparable to that of type 1 AGNs. The velocity dispersion of [OIII] is typically larger than that of Ha, suggesting that outflow is prevalent in type 2 AGNs. A weak correlation of the OIII luminosity with velocity shift and velocity dispersion indicates that outflow velocity is stronger for higher luminosity AGNs. Based on our 3-D biconical outflow models with simple assumptions on the velocity structure, we simulate the projected 2-D velocity and velocity dispersion maps, which are spatially integrated to reproduce the measurements of SDSS AGNs. By comparing the distribution of the measured velocity and velocity dispersion of OIII, with the model grids, we constrain the intrinsic outflow velocities. The outflow velocity ranges from a few hundreds to a thousand km/s, implying a strong feedback to ISM.

• Proceedings of the KSME Conference
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• 2007.05b
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• pp.3033-3038
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• 2007

In this research, Rayleigh instability of gas-liquid flow in annular pipe is studied in film boiling using viscous potential flow. Viscous potential flow is a kind of approximation of gas-liquid interface considering velocity field as potential including viscosity. A dispersion relation is obtained including the effect of heat and mass transfer and viscosity. New expression for dispersion relation in film boiling and critical wave number is obtained. Viscosity and heat and mass transfer have a stabilizing effect on instability and its effect appears in maximum growth rate and critical wave number. And the existence of marginal stability region is shown.

• Journal of the Korean Society of Safety
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• v.9 no.1
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• pp.146-154
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• 1994

A series of numerical calculations are performed in order to investigate the dispersion mechanism of toxic gaseous and solid pollutants in extremely short-term and short range. The calculations are carried out in an open space characterized by turbulent boundary layer. The simulation is made by the use of numerical model, in which a control-volume based finite difference method is used together with the SIMPLEC algorithm for the resolution of the pressure-velocity coupling problem. The Reynolds stresses are solved by two-equation, k-$\varepsilon$ model modified for buoyancy. The major parameters consider-ed in this study are temperature, velocity and Injection height of toxic gases, environmental conditions such as temperature and velocity of free stream air, and topographic factor. The results are presented and discussed in detail. The flow field is commonly characterized by the formation of a strong recirculation zone due to the upward motion of the hot toxic gas and ground shear stress. The driving force of the upward motion is explained by the effect of thermal buoyancy of hot gas and the difference of inlet velocity between toxic gas and free stream.