• Title/Summary/Keyword: Function Separation

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Separation of Hydrogen-Nitrogen Gas Mixture by PTMSP-Silica-PEI Composite Membranes (PTMSP-Silica-PEI 복합막에 의한 수소-질소 혼합기체 분리)

  • Lee Hyun-Kyung;Choi Youn-Jung
    • Membrane Journal
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    • v.14 no.4
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    • pp.304-311
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    • 2004
  • The poly(1-trimethylsilyl-1-propyne) (PTMSP) and silica-filled PTMSP membranes were prepared by casting from a toluene solution on porous polyetherimide (PEI). FT-IR spectrum, GPC and SEM pictures have been taken to characterize the membranes. The particle size of membrane decreases as silica content of the membrane increases from 23 to 60 wt%, and a uniform distribution of the silica is observed. The separation properties of the gas mixture (32 mol% $H_2$/ 68 mol% $N_2$) through the composite membranes were studies as a function of pressure and percentage of silica. Selectivity values of $H_2$/$N_2$ increased as the pressure of permeation cell and silica content of the membrane increased. The real separation factor($\alpha$), head separation factor($\beta$), and tail separation factor((equation omitted)) of PTMSP-PEI composite membrane were 2.28, 1.58, and 1.44 respectively at $\Delta$P 30 psi and $25^{\circ}C$. $\alpha$, $\beta$, and (equation omitted) of PTMSP-Silica-PEI composite membrane for 60 wt% silica were 3.34, 1.95, 1.72 at $\Delta$P 30 psi and $25^{\circ}C$.

Separation of $H_2$/$N_2$ Gas Mixture by PTMSP/PDMS-PEI Composite Membrane (PTMSP/PDMS-PEI 복합막에 의한 수소/질소 혼합기체 분리)

  • Kang Tae-Bum;Hong Se-Lyung
    • Membrane Journal
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    • v.14 no.4
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    • pp.298-303
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    • 2004
  • PTMSP/PDMS-PEI composite membrane was prepared by solution casting method. To investigate the characteristics of this membrane, the analytical methods such as FT-IR, $^1$H-NMR, DSC, TGA, GPC, and SEM have been utilized. The number-average((equation omitted)) and weight-average((equation omitted)) molecular weight of PTMSP/PDMS copolymer were 501,516 and 675,560 respectively. The separation of the gas mixture($H_2$/$N_2$) through the composite membrane was studied as a function of pressure. The separation factor($\alpha$, $\beta$, (equation omitted)) of the composite membrane used in this work increased as the pressure of permeation cell increased. The real separation factor($\alpha$), head separation factor($\beta$), and tail separation factor ((equation omitted)) of PTMSP/PDMS-PEI composite membrane were 21.50, 49.14 and 1.84 respectively at $\Delta$P 345.55 kPa and $25^{\circ}C$.

Separation of $H_2$/$N_2$ Gas Mixture by PTMSP-PEI and PDMS-PEI Composite Membranes (PTMSP-PEI와 PDMS-PEI 복합막에 의한 수소/질소 혼합기체 분리)

  • 강태범;조성혜;이현경
    • Membrane Journal
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    • v.13 no.4
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    • pp.291-299
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    • 2003
  • Polymer membranes such as poly(1-trimethylsilyl-1-propyne)-polyetherimide (PTMSP-PEI) and poly(dimethylsiloxane)- polyetherimide (PDMS-PEI) composite membrane were prepared by solution casting method. To investigate the characteristics of these membranes, the analytical methods such as FT-IR, $^1H-NMR,$ DSC, TGA, GPC, and SEM have been utilized. The number-average (equation omitted) and weight-average (equation omitted) molecular weight of PTMSP were 477,920 and 673,329 respectively. The glass transition temperature ($T_g$) of PTMSP was $224^{\circ}C.$ The separation of the gas mixture ($H_2/N_2$) through the composite membranes were studied as a function of pressure. The separation factor (${\alpha}, {\beta},$ quation omitted) of the composite membranes used in this work increased as the pressure of permeation cell increased. The real separation factor (${\alpha}$), head separation factor (${\beta}$), and tail separation factor (equation omitted) of PTMSP-PEI composite membrane were 2.28, 1.17, and 1.96 respectively at ${\Delta}P$ 30psi and $25^{\circ}C.$ (${\alpha}, {\beta}$ and equation omitted of PDMS-PEI composite membrane were 3.70, 1.53, and 2.42 respectively at ${\Delta}P$ 30psi and $25^{\circ}C$.

NUMERICAL SIMULATION ON PHASE SEPARATION BY 2D LATTICE-BOLTZMANN METHOD (LBM을 이용한 2차원 상분리 시뮬레이션)

  • Jung, Rho-Taek
    • 한국전산유체공학회:학술대회논문집
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    • 2009.11a
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    • pp.109-114
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    • 2009
  • As one of the promising model on the multiphase fluid mixtures, the Lattice-Boltzmann Method(LBM) is being developed to simulate flows containing two immisible components which are different mass values. The equilibrium function in the LBM can have a nonideal gas model for the equation of state and use the interfacial energy for the phase separation effect. An example on the phase separation has been carried out through the time evolution. The LBM based on the statistic mechanics is appropriate to solve very complicated flow problems and this model gives comparative merits rather than the continuum mechanics model.

