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A Study on the Deposition of Boron Phosphide at the Low Temperature using CVD Method and its Characteristics (CVD법을 이용한 보론 포스파이드의 저온 층착과 특성에 관한 연구)

  • 윤여철;김순영;박윤권;강재경;김철주
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.103-107
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    • 2000
  • Boron Phosphide films were deposited on the glass substrate at the low temperature, 55$0^{\circ}C$, by the reaction of B$_2$H$_{6}$ with PH$_3$ using CVD. $N_2$ was employed as carrier gas. The optimal gas rates were 50 $m\ell$/min for B$_2$H$_{6}$, 50 $m\ell$/min for PH$_3$ $m\ell$/min and 1.5 $\ell$/min for $N_2$. To investigate the annealing effect, the films were annealed for 1hour, 3hours in $N_2$ambient at 55$0^{\circ}C$ and tested. The deposition rate was 1000$\AA$/min and the refractive index of film was 2.6. The measurement of X-RD shows that the films have the preferred orientation of (1 0 1) and the intensity of the peak for (1 0 1) orientation decreases according to the annealing time. The data of VIS spectrophotometer proved that the films are transparent in the visible range and the maximal transmittance increases according to the annealing time; 75.49% for as-deposited, 76.71% for 1hr-annealed and 86.4 % for 3hrs-annealed. The measurement of AFM shows that the average surface roughness increases according to the annealing time; 73$\AA$ for as-deposited, 88.9$\AA$ for 1hr-annealed and 220$\AA$ for 3hrs-annealed. Also, The data of the secondary electron emission rate(Υ) shows that the secondary electron emission rate increases according to the annealing time; 0.317 for 1hr-deposited, 0.357 for 1hr-annealed and 0.537 for 3hrs-annealed. And, The measurement of FT-IR that the characteristic of transmittance in the infrared range was stabilized through annealing.ing.

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The study of environmental monitoring by science airship and high accuracy digital multi-spectral camera

  • Choi, Chul-Uong;Kim, Young-Seop;Nam, Kwang-Woo
    • Proceedings of the KSRS Conference
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    • 2002.10a
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    • pp.750-750
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    • 2002
  • The Airship PKNU is a roughly 12 m (32 ft) long blimp, filled with helium, whose two-gasoline power(3hp per engine) are independently radio controlled. The motors and propellers can be tilted and are attached to the gondola through an axle and supporting braces. Four stabilizing fins are mounted at the tail of the airship. To fill in the helium, a valve is placed at the bottom of the hull. The inaugural flight was on jul. 31.2002 at the Pusan, S.korea Most environment monitoring system\ problem use satellite image. But, Low resolution satellite image (multi-spectral) : 1km ∼ 250 m ground resolutions is lows. So, detail information acquisition is hard at the complex terrain. High resolution satellite image (black and white) 30m : The ground resolution is high. But it is high price, visit cycle and delivery time is long So. We want make high accuracy airship photogrammetry system. This airship can catch picture Multi. spectral Aerial photographing (visible, Near infrared and thermal infrared), and High resolution (over 6million pixel). It can take atmosphere datum (Temperature (wet bulb, dew point, general), Pressure (static, dynamic), Humidity, wind speed). this airship is very Quickness that aircraft install time is lower than 30 minutes, it is compact and that conveyance is easy. High-capacity save image (628 cut per 1time (over 6million and 4band(R,G,B,NIR)) and this airship can save datum this High accuracy navigatin (position and rotate angle) by DGPS tech. and Gyro system. this airship will do monitor about red-tide, sea surface temperate, and CH-A, SS and etc.

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Comparison of the Kinematic Variables in the Badminton Smash Motion (숙련도에 따른 배드민턴 스매쉬 동작의 운동학적 변인 비교)

