• 제목/요약/키워드: Fe-N/C

검색결과 1,027건 처리시간 0.033초

대형마찰용접을 이용한 로타샤프트 제조공정개발 (Process Development of Rotor Shaft using a Large Friction Welding)

  • 정호승;조종래;이낙규;박희천;최성규
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 2007년도 춘계학술대회 논문집
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    • pp.401-404
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    • 2007
  • Inertia welding is a solid-state welding process in which butt welds in materials are made in bar and in ring form at the joint face, and energy required for welding is obtained from a rotating flywheel. The stored energy is converted to frictional heat at the interface under axial load. The quality of the welded joint depends on many parameters, including axial force, initial revolution speed and energy, amount of upset, working time, and residual stresses in the joint. Inertia welding was conducted to make the large rotor shaft for low speed marine diesel engine, alloy steel for shaft of 140mm. Due to different material characteristics, such as, thermal conductivity and flow stress, on the two sides of the weld interface, modeling is crucial in determining the optimal weld geometry and parameters. FE simulation was performed by the commercial code DEFORM-2D. A good agreement between the predicted and actual welded shape is observed. It is expected that modeling will significantly reduce the number of experimental trials needed to determine the weld parameters.

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Structural and Magnetic Properties of Co2MnSi Heusler Alloy Films

  • Lim, W.C.;Okamura S.;Tezuka N.;Inomata K.;Bae, J.Y.;Kim, H.J.;Kim, T.W.;Lee, T.D.
    • Journal of Magnetics
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    • 제11권1호
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    • pp.8-11
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    • 2006
  • Recently half-metallic full-Heusler alloy films have attracted significant interests for spintronics devices. As these alloys have been known to have a high spin polarization, very large TMR ratio is expected in magnetic tunnel junctions. Among these alloys, $Co_2MnSi$ full-Heusler alloy with a high spin polarization and a high Curie temperature is considered a good candidate as an electrode material for spintronic devices. In this study, the magnetic and structural properties of $Co_2MnSi$ Heusler alloy films were investigated. TMR characteristics of magnetic tunnel junctions with a $Co_2MnSi/SiO_2/CoFe$ structure were studied. A maximum MR ratio of 39% with $SiO_2$ substrates and 27% with MgO(100) substrates were obtained. The lower MR ratio than expectation is considered due to off-stoichiometry and atomic disorder of $Co_2MnSi$ electrode together with oxidation of the electrode layer.

느타리속(Pleurotus species) 균의 균사 배양을 위한 새로운 합성 배지 (New synthetic medium for growth of mycelium of Pleurotus species)

  • 박원목;김규현;현재욱
    • 한국균학회지
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    • 제23권3호통권74호
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    • pp.275-283
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    • 1995
  • The nutritional requirements of mycelial growth for Pleurotus spp. were studied. As the carbon sources, soluble starch and dextrin, nitrogen sources, arginine and ammonium tartrate, and calcium sources, $CaCO_3$ enhanced mycelial growth. Optimum C/N ratio was 100 : 1. On the base of results from the experiment on nutritional requirements, the following receipe is suggested for growth of Pleurotus spp.; starch 15 g, arginine 3.484 g, ammonium tartrate 3.06 g, $CaCO_3$ 0.314 g, $KH_2PO_4$ 8.138 g, $K_2HPO_4$ 1.584 g, $MgSO_4{\cdot}7H_2O$ 1.5 g for P. sajor-caju and 2.5 g for P. ostreatus. $FeSO_4{\cdot}7H_2O$ 0.02 g, $ZnSO_4{\cdot}7H_2O$ 0.03 g, $MnSO_4{\cdot}7H_2O$ 0.02 g, optimum pH 6.0. This new synthetic medium is tentatively designated as Park's medium.