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A Study on the Utilization of the LNG Cold Heat for the Reduction of the Power Consumption in Main Air Compressors in Cryogenic Air Separation (심냉 공기분리공정의 공기압축공정에서 전력비 절감을 위한 액화천연가스 냉열 활용에 대한 연구)

  • CHO, DUHEE;CHO, JUNGHO
    • Journal of Hydrogen and New Energy
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    • v.31 no.3
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    • pp.322-327
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    • 2020
  • In this work, a study for the reduction of the electric power consumption has been estimated in main air compressors in the air separation unit through cryogenic distillation columns with PRO/II with PROVISION V10.2 at AVEVA company. Both required LNG mass flow rate and cold heat contained in 1 ton of LNG were also predicted using Peng-Robinson equation of state with Twu's new alpha function. Through this work, we concluded that 32.33-48.69% of electric power could be saved by using LNG cold heat.

Separation Effect Analysis for Rainfall Data (강우자료의 분리효과)

  • 김양수;허준행
    • Water for future
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    • v.26 no.4
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    • pp.73-83
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    • 1993
  • This study focuses on the separation effect analysis of rainfall data for 2-parameter log-normal, 3-parameter log-normal, type-extreme value, 2-parameter gamma, 3-parameter gamma, log-Pearson type-III, and general extreme value distribution functions. Difference in the relationship between the mean and standard deviation of skewness for historical data and relations derived from 7 distribution functions are analyzed suing the Monte Carlo experiment. The results show that rainfall data has the separation effect for 6 distribution functions except 3-parameter gamma distribution function.

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Freezing Characteristics in a Horizontal Rectangular Channel with the Two-Dimensional Protuberances (2차원 직사각형 덕트 내부에 돌기부를 갖는 흐름의 동결특성에 관한 연구)

  • Oh, Cheol
    • Journal of Advanced Marine Engineering and Technology
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    • v.27 no.6
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    • pp.721-727
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    • 2003
  • Freezing of turbulent water flow between two horizontal cooled parallel plates with the separated region has been investigated experimentally. The flow separation was induced by vertical plates (two-dimensional plates) situated at the inlet of the rectangular channel. The degree of flow separation was varied by employing vertical thin plates with various heights. Three kinds of the vertical plates with 8.0, 9.8 and 12.5 mm in height were utilized. The Reynolds number and cooling temperature ratio were ranged from $3.45\times10^3 to 1.73\times10^4$ and 7.0 to 20.0 respectively, The measurements show that the flow separation influenced remarkably on the local ice formation characteristics. The location of the first ice layer and the average heat transfer at the ice surface were found be correlated as a function of the Reynolds number, the cooling temperature ratio, and the orifice height ratio.

Performance Analysis of a Hydrodynamic Separator for Treating Particulate Pollutants in Highway Rainfall Runoff

  • Yu, Jianghua;Yi, Qitao;Kim, Young-Chul
    • Environmental Engineering Research
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    • v.14 no.4
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    • pp.262-269
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    • 2009
  • This study examined the separation characteristics of particles in the rainfall runoff from paved roads using a ${\varphi}7.5$ cm hydrocyclone. The volume fraction and total suspended solids concentrations in the overflow and underflow from the hydrocyclone, as well as the separation efficiency were determined. The results indicated that the overflow volume increased with increasing operational pressure, but decreased with decreasing ratio of underflow outlet to inlet sizes ($D_u/D_i$), while the underflow to overflow volumes showed contrary behavior. The total suspended solid (TSS) concentration ratio between the overflow and inflow ($TSS_{over/in}$) decreased as a function of the operational pressure, while the corresponding ratio of underflow to inflow ($TSS_{under/in}$) increased. There was no visible difference in the $TSS_{over/in}$ with increasing $D_u/D_i$ ratio, but the $TSS_{under/in}$ decreased sharply. The particle removal efficiency was mainly affected by the particle size.

Solution NMR spectroscopy for investigation of liquid-liquid phase separation

  • Saio, Tomohide;Okumura, Masaki;Lee, Young-Ho
    • Journal of the Korean Magnetic Resonance Society
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    • v.24 no.2
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    • pp.47-52
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    • 2020
  • Liquid-liquid phase separation (LLPS) of biomolecules, a newly-found phase behavior of molecules in the liquid phase, has shown to its relationship to various biological function and misfolding diseases. Extensive studies have increasingly revealed a general mechanism of LLPS and characterized the liquid droplet; ho wever, intermolecular interactions of proteins and structural states of LLPS-inducing proteins inside of the droplet remain largely unknown. Solution NMR spectroscopy has emerged as a powerful approach as it provides invaluable information on protein intermolecular interactions and structures at the atomic and residue level. We herein comprehensively address useful techniques of solution NMR including the effect of paramagnetic relaxation enhancement for the study on the LLPS and droplet based on recent studies.

Mechanism Design of Cube Satellite for Multi-deployable Structures and Autonomous System Operation after Launcher Separation (복수구조 전개 및 발사체 분리직후 시스템 자동운용을 위한 큐브위성의 메커니즘 설계)

  • Lee, Myoung-Jae;Jung, Hyun-Mo;Oh, Hyun-Ung
    • Journal of Aerospace System Engineering
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    • v.7 no.3
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    • pp.20-25
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    • 2013
  • In case of cube satellite, it is difficult to realize the same performance as commercial satellite due to its highly restricted unit accommodation space. To maximize the performance of the cube satellite, design concept considering the multi-function of satellite is required. In this paper, mechanism design of cube satellite which is applicable for the holding and release of multi-deployable structures has been proposed and investigated. In addition, a switch mechanism design for the autonomous system operation just after the cube satellite separation from P-POD has also been proposed. The effectiveness of the mechanism design for holding and release of multi-deployable structures has been demonstrated by EM test of the holding and release mechanism.