  • So, Jae-Moo;Han, Sang-Min;Seo, Jin-Hee
    • Korean Journal of Applied Biomechanics
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    • v.13 no.2
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    • pp.65-74
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    • 2003
  • The purpose of this study was to analyze kinematic variables in the badminton smash motion through 3-dimensional image analysis. The kinematic variables were velocity of joints in upper limbs, the angle of wrist in the impact, and the angular velocity of the top of racket head. The smash motions of four male badminton players in H University and four male students at department of the physical education in K University who were not majoring in badminton were analyzed kinematically and the attained conclusions were as follow. 1. The velocity of segments in upper limbs of the unskilled group was faster than that of the skilled group. The movement pattern was fast back swing-slow impact moment-fast fellow through in the unskilled group, but slow back swing-fast impact moment-slow follow through in the sullied group. 2. As the BS phases, the velocity of segment in right shoulder was different significantly between groups. Right elbow and right wrist segments, velocity of racket head was different significantly between groups(p<.05) by IP phases. As the FT phases, there was no significant difference. 3. The angle of right wrist at the impact, the angle of palm flexion and the angle of palm flexion in aspect were shown that the skilled group was higher than unskilled group. There was no significant difference. 4. The velocity of racket head was shown that the unskilled group has fast velocity, but the angle velocity was shown the unskilled group has slow. 5. The angle velocity of racket head in aspect were no significant difference between groups, but maximal angle velocity was different significantly between groups(p<.05).

Degradation Characteristics of Wood Cellulose by Ruminal Cellulolytic Anaerobic Bacterium Ruminococcus albus F-40 (혐기성 세균 Ruminococcus albus F-40에 의한 목재 cellulose의 분해특성)

  • Kim, Yoon-Soo;Wi, Seung-Gon;Myung, Kyu-Ho
    • Journal of the Korean Wood Science and Technology
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    • v.25 no.3
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    • pp.83-95
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    • 1997
  • The degradation mode of lignocellulose by anaerobic ruminal cellulolytic bacterium Ruminococcus albus F-40 was investigated. Birchwood holocellulose and filter paper were incubated as the sole carbohydrate sources with using the Hungate techniques. After 2 or 4 days of incubation, samples were employed for chemical and electron microscopic evaluations. The degradation rate of cellulosic substrates and the adhesion rate of bacteria to the substrates increased proportionally with the decrease of relative crystallinity of cellulose, indicating the preferential breakdown of amorphous cellulose, by this bacterium. X-ray diffraction analyses and polarized light microscopy showed, however, that crystalline cellulose was also degraded by R. albus. FT-IR spectra indicated that not only cellulose but hemicellulose was also degraded by this bacterium. Electron microscopic investigations showed the protuberant structures on the surface of R. albus. These structures were much more significant when bacterial cells were grown in the media containing insoluble substrates, such as cellulose, indicating clearly that bacterial protuberant structures were induced by the substrates. Protuberant structures extended from the bacterial cells adhered tightly to the substrates and numerous vesicles covered the surface of cellulosic substrates affected. Cellulosome-like structures were distributed on the cellulose matrix. Electron microscopic works showed that diverse surface organells of R. albus were involved in the degradation of cellulosic materials. SEM examinations showed the breakdown of cellulose by R. albus was proceeded by severeal routes : short fiber formation, defibrillation and destrafication of cellulose microfibril.

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Total Utilization of Woody Biomass by Steam Explosion(II) -The Preparation of Carboxymethylcellulose from Exploded Wood- (폭쇄법(爆碎法)을 이용(利用)한 목질계(木質系) biomass의 종합적(綜合的) 이용(利用)(II) -폭쇄재(爆碎材)로부터 Carboxymethyl cellulose의 제조(製造)-)

  • Han, Sang-Yeol;Chang, Jun-Pok;Lee, Jong-Yoon
    • Journal of the Korean Wood Science and Technology
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    • v.22 no.2
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    • pp.30-36
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    • 1994
  • Steam explosion process is one of the most efficient, pretreatment method for the utilization of lignocellulosic biomass. The carbxymethyl-cellulose(CMC) was prepared with steam exploded wood(EXW), pine(Pinus densiflora) and oak(Quercus mongolica), by standard method using isopropyl alcohol and monochloroacetic acid. The range of water solubility of carboxymethylated pine exploded wood was 45.2~66.8 % and those of oak was 60.7~84.7 %. The degree of substitution(D.S) of carboxymethylated pine exploded wood was 0.11~0.33 and oak exploded wood was 0.48~0.76. The color of carboxymethylated pine and oak exploded wood was brown-black. When carboxymethylated EXW was purified by sulfuric acid, the yield of carboxymethylated wood was lower than non-treated one. However, the color was still brown-black although after delignification. In carboxymethylated EXM prepared after delignification, the water solubility and degree of substitution(D.S) of pine were 81.4~95.9 % and 0.71~0.79, and those of oak were 76.2~89.5 % and 0.79~1.05. The values were higher than non-treated. The degree of substitution of purified carboxymethylated wood prepared with delignified EXM, pine and oak were 0.50~0.71 and 0.70~0.88. The color of carboxymethylated wood was white. In carboxymethylated wood preparde after delignification of EXM, swelling ratio and water retention value of pine were 95.9~96.5 and 580.0~751.2, those of oak were 76.2~89.5 and 124.3~307.6.