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RF-Magnetron sputtering법을 이용한 ZnO buffer layer가 ZnO:(Al,P) 박막의 미세구조에 미치는 영향

  • 신승학;김종기;이준형;허영우;김정주
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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    • pp.266.2-266.2
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    • 2016
  • 최근 디스플레이 산업의 확대에 따라 투명 전도 산화물(Transparent Conducting Oxides:TCOs)의 수요가 급증하고 있다. 이 중 ZnO는 wide bandgap (3.37eV)와 large exciton binding energy (60meV)의 값을 가져 차세대 투명 전도 산화물, LED와 LD 등의 소자 소재로 각광받고 있다. ZnO는 electron을 내어놓는 native defect 때문에 기본적으로 n-type 물성을 띈다. 그래서 dopant를 이용해 p-type ZnO를 제작할 때 native defect를 줄이는 것이 중요한 요점이 된다. 이 때 buffer layer를 사용하여 native defect를 줄이는 방법이 사용되고 있다. 본연구에서는 RF-magnetron sputtering법을 이용하여 c-plane sapphire 기판 위에 다양한 조건의 ZnO buffer layer를 증착하고, 그 위에 ZnO:(Al,P) co-doping한 APZO를 증착하였다. ZnO buffer layer 증착조건의 변수는 증착온도와 Ar:O2의 비율을 변수로 두었다. 이러한 박막을 FE-SEM, XRD, Hall effect measurement, AFM을 통하여 미세구조와 물성을 관찰하였다. 이 때 APZO보다 낮은 증착온도에서 ZnO buffer layer가 증착되면 APZO를 증착하는 동안 chamber 내부에서 열처리하는 효과를 얻게 되고, UHV(Ultra High Vaccum)에서 열처리 될 때 ZnO buffer layer의 mophology와 결정성이 변하게 되는 모습을 관찰아혔다. 또한 본 실험을 통해 ZnO buffer layer의 증착 온도가 APZO의 증착온도보다 높을 때 제어 가능한 실험이 됨을 확인 할 수 있었다.

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피로 자료 분산을 고려한 자동차 부품의 신뢰도 해석 (Evaluation of chassis component reliability considering variation of fatigue data)

  • 남기원;이병채
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 2005년도 춘계학술대회 논문집
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    • pp.690-693
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    • 2005
  • In this paper, probabilistic distribution of fatigue life of chassis component is determined statistically by applying the design of experiments and the Pearson system. To construct $p-\varepsilon-N$ curve, the case that fatigue data are random variables is attempted. Probabilistic density function(p.d.f) for fatigue life is obtained by design of experiment and using this p.d.f fatigue reliability about any aimed fatigue life can be calculated. Lower control arm and rear torsion bar of chassis component are selected as examples for analysis. Component load histories, which are obtained by multi-body dynamic simulation for Belsian load history, are used. Finite element analysis are performed using commercial software MSC Nastran and fatigue analysis are performed using FE Fatigue. When strain-life curve itself is random variable, probability density function of fatigue life has very little difference from log-normal distribution. And the case of fatigue data are random variables, probability density functions are approximated to Beta distribution. Each p.d.f is verified by Monte-Carlo simulation.

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치과용 임플란트의 형상과 계면 응력의 상관관계 (The relation between shape and interfacial stress of dental implants)

  • 김한성;이상업;조남효;고재영;박상수;이훈;안세영;심준성;이철영;문홍석
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 2002년도 춘계학술대회 논문집
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    • pp.128-131
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    • 2002
  • Several FE models were developed based on micro-CT images of a mandibular specimen. A new dental implant model was suggested from parameter study for the relation between shape and interfacial stress of dental implants. It is found that the proposed model is highly beneficial.

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아크릴 섬유의 아미도옥심화에 관한 연구(I) -아미도옥심 반응과 천이금속의 흡착능- (Studies on Amidoximated Acrylic Fiber(I) -Amidoximation and Adsorption Capacity to Transition Metals -)

  • Chin, Young Gil;Kim, Kyu Beom
    • 한국염색가공학회지
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    • 제8권6호
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    • pp.40-46
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    • 1996
  • In order to investigate a practical application of fibrous absorbents to transition metals such as copper, nickel, cobalt, chrome, and iron, amidoximated fiber as a particular class of solid chelate agents were prepared from acrylic fibers treatment with hydroxylamine. The adsorption mechanisms of metal ions onto amidoximated acrylic fibers and their complexes were studied. Amidoximation of acrylic fiber with hydroxylamine is found to be first-order reaction, followed by the disappearance of infrared adsorption peaks due to nitrile groups of acrylic fibers. The uptake of metal ions onto amidoximated acrylic fiber is increased with temperature raising and the adsorption is also depended on pH of the soiutions. About 70% of metal ions can be recovered from aqueous solutions of Ni(II), Co(II), Cr(III), and Fe(II) on the concentration below 5x 10$^$^{-4}$ in the range of pH 2.1~10.0. Transition metals are adsorbed to form complex with amidoxime group by the ligand sites such as C=N, NH, NO, NHOH.OH.

