• Journal of the Korean Electrochemical Society
• /
• v.5 no.4
• /
• pp.226-231
• /
• 2002

Power densities produced by the permeation of methanol through membranes were directly measured by inserting the membrane in front of anode in a membrane-electrode-assembly of a direct methanol fuel cell (DMFC). The power density was closely related to the loss of power in the DMFC and was strongly affected by temperature. As the cell temperature was increased, the power density resulting from methanol crossover was increased. The increase in methanol crossover had be attributed to diffusion caused or affected by temperature. Methanol crossover a major effect on the performance of a DMFC at a relatively low temperature with $26\%\;loss\;at\;30^{\circ}C$. In order to reduce methanol crossover, a conventional Nafion membrane was modified by the incorporation of Pt or Pd. The reduction in methanol crossover was investigated in these modified membranes by our cell performance measurement. Pt and Pd particles incorporated in the Nafion membranes block methanol pathway and prevent methanol transport through the membranes, which was proved by combining with liquid chromatography.

• Journal of the Korea Institute of Military Science and Technology
• /
• v.6 no.3
• /
• pp.54-61
• /
• 2003

$SnO_2$ gas sensor for the detection DMMP, simulant of nerve gas was fabricated and its characteristics were examined. Sensing materials were $SnO_2$ added by TEX>$\alpha$-$Al_{2}O_{3}$ with 0∼20wt.% and $In_{2}O_{3}$ with 0∼3wt.% and were physically mixed each material. They were deposited by screen printing method on alumina substrate. The sensor was consisted of sensing electrode with interdigit(IDT) type in front and a heater in back side. Its dimension was 7$\times$10$\times$0.6$\textrm{mm}^2$. Crystallite size 8t phase identification, specific surface area and morphology of fabricated $SnO_2$ powders were analyzed by X-ray diffraction(XRD), surface area analyzer(BET) and by a scanning electron microscope(SEM), respectively. Sensor was measured as flow type and sensor resistance change was monitored as real time using LabVIEW program. The best sensitivities were 75% at adding 4wt.% TEX>$\alpha$-$Al_{2}O_{3}$, operating temperature $300^{\circ}C$ and 87% at adding 2wt.% $In_{2}O_{3}$, operating temperature $350^{\circ}C$ to DMMP 0.5ppm. Response and recovery times were about 1 and 3 min., respectively. Repetition measurement was very good with $\pm$3% in full scale. As a result, operating temperature was lower TEX>$\alpha$-$Al_{2}O_{3}$ than $In_{2}O_{3}$, but sensitivity was higher $In_{2}O_{3}$ than $\alpha$-$Al_{2}O_{3}$.

• Korean Journal of Optics and Photonics
• /
• v.12 no.2
• /
• pp.103-108
• /
• 2001

In this paper, we designed and made the scanned point detecting system for 3-dimensional measurement of the light emitted from plasma display panel (PDP) , and we measured and analyzed 3-dimensional light emitted from a real PDP by using this scanned point detecting system. The scanned point detecting system has a point detector with a pinhole. The light emitted from the source at the in-focus position can pass through the pinhole and be collected by detector. The light from other sources at outof-focus positions is focused at points in front of or behind the pinhole, and thus it is intercepted by the pinhole. Therefore, we can detect light information from a particular point of a PDP cell of 3-dimensional structure. We know the electric field distribution inside the PDP cell from the 3-dimensionallight intensity distribution measured by using the scanned point detecting system. As the Z axial measurement increases, the intensity of light detected increases and intensity of light detected on the inside edge of the ITa electrode is larger than outside edge of the ITa eletrode and gap of the ITa electrodes. Also, as the measurement point moves from one barrier rib to another, the detected light is weaker near to the barrier ribs than at the center between the barrier ribs. The emitted light is concentrated at the center between barrier ribs. ribs.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2016.02a
• /
• pp.431-431
• /
• 2016

Typical Cu(In,Ga)Se2 (CIGS)-based solar cells have a buffer layer between CIGS absorber layer and transparent ZnO front electrode, which plays an important role in improving the cell performance. Among various buffer materials, chemical bath deposition (CBD)-ZnS is being steadily studied to alternative to conventional CdS and the efficiency of CBD-ZnS/CIGS solar cell shows the comparable values with that of CdS/CIGS solar cell. The intriguing thing is that reversible changes occur after exposure to illumination due to the metastable defect states in completed ZnS/CIGS solar cell, which induces an improvement of solar cell performance. Thus, it implies that the understanding of metastable defects in CBD-ZnS/CIGS solar cell is important issue. In this study, we fabricate the ITO/i-ZnO/CBD-ZnS/CIGS/Mo/SLG solar cells by controlling the NH4OH mole concentration (from 2 M to 3.5 M) of CBD-ZnS buffer layer and observe their conversion efficiency with and without light soaking for 1 hr. From the results, NH4OH mole concentration and light exposure can significantly affect the CBD-ZnS/CIGS solar cell performance. In order to investigate that which layer can contain metastable defect states to influence on solar cell performance, impedance spectroscopy and capacitance profiling technique with exposure to illumination have been applied to CBD-ZnS/CIGS solar cell. These techniques give a very useful information on the density of states within the bandgap of CIGS, free carriers density, and light-induced metastable effects. Here, we present the rearranged charge distribution after exposure to illumination and suggest the origin of the metastable defect states in CBD-ZnS/CIGS solar cell.