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Optical properties of epitaxial $Gd_2$O_3:EU^{3+}$luminescent thin films depending on crystallinity ($Gd_2$O_3:EU^{3+}$ 형광체 박막의 결정성에 따른 발광특성 연구)

  • 장문형;최윤기;정권범;황보상우;장홍규;노명근;조만호;손기선;김창해
    • Journal of the Korean Vacuum Society
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    • v.12 no.4
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    • pp.275-280
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    • 2003
  • Epitaxial Gd$_2O_3:Eu^{3+}$luminescent thin films have been grout on Si(III) substrates using ionized Cluster Beam Deposition (ICBD). After the film growing, they were implanted and post annealed to change the crystal structure. The initial growth stage was monitored by using in-situ Reflection High Energy Electron Diffraction (RHEED). The formed crystal structure was identified with X-ray diffraction (XRD) technique and Fourier transform infrared (FT-R) spectroscopy. The electronic states variations were investigated by Near Edge X-ray Absorption Fine Structure (NEXAFS). Photoluminescence (PL), Cathodoluminescence (CL). and Vacuum ultraviolet (VUV) spectrum were used for examining the optical properties. We report the optical property changes depending on crystal structure and the electronic states.

A Simple Carbamidomethylation-Based Isotope Labeling Method for Quantitative Shotgun Proteomics

  • Oh, Donggeun;Lee, Sun Young;Kwon, Meehyang;Kim, Sook-Kyung;Moon, Myeong Hee;Kang, Dukjin
    • Mass Spectrometry Letters
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    • v.5 no.3
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    • pp.63-69
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    • 2014
  • In this study, we present a new isotope-coded carbamidomethylation (iCCM)-based quantitative proteomics, as a complementary strategy for conventional isotope labeling strategies, with providing the simplicity, ease of use, and robustness. In iCCM-based quantification, two proteome samples can be separately isotope-labeled by means of covalently reaction of all cysteinyl residues in proteins with iodoacetamide (IAA) and its isotope (IAA-$^{13}C_2$, $D_2$), denoted as CM and iCCM, respectively, leading to a mass shift of all cysteinyl residues to be + 4 Da. To evaluate iCCM-based isotope labeling in proteomic quantification, 6 protein standards (i.e., bovine serum albumin, serotransferrin, lysozyme, beta-lactoglobulin, beta-galactosidase, and alpha-lactalbumin) isotopically labeled with IAA and its isotope, mixed equally, and followed by proteolytic digestion. The resulting CM-/iCCM-labeled peptide mixtures were analyzed using a nLC-ESI-FT orbitrap-MS/MS. From our experimental results, we found that the efficiency of iCCM-based quantification is more superior to that of mTRAQ, as a conventional nonisobaric labeling method, in which both of a number of identified peptides from 6 protein standards and the less quantitative variations in the relative abundance ratios of heavy-/light-labeled corresponding peptide pairs. Finally, we applied the developed iCCM-based quantitative method to lung cancer serum proteome in order to evaluate the potential in biomarker discovery study.

Surface Immobilization of $(1{\to}3)(1{\to}6)-{\beta}-glucan$ onto Biodegradable Polymer for Tissue Regeneration (조직 재생을 위한 Poly (D, L-lactide-co-glycolide) 표면에 $(1{\to}3)(1{\to}6)-{\beta}-glucan$ 고정에 대한 세포 점착 및 성장 효과)