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유동층 반응기에서 카본블랙 촉매를 이용한 프로판의 촉매 분해에 의한 수소생산 연구 (Hydrogen production by catalytic decomposition of propane over carbon black catalyst in a fluidized bed)

  • 윤용희;이승철;한귀영
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2007년도 춘계학술대회
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    • pp.81-85
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    • 2007
  • A fluidized bed reactor is made with quartz. The size of FBR is 0.055 m I.D. and 1.0 m in height. The FBR was employed for the thermocatalytic decomposition of propane to produce hydrogen without $CO_{2}$. The fluidized bed was proposed for the continuous withdraw of product carbons from the reactor. Carbon black DCC-N330 is used to decompose the propane gas. The propane decomposition reaction over carbon black catalyst in a fluidized bed reactor was carried out the temperature range of 600 ${\sim}$ 800 $^{\circ}C$, propane gas velocity of 1.0 ${\sim}$ 4.0$U_{mf}$($1U_{mf}$ = 0.61cm/s) and the catalyst loading of 100 ${\sim}$ 200g. Production of $H_{2}$ such as other reaction temperature, gas velocity, catalytic loading on the reaction rates was investigated. The carbon depositied on the catalyst surface was observed by FE-SEM. The particle size of the carbon black was observed by Particle size analyzer. Resulting production in the experiment was not only hydrogen but also several by-products such as methane, ethylene, ethane, and propylene.

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저합금강 소결체의 미세조직 및 기계적 특성에 미치는 인(P) 첨가의 영향 (Effect of Phosphorus Addition on Microstructure and Mechanical Properties of Sintered Low Alloy Steel)

  • 김유영;조권구
    • 한국분말재료학회지
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    • 제27권1호
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    • pp.31-36
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    • 2020
  • Phosphorus is an element that plays many important roles in powder metallurgy as an alloy element. The purpose of this study is to investigate the influence of phosphorus addition on the microstructures and mechanical properties of sintered low-alloy steel. The sintered low-alloy steels Fe-0.6%C-3.89%Ni-1.95%Cu-1.40%Mo-xP (x=0, 0.05, 0.10, 0.15, 0.20%) were manufactured by compacting at 700 MPa, sintering in H2-N2 at 1260 ℃, rapid cooling, and low-temperature tempering in Ar at 160 ℃. The microstructure, pore, density, hardness, and transverse rupture strength (TRS) of the sintered low-alloy steels were evaluated. The hardness increased as the phosphorus content increased, whereas the density and TRS showed maximum values when the content of P was 0.05%. Based on microstructure observation, the phase of the microstructure changed from bainite to martensite as the content of phosphorus is increased. Hence, the most appropriate addition of phosphorus in this study was 0.05%.

Pt/MOF-5 Hybrid Composite Encapsulated with Microporous Carbon Black to Improve Hydrogen Storage Capacity and Hydrostability

  • 여신영;곽승엽
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 2011년도 춘계학술발표대회
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    • pp.45.2-45.2
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    • 2011
  • Metal organic frameworks (MOF) have generated considerable interests as a potential candidate for hydrogen storage owing to their extremely high surface-to-volume ratio and low density. In this study, Pt nanoparticles of about 3 nm in size were introduced outside MOF-5 [$Zn_4O$(1,4-benzenedicarbocylate)3], which was then encapsulated with hydrophobic microporous carbon black (denoted CB@Pt/MOF-5) in order to enhance hydrogen uptake capacity without decreasing the specific surface area and hydrostability. To study the chemical composition, morphology, crystal information, and properties of the synthesized material, a variety of techniques is employed, including WXRD, XPS, ICP-AES, FE-SEM, HR-TEM, and N2 adsorption-desorption, confirming the formation of novel hybrid composite designated CB@Pt/MOF-5 with highly crystalline structure, large specific surface area and pore volume. In addition, $H_2$ storage capacity for resulting material was measured using magnetic suspension microbalance at 77 and 298 K under high-pressure condition, and the hydrostability was also tested by exposing the sample to 33% relative humidity at $23^{\circ}C$ and measuring XRD as a function of time.

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