• Journal of Korean Neurosurgical Society
• /
• v.30 no.1
• /
• pp.41-46
• /
• 2001

Objective : The exact position of the lesion during the pallidotomy is critical to obtain the clinical improvement of parkinson's disease without damage to surrounding structure. Ventriculogrphy, CT(computed tomograpy) or MRI(magnetic resonance imaging) have been used to determine the initial coordinates of stereotactic target for pallidotomy. The goal of this study was to determine whether microelectrode recording significantly improves the neurophysiologic localization of the target obtained from MRI. Methods : Twenty patients were studied. They underwent a unilateral pallidotomy. Leksell frame was applied and T1 axial images parallel to the AC-PC(anterior commissure-posterior commissure) plane using a 1.5 Tesla MRI with 3mm slice thickness were obtained. Anteroposterior coordinate of target was chosen at 2mm in front of the midcommissural point and lateral coordinate between 19 and 22mm from the midline. The vertical coordinate was calculated on coronal slice using a fast spin echo inversion recovery sequence(FSEIR) related to the position of the choroidal fissure and ranged over 4-5mm below the AC-PC plane. Confirmation of the anatomical target was done on axial slices using the same FSEIR sequence . Microrecording was done at the pallidum contralateral to the symptomatic side using an electrode with a tip diameter of $1{{\mu}m}$ diameter tip and 1.1-1.4 mOhm impedance at 1000Hz. Electrophysiologic localization of the target was also confirmed intraoperatively by macrostimulation. Results : Microrecording techniques were reliable to define the transition from the base of the pallidum which was characterized by the disappearance of spike activity and by the change of the audible background activity. Signals from high amplitude neurons firing at 200-400Hz were recorded in the pallidal base. X, Y and Z coordinates of target obtained from the MRI were within 1mm from the X, Y, Z coordinates obtained with microrecording in 16 patients (80%), 15 patients(75%), 10 patients(50%) respectively. The difference of Y coordinate between on MRI and on microrecording was 4mm in only one patient. Conclusion : The MRI was accurate to localize the target within 1mm of the error from microrecording target in 70% of the patients. 4mm discrepancy was observed only once. We conclude that MRI alone can be used to determine the target for pallidotomy in most patients. However, microrecording technique can still be extremely valuable in patents with aberrant anatomy or unusual MRI coordinates. We also consider physiologic confirmation of the target using macrostimulation to be mandatory in all cases.

• Journal of Korea Soil Environment Society
• /
• v.5 no.1
• /
• pp.25-32
• /
• 2000

The electrokinetic apparatus for remediation of the soil contaminated with $Sr^{2+}$ was designed. After kaolin clay compulsorily contaminated by $Sr^{2+}$ solution, the remediation characteristics by electrokinetic method were analyzed. Meanwhile. the numerical code for analysis of electrokinetic migration was developed for modelling of the soil remediation. And the input parameters needed for modelling were measured by laboratory experiment or taken from literature. Experimental results are as follows: After 3 day remidiation under 40 voltage, the front part of experimental cell was almost decontaminated, but the behind part didnt almost be decontaminated. Consequently. the total remediation ratio of $Sr^{2+}$ from cell soil was about 42.6%. Also, the total $Sr^{2+}$remediation ratio from cell soil was about 84.8% after 6 days. The values calculated by the developed code almost agreed with experimental values When voltages of electrode were increased by 10, 30, 40V, the total $Sr^{2+}$ remediation ratlos were about 21.9%. 43.3%, 84.8%, respectively, after 6 days.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
• /
• v.22 no.12
• /
• pp.122-129
• /
• 2008

This paper gives the experimental results for the effective precipitation of particulated matter(PM) below 1[${\mu}m$] of diameter using the electrostatic precipitator, which is designed by ourselves. In order to improve the precipitation efficiency, the vertical and parallel magnetic field to the electric field is applied simultaneously by arranging ferrite magnets. When the parallel magnetic field is applied, the precipitation efficiency does not improve in comparison with non-magnets. However, when the vertical magnetic field is applied, it is improved about 5[%] more than the case of non-magnetized ferrite plate used. In addition, when the magnets are installed at the center of ground plate electrodes, the precipitation efficiency is ranged from 17 to 32[%] under the applied voltage of 5[kV]. It is similar to the case of the magnet arrangement at the front part of ground electrode. Also, the precipitation efficiency is more improved by arranging magnets as the inside part and zigzag on the electrodes. Especially, large particles of 0.7 and 1[${\mu}m$] is more easily captured by electrostatic precipitator. Consequently, it is convinced that the vertical magnetic field is more desirable than parallel magnetic field on the electric field for the effective treatment of particulated matter.

• Journal of Korean Tunnelling and Underground Space Association
• /
• v.25 no.6
• /
• pp.403-421
• /
• 2023

As the number of underground structures has increased in recent decades, it has become crucial to predict geological hazards ahead of a tunnel face during tunnel construction. Consequently, this study developed a finite element (FE) numerical model to simulate electrical resistivity surveys in tunnel boring machine (TBM) operations for predicting mixed ground conditions in front of tunnel faces. The accuracy of the developed model was verified by comparing the numerical results not only with an analytical solution but also with experimental results. Using the developed model, a series of parametric studies were carried out to estimate the effect of geological conditions and sensor geometric configurations on electrical resistivity measurements. The results of these studies showed that both the interface slope and the difference in electrical resistivity between two different ground formations affect the patterns and variations in electrical resistivity observed during TBM excavation. Furthermore, it was revealed that selecting appropriate sensor spacing and optimizing the location of the electrode array were essential for enhancing the efficiency and accuracy of predictions related to mixed ground conditions. In conclusion, the developed model can serve as a powerful and reliable tool for predicting mixed ground conditions during TBM tunneling.