  • Lee, S.G.;Lee, J.B.;Yu, S.M.;Park, J.C.;Choi, J.B.;Kim, J.K.
    • Journal of Biomedical Engineering Research
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    • v.27 no.5
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    • pp.218-223
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    • 2006
  • We examined the effects of ${\beta}$-glucan-reinforced PLGA film and scaffold on HDFs (human dermal fibroblast) attachment and proliferation. The PLGA films were prepared by simple solvent-casting method. The prepared films were grafted with $(1{\to}3)(1{\to}6)-{\beta}-glucan$ in various ratios after plasma treatment on surface. The surface of the film was characterized by contact angle measurement, scanning electron microscope (SEM), and Fourier-transform infrared spectrophotometer (FT-IR). The amount of $(1{\to}3)(1{\to}6)-{\beta}-glucan$ in the prepared film was indirectly determined by phenol-sulfuric acid method. The HDFs (Human dermal fibroblasts) were used to evaluate the cell attachment and proliferation on PLGA specimens before and after plasma/${\beta}-glucan$ treatment. The result showed that the plasma treated groups exhibited more mont of ${\beta}-glucan$ might be grafted than the non plasma treated groups. Cell attachment was significantly enhanced in the plasma/${\beta}-glucan$ grafted group after 4 hours incubation (p<0.05) due to the improved hydrophilicity and cytoactivity effect of the ${\beta}-glucan$. The cell proliferation of plasma/${\beta}-glucan$ (2mg/ml) grafted group was the highest rate among the groups (p<0.05).

Study on the Dental Caries of the Lower First Permanent Molars in the Age from 20 to 29 in Iri City, Chunrabuk-do (전라북도 이리지역의 20대 남녀 하악 제1대구치 우식에 관한 연구)

  • Lee, In-Kyu;Kim, Yun-Su
    • Journal of Technologic Dentistry
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    • v.8 no.1
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    • pp.91-99
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    • 1986
  • In order to evaluate the community dental health level the actual health capacity of the lower-first permanent molar is suitable as a indicator for assessment. So we had surveyed decayed, missed and filled lower permanent first molar of 460 persons who were in the age from 20 to 29 in Iri City. The obtained results were as follows: 1. The DMFT indices of the lower first permancent molars showed in 1.40 in the age group of from 20 to 24 and 1.44 from 25 to 29. 2. The actual dental health capscities of the lower first permanent molars showed in 84.86% in the age group of from 20 to 24 and 81.03% from 25 to 29. 3. The DMF indices of the lower first permanent molars showed 15.15% in the age group of from 20 to 24 and 18.98% of from 25 to 29. 4. The DMF rates of the lower first permanent molars showed 85.66% in the age group of from 20 to 24 and 88.70% of from 25 to 29. 5. The DMF rates of the lower first permanent molars showed 70.00% in the age group of from 20 to 24 and 71.96% of from 25 to 29. 6. The DT rates of the lower first permanent molars showed 48.84% in the age group of from 20 to 24 and 39.55% of from 25 to 29. 7. The FT rates the lower first permanent molars showed 40.22% in the age group of from 20 to 24 and 43.98% of from 25 to 29. 8. The MT rates of the lower first permanent molars showed 10.94% in the age group of from 20 to 24 and 16.17% of from 25 to 29.

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Solubility and Conformation of Silk Fibroin Membrane

  • Kweon, Hae-Yong;Kang, Seok-Woo;Lee, Kwang-Gill;Park, Kwang-Young;Jo, You-Young;Kang, Pil-Don;Sung, Gyoo-Byung;Lee, Heui-Sam;Yeo, Joo-Hong;Shin, Kyu-Hwan;Park, Chan-Hum
    • International Journal of Industrial Entomology and Biomaterials
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    • v.22 no.2
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    • pp.101-105
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    • 2011
  • Transparency and insolubility of eardrum patch against exudates are important for otolaryngological surgery. The author prepared silk fibroin (SF) films with various concentrations and temperature and then examined solubility and conformation of SF films. SF films were transparent regardless of the various preparation conditions. Although most SF films are soluble in 1X PBS solution at $37^{\circ}C$ for 1 h, the SF film with 3.4% with $60^{\circ}C$ was insoluble. Scanning electron microscopy (SEM) showed that the SF films have solid and smooth surface. Fourier transform infrared spectroscopy (FT-IR) and differential scanning calorimetry (DSC) results showed that the conformation of SF films was influenced by the preparation conditions including SF concentration and casting temperature. In conclusion, SF membrane with transparence and insolubility against exudates could be considered as eardrum patch resources.